Preparation and Characterization of a Novel Hyperbranched Polyester Polymers Using A2+B3 Monomers

• Autorzy: Al-Mutairi Nabeel Hasan , Al-Zubiedy Ali , Al-Zuhairi Ali J

Identyfikatory

DOI

10.30657/pea.2023.29.5

• Języki publikacji: EN

Abstrakty

EN

Compared to linear analogs, hyperbranched polymers (HBPs) have gotten much attention in the last decade because of their intrinsic globular topologies and distinctive features like low viscosity, high solubility, and a high degree of functionality. In this work, four types of hyperbranched polyester polymer HBPs have been synthesized using the A2+B3 polycondensation methodology. Firstly, the starting material B3 monomer (Pyrimidine-2,4,6-triol) has been synthesized using urea and malonic acid with the presence of sodium Na as the catalyst for the reaction. Secondly, four types of materials (tartaric acid TA, adipic acid AD, maleic acid MA, and phthalic anhydride PA) as A2 monomers were added to the starting material B3 monomer in an oil bath to prepare the four types of HBP. The chemical structure of HBPs was characterized by FTIR, and 1H-NMR. The molecular weight of the prepared HBPs was characterized by gel permeation chromatography GPC, and thermal properties were characterized by differential scanning calorimetry DSC and thermal gravimetric analysis TGA. FTIR results showed that there are new bands, such as C-O-C between A2 and B3 monomers, as indicated by 1H-NMR. In addition, GPC shows that the prepared polymers have a narrow molecular weight distribution with good thermal stability, as indicated by DSC and TGA.

Słowa kluczowe

EN

hyperbranched polyester HBP; A2+B3 monomer; polycondensation; 1H-NMR; GPC

PL

hiperrozgałęziony poliester HBP; monomer A2+B3; polycondensation; 1H-NMR; GPC

• Wydawca: Oficyna Wydawnicza Stowarzyszenia Menedżerów Jakości i Produkcji
• Czasopismo: Production Engineering Archives
• Rocznik: 2023
• Tom: Vol. 29, Iss. 1
• Strony: 28--36
• Opis fizyczny: Bibliogr. 22 poz., rys., tab.

Twórcy

autor

Al-Mutairi Nabeel Hasan

• 1Polymer and Petrochemical Industries Department, University of Babylon, Hilla, Iraq; Tel.: [phone]

autor

Al-Zubiedy Ali

• Polymer and Petrochemical Industries Department, University of Babylon, Hilla, Iraq

autor

Al-Zuhairi Ali J

• 2Department of Energy, College of Engineering, University of Babylon, Al-Musayyab, Iraq

Bibliografia

• 1. AL-Abayechi, M.M.H., AL-Zuhairi, A.J., AL-Baiati, M.N., 2020. Physical properties of hyperbranched polymers containing melamine derivative. AIP Conference Proceedings, 2290(1), 30027.10.1063/5.0027821
• 2. Al-Mutairi, N.H., Al-Zubiedy, A., J Al-Zuhairi, A., 2022. Hyperbranched Polyester Polymer Preparation and Study Its Effect on Some Properties of Polypropylene. Egyptian Journal of Chemistry, 65(8), 35–43.
• 3. Al-zuhairi, A., 2020. Synthesis of Hyper Branched Polyester Polymers Containing Thiobarbituric Acidand Study of its Optical Properties. 12(1), 1–11.10.31838/ijpr/2020.12.01.137
• 4. Al-Zuhairi, A.J., Allw, A.S., Obaid, K.A., Rasool, S.R., Mousa, A.O., 2017. Synthesis of hyperbranched polymers and study of its optical properties. Journal of Engineering and Applied Sciences, 12(Specialissue6), 7800–7804. DOI: 10.3923/jeasci.2017.7800.7804
• 5. Diao, J., Song, X., PENG, Z. H., Wang, Y., 2006. Compatibilization effects of a hyperbranched polymer on acrylonitrile-butadiene-styrene/poly (vinylchloride) blends. Iranian Polymer Journal (English), 15(11), 863–870.
• 6. Flory, P. J., 1952. Molecular size distribution in three dimensional polymers. VI. Branched polymers containing A—R—Bf-1 type units. Journal of the American Chemical Society, 74(11), 2718–2723.10.1021/ja01131a008
• 7. Gao, C., Yan, D., 2004. Hyperbranched polymers: From synthesis to applications. Progress in Polymer Science (Oxford), 29(3), 183–275. DOI: 10.1016/j.progpolymsci.2003.12.002
• 8. Higashihara, T., Segawa, Y., Sinananwanich, W., Ueda, M., 2012. Synthesis of hyperbranched polymers with controlled degree of branching. Polymer Journal, 44(1), 14–29. DOI: 10.1038/pj.2011.99
• 9. Hobson, L.J., Harrison, R.M., 1997. Dendritic and hyperbranched polymers: advances in synthesis and applications. Current Opinion in Solid State and Materials Science, 2(6), 683–692.10.1016/S1359-0286(97)80010-1
• 10. Inoue, K., 2000. Functional dendrimers, hyperbranched and star polymers. Progress in Polymer Science, 25(4), 453–571.10.1016/S0079-6700(00)00011-3
• 11. Ishida, Y., Jikei, M., Kakimoto, M.A., 2000. Synthesis of hyperbranched aromatic polyesters by carbon monoxide insertion reaction using palladium catalyst. Polymers for Advanced Technologies, 11(8–12), 698–704. DOI: 10.1002/1099-1581(200008/12)11:8/12<698::AID-PAT22>3.0.CO;2-W
• 12. Jikei, M., Kakimoto, M., 2001. Hyperbranched polymers: a promising new class of materials. Progress in Polymer Science, 26(8), 1233–1285.10.1016/S0079-6700(01)00018-1
• 13. Kim, Y.H., Webster, O.W., 1990. Water soluble hyperbranched polyphenylene:” a unimolecular micelle?”. Journal of the American Chemical Society, 112(11), 4592–4593.10.1021/ja00167a094
• 14. Kricheldorf, H.R., Zang, Q.Z., Schwarz, G., 1982. New polymer syntheses: 6. Linear and branched poly (3-hydroxy-benzoates). Polymer, 23(12), 1821–1829.10.1016/0032-3861(82)90128-8
• 15. Mohammad, F., 2007. Specialty polymers: materials and applications. IK International Pvt Ltd.
• 16. Mulkern, T.J., Tan, N.C.B., 2000. Processing and characterization of reactive polystyrene/hyperbranched polyester blends. Polymer, 41(9), 3193–3203.10.1016/S0032-3861(99)00543-1
• 17. Tatiya, P.D., Nevare, M.R., Mahulikar, P.P., Gite, V.V., 2014. Melt processing and characterization of nanocomposites of PP/Na+ MMT blending with hyperbranched polyester. Polymer-Plastics Technology and Engineering, 53(9), 941–951.10.1080/03602559.2014.886064
• 18. Tomalia, D.A., Fréchet, J.M.J., 2002. Discovery of dendrimers and dendritic polymers: a brief historical perspective. Journal of Polymer Science Part A: Polymer Chemistry, 40(16), 2719–2728.
• 19. Wågberg, L., Ondaral, S., Enarsson, L.E., 2007. Hyperbranched polymers as a fixing agent for dissolved and colloidal substances on fiber and SiO2 surfaces. Industrial & Engineering Chemistry Research, 46(7), 2212–2219.10.1021/ie061108b
• 20. Yiyun, C., Dazhu, C., Rongqiang, F., Pingsheng, H., 2005. Behavior of polyamidoamine dendrimers as curing agents in bis-phenol A epoxy resin systems. Polymer International, 54(3), 495–499.10.1002/pi.1748
• 21. Yue, L., Cao, Y., Huang, T., Huang, L., Bai, Y., Zhou, Y., 2013. Synthesis of aromatic hyperbranched polyester (HBPE) and its use as a nonmigrating plasticiser. Australian Journal of Chemistry, 67(1), 22–30.10.1071/CH13195
• 22. Zhang, D., Jia, D., Zhou, Z., 2009. Synthesis and characterization of low viscosity aromatic hyperbranched polyester epoxy resin. Macromolecular Research, 17(5), 289–295. https://doi.org/10.1007/BF0321886410.1007/BF03218864

Uwagi

Opracowanie rekordu ze środków MEiN, umowa nr SONP/SP/546092/2022 w ramach programu "Społeczna odpowiedzialność nauki" - moduł: Popularyzacja nauki i promocja sportu (2022-2023).