Reforming parowy glicerolu na katalizatorach Ni-Re/α-Al₂O₃

• Autorzy: Cichy M. , Borowiecki T.

Warianty tytułu

EN

Glycerol steam reforming over Ni-Re/α -Al₂O₃ catalysts

• Języki publikacji: PL EN

Abstrakty

PL

W reakcji transestryfikacji otrzymywania tzw. biodiesla powstają duże ilości odpadowej frakcji glicerynowej. Jednym z możliwych sposobów jej zagospodarowania jest konwersja do gazów syntezowych. Zbadano możliwość wykorzystania katalizatorów niklowych modyfikowanych renem w reakcji reformingu parowego glicerolu. Katalizatory te okazały się aktywne i stabilne w procesie reformingu parowego metanu oraz reformingu metanu z dwutlenkiem węgla. Zawartość renu w katalizatorach wynosiła maksymalnie 4% wag., temperatura reakcji mieściła się w zakresie 650–800°C, a stosunek molowy pary do węgla w mieszaninie glicerol-woda wynosił S/C = 3. Dodatek renu wpłynął pozytywnie na właściwości katalizatora, takie jak aktywność w konwersji glicerolu i produkcja wodoru. Najbardziej obiecujące wyniki uzyskano dla układu zawierającego 1% wag. Re. Wykazano, że katalizatory Ni-Re mogą być użyteczne w produkcji gazu syntezowego o wysokim stosunku CO:H₂.

EN

Large amount of glycerol waste fraction is still produced during biodiesel synthesis through the transesterification reaction. One of possible ways of its utilization seems to be conversion to synthesis gas. A steam reforming of glycerol on the rhenium doped nickel catalysts, supported on the commercial alumina oxide, was evaluated. The catalysts previously show good activity and stability in the methane steam reforming and CO₂ methane reforming. Rhenium content was changed up to 4 wt.%, temperatures range of the reforming reaction was 650-800°C with S/C = 3. Rhenium addition show significant influence on catalysts properties, such as activity in glycerol conversion and hydrogen production. The most promising results were obtained for Ni/Al₂O₃ catalyst with 1 wt.% rhenium addition. Ni-Re catalyst proved to be useful in syngas generation with high CO: H₂ ratio.

Słowa kluczowe

PL

glicerol; reforming parowy; katalizatory Ni-Re; gaz syntezowy

EN

glycerol; steam reforming; Ni-Re catalysts; syngas

• Wydawca: Stowarzyszenie Inżynierów i Techników Przemysłu Chemicznego, ZW CHEMPRESS-SITPChem
• Czasopismo: Chemik
• Rocznik: 2016
• Tom: Vol. 70, nr 5
• Strony: 261--269
• Opis fizyczny: Bibliogr. 49 poz., rys., tab.

Twórcy

autor

Cichy M.

• Zakład Technologii Chemicznej, Wydział Chemii, Uniwersytet Marii Curie-Skłodowskiej, Lublin

autor

Borowiecki T.

• Zakład Technologii Chemicznej, Wydział Chemii, Uniwersytet Marii Curie-Skłodowskiej, Lublin

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Uwagi

Opracowanie ze środków MNiSW w ramach umowy 812/P-DUN/2016 na działalność upowszechniającą naukę.