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In this work, a novel process of pellet non-salt roasting and H2SO4 leaching was proposed for the selective extraction of vanadium from vanadium–titanium magnetite concentrate. Vanadium can be leached but the iron impurity was maintained in the pellets. Moreover, the leached pellets can meet the quality requirements of the iron-making process after secondary roasting, realizing comprehensive utilization. The maximal vanadium leaching efficiency was up to 60.3%, whereas 0.17% of the iron impurity was leached. The optimum conditions of pellet roasting and leaching were obtained by single-factor experiments. The X-ray diffraction and scanning electron microscopy–energy disperse X-ray spectrometry analyses showed that the vanadium iron spinel can be oxidized and decomposed into Fe2O3 and vanadate during the roasting process. Given that dilute sulfuric acid can react with vanadate without reacting with Fe2O3 in the leaching process, selective vanadium extraction was realized. This work provides new insights into the industrial production of vanadium–titanium magnetite concentrate involving the direct extraction of vanadium.
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36--47
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Bibliogr. 21 poz., rys. kolor.
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- National Engineering Laboratory of Biohydrometallurgy, GRINM Group Corporation Limited. Beijing 101407, China GRINM Resources and Environment Tech. Co., Ltd. Beijing 101407, China General Research Institute for Nonferrous Metals. Beijing 100088, China
autor
- National Engineering Laboratory of Biohydrometallurgy, GRINM Group Corporation Limited. Beijing 101407, China GRINM Resources and Environment Tech. Co., Ltd. Beijing 101407, China General Research Institute for Nonferrous Metals. Beijing 100088, China
autor
- National Engineering Laboratory of Biohydrometallurgy, GRINM Group Corporation Limited. Beijing 101407, China GRINM Resources and Environment Tech. Co., Ltd. Beijing 101407, China General Research Institute for Nonferrous Metals. Beijing 100088, China
autor
- National Engineering Laboratory of Biohydrometallurgy, GRINM Group Corporation Limited. Beijing 101407, China GRINM Resources and Environment Tech. Co., Ltd. Beijing 101407, China General Research Institute for Nonferrous Metals. Beijing 100088, China
autor
- National Engineering Laboratory of Biohydrometallurgy, GRINM Group Corporation Limited. Beijing 101407, China GRINM Resources and Environment Tech. Co., Ltd. Beijing 101407, China General Research Institute for Nonferrous Metals. Beijing 100088, China
Bibliografia
- CHEN, D.S., ZHAO, H.X., HU, G.P., QI, T., YU, H.D., ZHANG, G.Z., WANG, L.N., WANG, W.J., 2015. An extraction process to recover vanadium from low-grade vanadium-bearing titanomagnetite. J.Hazard.Mater., 294, 35-40.
- CHEN, D.S., ZHAO, L.S., LIU, Y.H., QI, T., WANG, J.C., WANG, L.N., 2013. A novel process for recovery of iron, titanium, and vanadium from titanomagnetite concentrates: NaOH molten salt roasting and water leaching processes. J.Hazard.Mater., 244-245, 588-595.
- GILLIGAN, R., NIKOLOSKI, A.N., 2020. The extraction of vanadium from titanomagnetites and other sources. Miner.Eng., 146, 106106.
- GUO, Y., LI, H.Y., SHEN, S., WANG, C.J., XIE, B., 2020. Recovery of vanadium from vanadium slag with high phosphorus content via recyclable microemulsion extraction. Hydrometallurgy, 198, 105509.
- HU, P.C., ZHANG, Y.M., LIU, T., HUANG, J., YUAN, Y., ZHENG, Q., 2017. Highly selective separation of vanadium over iron from stone coal by oxalic acid leaching. J.Ind.Eng.Chem., 45, 241-247.
- HU, P.C., ZHANG, Y.M., LIU, T., HAUNG, J., YUAN, Y.Z., XUE, N.N., 2018. Source separation of vanadium over iron from roasted vanadium-bearing shale during acid leaching via ferric fluoride surface coating. J.Clean Prod., 181, 399-407.
- JI, Y.L., SHEN, S.B., LIU, J.H., XUE, Y., 2017. Cleaner and effective process for extracting vanadium from vanadium slag by using an innovative three-phase roasting reaction. J.Clean Prod., 149, 1068-1078.
- KUL, M., OSKAY, K.O., SIMSIR, M., SUBUTAY, H., KIRGEZEN, H., 2015. Optimization of selective leaching of Zn from electric arc furnace steelmaking dust using response surface methodology. Trans. Nonferrous Met. Soc. China, 25, 2753-2762.
- LI, H.Y., FANG, H.X., WANG, K., ZHOU, W.,YANG, Z., YAN, X.M., 2015. Asynchronous extraction of vanadium and chromium from vanadium slag by stepwise sodium roasting–water leaching. Hydrometallurgy, 156, 124-135.
- LI, M., LIU, B., ZHENG, S., WANG, S., DU, H., Dreisinger, D.B., Zhang, Y., 2017. A cleaner vanadium extraction method featuring non-salt roasting and ammonium bicarbonate leaching. J.Clean Prod., 149, 206-217.
- LI, R.M., LIU, T., ZHANG, Y.M., HHAUNG, J., XU, C.B., 2018. Efficient Extraction of Vanadium from Vanadium–Titanium Magnetite Concentrate by Potassium Salt Roasting Additives. Minerals, 8(1), 25-39.
- LIU, Z.S., HUANG, J., ZANG, Y.M., HU, P.C., LIU, H., ZHENG, Q.S., 2020. Separation and recovery of iron impurities from a complex oxalic acid solution containing vanadium by K3Fe (C2O4)3• 3H2O crystallization. Sep.Purif.Technol., 232, 115970.
- LIU, S., DING, E., NING, P., XIE, G., YANG, N., 2021. Vanadium extraction from roasted vanadium-bearing steel slag via pressure acid leaching.J. Environ. Chem. Eng.,9(3), 105195.
- LUO, Y., CHE, X.K., CUI, X.L., ZHENG, Q., WANG, L., 2021. Selective leaching of vanadium from V-Ti magnetite concentrates by pellet calcification roasting-H2SO4leaching process. Int. J. Min. Sci. Technol., https://doi.org/10.1016/j.ijmst.2021.02.002.
- MIRAZIMI, S., RASHCHI, F., SABA, M., 2013. Vanadium removal from roasted LD converter slag: Optimization of parameters by response surface methodology (RSM). Sep.Purif.Technol., 116, 175-183.
- NING, L,F., HE, D.W., CHEN, W., ZHOU, K.G., 2019. Sulfuric acid leaching and kinetics study for separation of iron and scandium from red mud. Mini.Metall. Eng., 39, 81-84.
- WANG, L., 2011. The study on direct extracting vanadium from vanadium-titanium magnitite concentrate. Northeastern University.
- WANG, Z.H., CHEN, L., ALDAHRIB, T., LI, C., LIU, W.Z., ZHANG, G.Q., YANG, Y.H., LUO, D.M., 2020.Direct recovery of low valence vanadium from vanadium slag -Effect of roasting on vanadium leaching. Hydrometallurgy, 191, 105156.
- XUE, N.N., ZHANG, Y.M., HAUNG, J., LIU, T., WANG, L.Y., 2017. Separation of impurities aluminum and iron during pressure acid leaching of vanadium from stone coal. J.Clean Prod., 166, 1265-1273.
- ZHENG, H.Y., ZHANG, W.L., GUO, Y.C., GAO, Q.J., SEHN, F.M., 2019. Transformation of Vanadium-Bearing Titanomagnetite Concentrate in Additive-Free Roasting and Alkaline-Pressure Leaching for Extracting Vanadium (V). Minerals, 9(3), 197.
- ZHU, X.B., LI, W., GUAN, X.M., 2016. Vanadium extraction from titano-magnetite by hydrofluoric acid. Int.J.Miner.Process., 157, 55-59.
Typ dokumentu
Bibliografia
Identyfikator YADDA
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