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In this study European ash wood (Fraxinus excelsior L.) was modified at 192ºC and 202ºC in Thermo-Drewno®, Poland; and at 212ºC in Termogenik®, Spain. After modification, samples were characterized by wet chemistry according to standard methods (TAPPI) and by instrumental methods (FT-IR); in addition, surface and physical properties were measured (density, acidity, moisture, water uptake, contact angle, colour) in order to quantify changes due to treatment and temperature. The results showed that chemical composition of modified wood presents a gradual variation according to the heating regime, regardless of the industrial process applied; the greatest differences were obtained in treatment at 212°C compared to untreated wood. Furthermore, the density (< 0.68 g·cm-3) of modified wood decreased proportionally to treatment temperature. Colour measurements showed proportional changes to darker colours depending on the treatment temperature. On the other hand, some physical properties did not vary significantly between treatments, obtaining similar values of contact angle (97°-99°) and of moisture content (<7%).
Słowa kluczowe
Rocznik
Tom
Strony
151--164
Opis fizyczny
Bibliogr. 40 poz., rys., tab.
Twórcy
autor
- University of the Basque Country UPV/EHU, San Sebastian, Spain
autor
- Poznan University of Life Sciences, Poznan, Poland
autor
- University of the Basque Country UPV/EHU, San Sebastian, Spain
autor
- University of the Basque Country UPV/EHU, San Sebastian, Spain
Bibliografia
- Akerholm M., Hinterstoisser B., Salmén L. [2004]: Characterization of the crystalline structure of cellulose using static and dynamic FT-IR spectroscopy. Carbohydrate research 339 [3]: 569-578
- Aksoy A., Devici M., Baysal E., Toker H. [2011]: Color and gloss changes of scots pine after heat modification. Wood Research 56 [3]: 329-336
- Bekhta P., Proszyk S., Lis B., Krystofiak T. [2014]: Gloss of thermally densified alder (Alnus glutinosa Goertn.), beech (Fagus sylvatica L.), birch (Betula verrucosa Ehrh.), and pine (Pinus sylvestris L.) wood veneers. Holz als Roh u. Werkstoff. 72 [6]: 799-808
- Boonstra M.J., Tjeerdsma B. [2006]: Chemical analysis of heat-treated softwoods. Holz als Roh- und Werkstoff 64: 204-211
- Boonstra M.J., Van Acker J., Tjeerdsma B.F., Kegel E. [2007]: Strength properties of thermally modified softwoods and its relation to polymeric structural wood constituents. Annals of Forest Science 64: 679-690
- Brischke C., Rapp A.O. [2006]: Decay influencing factors: A basis for service life prediction of wood and wood-based products. Wood Material Science and Engineering 2: 91-107
- Cao J., Kamdem P.D. [2007]: Surface energy of preservative-treated southern yellow pine (Pinus spp.) by contact angle measurement. Frontiers of Forestry in China 2(1): 99-103
- Carvalheiro F., Duarte L.C., Gírio F.M. [2008]: Hemicellulose biorefineries: a review on biomass pretreatments. Journal of Scientific and Industrial Research 67: 849-864
- Esteves B., Pereira H. [2008a]: Wood modification by heat treatment: A review. BioResources 4 [1]: 370-404
- Esteves B., Graça J., Pereira H. [2008b]: Extractive composition and summative chemical analysis of thermally treated eucalypt wood. Holzforschung 62: 344-351
- Esteves B., Velez Marques A., Domingos I., Pereira H. [2013]: Chemical changes of heat treated pine and eucalyptus wood monitored by FTIR. Maderas: ciencia y tecnologia 15 [2]: 245-258
- Epmeier H., Westin M., Rapp A. [2004]: Differently modified wood: Comparison of some selected properties. Scandinavian Journal of Forest Research 19 [5]: 31-37
- Gérardin P., Petric M., Petrissans M., Lambert J., Ehrhrardt J.J. [2007]: Evolution of wood surface free energy after heat treatment. Polymer degradation and stability 92 [4]: 653-657
- Gindl M., Tschegg S. [2002]: Significance of the acidity of wood to the surface free energy components of different wood species. Langmuir 18: 3209-3212
- Hakkou M., Petrissans M., Zoulalian A., Gerardin P. [2005]: Investigation of the reasons for the increase of wood durability after heat treatment based on changes of wettability and chemical composition. In: Proceedings of the second European conference on wood modification ECWM: 38-46
- Herrera R., Erdocia X., Llano-Ponte R., Labidi J. [2014]: Characterization of hydrothermally treated wood in relation to changes on its chemical composition and physical properties. Journal of analytical and Applied Pyrolysis 107: 256-266
- Hochmanska P., Mazela B., Krystofiak T. [2014]: Hydrophobicity and weathering resistance of wood treated with silane-modified protective systems. Drewno 57 [191]: 99-110
- Junghans K., Niemz P., Bächle F. [2005]: Untersuchungen zum Einf luss der thermischen. Vergütung auf die Porosität von Fichtenholz. Holz als Roh- und Werkstoff 63: 243-244
- Kocaefe D., Poncsak S., Boluk Y. [2008]: Effect of thermal treatment on the chemical composition and mechanical properties of birch and aspen. Bioresources 3[2]: 517-537
- Korkut D.S., Hiziroglu S., Aytin A. [2012]: Effect of heat treatment on surface characteristics wild cherry wood. Bioresources 8 [2]: 1582-1590
- Kutnar A., Kričej B., Pavlič M., Petrič, M. [2013]: Influence of treatment temperature on wettability of Norway spruce thermally modified in vacuum. Journal of adhesion science and technology 27 [9]: 963-972
- Matsuda H. [1987]: Preparation and utilization of esterified woods bearing carboxyl groups. Wood Science Technology 21: 75-88
- Militz H. [2002]: Thermal treatment of wood: European Processes and their background. Document No. IRG/WP/02-40241. International Research Group on Wood Protection, Stockholm, Sweden
- Pandey K.K., Pitman A.J. [2003]: FTIR studies of the changes in wood chemistry following decay by brown-rot and white-rot fungi. International Biodeterioration and Biodegradation 52: 151-160
- Piao C., Winandy J.E., Shupe T.F. [2010]: From hydrophilicity to hydrophobicity: a critical review: part I wettability and surface behavior. Wood and Fiber Science 42: 490-510
- Popescu M. C., Popescu C. M., Lisa G., Sakata Y. [2011]: Evaluation of morphological and chemical aspects of different wood species by spectroscopy and thermal methods. Journal of Molecular Structure 988: 65-72
- Rowell R. [1984]: The chemistry of solid wood. Advances in chemistry series. American Chemical Society, Washington, DC, 1983
- Shen D.K., Gu S., Bridgwater A.V. [2010]: The thermal performance of the polysaccharides extracted from hardwood: Cellulose and hemicellulose. Carbohydrate Polymers 82 [1]: 39-45
- Tjeerdsma B.F., Militz H. [2005]: Chemical changes in hydrothermal treated wood: FTIR analysis of combined hydrothermal and dry heat treated wood. Holz als Roh- und Werkstoff 63 [1]: 102-111
- Choi J.W., Choi D.H., Faix O. [2007]: Characterization of lignin-carbohydrate linkages in the residual lignins isolated from chemical pulps of spruce (Picea abies) and beech wood (Fagus sylvatica). Journal of Wood Sciences 53: 309-313
- Welzbacher R.C., Rapp A.O. [2007]: Durability of thermally modified timber from industrial-scale processes in different use classes: Results from laboratory and field tests. Wood Material Science and Engineering 2 [1]: 4-14
- Wiedenhoeft A.C., Miller R.B. [2005]: Structure and Function of Wood. Handbook of wood chemistry and wood composites: 9-32
- Wikberg H., Maunu S. [2004]: Characterisation of thermally modified hard- and softwoods by 13C CPMAS NMR. Carbohydrate Polymers 58: 461-466
- Willems W. [2014]: The water vapor sorption mechanism and its hysteresis in wood: the water/void mixture postulate. Wood Science and Technology 48 [3]: 499-518
- Windeisen E., Strobel C., Wegener G. [2007]: Chemical changes during the production of thermo treated beech wood. Wood Science and Technology 41 [6]: 523-536
- Wise L.E., Murphy M., D'Addieco A.A. [1946]: Chlorite holocellulose, its fractionation and bearing on summative wood analysis and studies on the hemicelluloses. Paper Trade Journal 122: 35-43
- Yildiz U., Gercek Z., Gezer E., Serdar B., Yildiz S., Gezer E.D., Dizman E., Temiz A. [2004]: The effects of heat treatment on anatomical changes of beechwood. International Research Group on Wood Preservation Document No.IRG/WP/02-40223
- List of standards
- TAPPI T211 om-12 – Ash in wood, pulp, paper and paperboard: combustion at 525°
- TAPPI T264 cm-07 – Preparation of wood for chemical analysis
- TAPPI T222 om-02 – Acid-insoluble lignin in wood and Pulp
Uwagi
Opracowanie ze środków MNiSW w ramach umowy 812/P-DUN/2016 na działalność upowszechniającą naukę.
Typ dokumentu
Bibliografia
Identyfikator YADDA
bwmeta1.element.baztech-a174b56b-66c5-4051-a958-44bb3b004305