Self-ordered cellulose nanocrystals and microscopic investigations

• Autorzy: Castro-Guerrero C. F. , Morales-Cepeda A. B. , Díaz-Guillén M. R. , Delgado-Arroyo F. , López-González F. A.

Identyfikatory

DOI

10.2478/msp-2020-0068

• Języki publikacji: EN

Abstrakty

EN

Cellulose nanocrystals were extracted from cotton. The cellulose nanocrystals made a self-assembly structure when dried under slow conditions, as it was revealed by the characterization made to the material. The AFM images of the nanocrystals showed that they had a changing local orientation, pointing in a preferred direction that underwent a periodic change. This periodic change resembles the orientation of a chiral nematic phase. The TEM images showed that the nanocrystals had a rod-like appearance with average length size of 98.5 nm and a diameter of 4.7 nm. The TEM characterization showed the nanocrystals with more details than AFM. In this paper, the self-assembling of CNC was observed by AFM, and further investigations were done by TEM, deconvoluting the process of CNC nanorods aggregation.

Słowa kluczowe

EN

cellulose nanocrystals; biopolymer; self-assembly; TEM of cellulose

• Wydawca: De Gruyter
• Czasopismo: Materials Science Poland
• Rocznik: 2020
• Tom: Vol. 38, No. 4
• Strony: 613--618
• Opis fizyczny: Bibliogr. 27 poz., rys.

Twórcy

autor

Castro-Guerrero C. F.

• CONACyT-Instituto Nacional de Electricidad y Energías Limpias, División de Sistemas Mecánicos, Reforma 113, Col. Palmira, Cuernavaca, Mor., C.P. 62490, Mexico

autor

Morales-Cepeda A. B.

• Instituto Tecnológico de Ciudad Madero, División de Estudios de Posgrado e Investigación, Juventino Rosas y Jesús Uruetas/n, Col. Los Mangos, Tampico, Tam., C.P. 89440, Mexico

autor

Díaz-Guillén M. R.

• Instituto Nacional de Electricidad y Energías Limpias, División de Sistemas Mecánicos, Reforma 113, Col. Palmira, Cuernavaca, Mor., C.P. 62490, Mexico

autor

Delgado-Arroyo F.

• Instituto Nacional de Electricidad y Energías Limpias, División de Sistemas Mecánicos, Reforma 113, Col. Palmira, Cuernavaca, Mor., C.P. 62490, Mexico

autor

López-González F. A.

• Instituto Nacional de Electricidad y Energías Limpias, División de Sistemas Mecánicos, Reforma 113, Col. Palmira, Cuernavaca, Mor., C.P. 62490, Mexico

Bibliografia

• [1] REVOL J.F., BRADFORD H., GIASSON J., MARCHESSAULT R.H., GRAY D.G., Int. J. Biol. Macromol., 14 (1992), 170.
• [2] ROMAN M., GRAY D.G., Langmuir, 21 (2005), 5555.
• [3] CASTRO-GUERRERO C.F., GRAY D.G., Cellulose, 21 (2014), 2567.
• [4] ZAMARRIPA-CERÓN J.L., GARCÍA-CRUZ J.C., MARTÍNEZ-ARELLANO A.C., CASTRO-GUERRERO C.F., ÁNGELES-SAN MARTÍN M.E., MORALESCEPEDA A.B., J. Appl. Polym. Sci., 133 (2016), 43285.
• [5] GRAY D.G., Nanomaterials, 6 (2016), 213.
• [6] PAL K., MAITI U.N., MAJUMDER T.P., DEBNATH S.C., GHOSH S., ROY S.K., OTON J.M., Nanotechnology, 24 (2013), 125702.
• [7] SAGADEVAN S., PAL K., CHOWDHURY Z.Z., FOLEY M., J. Alloy. Compd., 728 (2017), 645.
• [8] PAL K., MOHAN M.L.N., FOLEY M., AHMED W., Org. Electron., 56 (2018), 291.
• [9] THIRUGNANASAMBANDAN T., PAL K., SIDHU A., ELKODOUS M.A., PRASATH H., KULASEKARAPANDIAN K., AYESHAMARIAM A., JEEVANANDAM J., Nano-Struct. Nano-Objects, 16 (2018), 224.
• [10] HABIBI Y., CHANZY H., VIGNON M.R., Cellulose, 13 (2006), 679.
• [11] ROMAN M., WINTER W.T., Biomacromolecules, 5 (2004), 1671.
• [12] HABIBI Y., CHANZY H., VIGNON M.R., Cellulose, 13 (2006), 679.
• [13] KANG X., KUGA S., WANG C., ZHAO Y., WU M., HUANG Y., ACS Sustain. Chem. Eng., 6 (2018), 2954.
• [14] TRACHE D., HUSSIN M.H., HAAFIZ M.K.H., THAKUR V.K., Nanoscale, 9 (2017), 1763.
• [15] OUN A.A., RHIM J.W., Carbohydr. Polym., 134 (2015), 20.
• [16] CHERHAL F., COUSIN F., CAPRON I., Biomacromolecules, 17 (2016), 496.
• [17] WANG P.-X., HAMAD W.Y., MACLACHLAN M.J., Angew. Chem. Int. Ed., 55 (2016), 1.
• [18] PILLERS M.A., SHUTE R., FARCHONE A., LINDER K.P., DOERFLER R., GAVIN C., GROSS V., LIEBERMAN., J. Vis. Exp., 101 (2015) e52972.
• [19] BECK S., BOUCHARD J., BERRY R., Biomacromolecules, 12 (2011), 167.
• [20] ARAKI J., WADA M., KUGA S., Langmuir, 17 (2001), 21.
• [21] DIERKING I., AL-ZANGANA S., Nanomaterials, 7 (2017), 305.
• [22] GRAY D.G., MU X., Materials, 8 (2015), 7873.
• [23] PARKER R.M., FRKA-PETESIC B., GUIDETTI G., KAMITA G., CONSANI G., ABELL C., VIGNOLINI S., ACS Nano, 10 (2016), 8443.
• [24] ONSAGER L., Ann. N. Y. Acad. Sci., 51 (1949), 627.
• [25] BECK-CANDANEDO S., ROMAN M., GRAY D.G., Biomacromolecules, 6 (2005), 1048.
• [26] HONORATO-RÍOS C., LEHR C., SANCTUARY R., OSIPOV M.A., BALLER J., LAGERWALL J.P.F., NPG Asia Mater, 10 (2018), 455.
• [27] STINSON-BAGBY K.L., ROBERTS R., FOSTER J., Carbohydr. Polym., 186 (2018), 429.

Uwagi

Opracowanie rekordu ze środków MNiSW, umowa Nr 461252 w ramach programu "Społeczna odpowiedzialność nauki" - moduł: Popularyzacja nauki i promocja sportu (2021).