Wpływ surfaktantów na właściwości adsorpcyjne substancji organicznych i jonów metali ciężkich w układach koloidalnych

• Autorzy: Chibowski Stanisław , Wiśniewska Małgorzata

Identyfikatory

DOI

10.53584/wiadchem.2021.10.2

Warianty tytułu

EN

Effect of surfactants on the adsorption properties of organic substances and heavy metal ions in colloidal systems

• Języki publikacji: EN

Abstrakty

EN

The main purpose of this paper is description of the mechanisms governing the adsorption process of organic substances (such as polymers and dyes soluble in water) and inorganic substances (i.e. heavy metal ions) on the solid surface in the presence of synthetic surfactants of various ionic nature (anionic SDS, cationic CTAB and nonionic Triton X-100). The following polymers were applied: polyacrylamide, poly(ethylene glycol), poly(vinyl alcohol) and poly(acrylic acid). Moreover, the mono-, di- and triazo dyes with acidic, reactive and direct characters were used. Metal oxides – both simple (alumina, zirconia, titania) and mixed (double: silica-alumina, silica-titania and triple: alumina-silica-titania), as well as activated carbons obtained from biomass and peat were applied in the role of adsorbents. The effects of solution pH, ionic character of adsorbate, its molecular weight, elemental composition of the solid, its acid-base properties and textural structure, were determined. The understanding of the phenomena occuring at this type of interface is extremaly important for the effective control of colloidal suspensions stability, which is essential for practical applications. The formation of mixed adsorption layers composed of polymer-surfactant, dye-surfactant or polymer-surfactant-metal ion complexes results in many cases in a significant modification of the surface properties of solids, which is manifested not only by the changes in amount of bound adsorbate, but also by the changes in the structure of electrical double layer. The analysis of the obtained results indicated two main mechanisms of the surfactants influence on the adsorption process of organic and inorganic substances in colloidal systems containing a highly dispersed solid. The first one is the formation of polymer-surfactant, dye-surfactant or polymer-surfactant-metal complexes through both hydrophobic and electrostatic interactions, which show different affinity to the adsorbent surface. In most of the examined systems, these complexes were effectively bound at the solid-liquidinterface, which resulted in the adsorption increase of polymer, dye and heavy metal ions. The second important mechanism is the competition of surfactant molecules and other adsorbates for the active sites of the solid surface (the components of mixed adsorbates had the same ionic character). As a result of these two processes, mixed adsorption layers with a specific structure were formed, which determined the stability of the colloidal suspension.

Słowa kluczowe

EN

competitive adsorption; surfactant; dyes removal; polymer-surfactant complexes; suspension stability; electrical double layer

PL

adsorpcja konkurencyjna; surfaktant; usuwanie barwników; kompleksy polimer-surfaktant; stabilność suspensji; podwójna warstwa elektryczna

• Wydawca: Polskie Towarzystwo Chemiczne
• Czasopismo: Wiadomości Chemiczne
• Rocznik: 2021
• Tom: [Z] 75, 9-10
• Strony: 1181--1202
• Opis fizyczny: Bibliogr. 43 poz., rys., schem., tab., wykr.

Twórcy

autor

Chibowski Stanisław

• Katedra Radiochemii i Chemii Środowiskowej, Instytut Nauk Chemicznych, Wydział Chemii, Uniwersytet Marii Curie-Skłodowskiej w Lublinie, Pl. Marii Curie-Skłodowskiej 3, 20-031 Lublin

• https://orcid.org/0000-0002-3549-0172

autor

Wiśniewska Małgorzata

• Katedra Radiochemii i Chemii Środowiskowej, Instytut Nauk Chemicznych, Wydział Chemii, Uniwersytet Marii Curie-Skłodowskiej w Lublinie, Pl. Marii Curie-Skłodowskiej 3, 20-031 Lublin

• https://orcid.org//0000-0003-4003-9877

Bibliografia

• [1] S. Farrokhpay, G. Morris, D. Fornasiero, P. Self, Prog. Colloid Polym. Sci., 2004, 128, 216.
• [2] H.T. Chen, S.A. Ravishankar, R.S. Farinato, Int. J. Min. Proc., 2003, 72, 75.
• [3] R.E. Sojka, D.L. Bjorneberg, J.A. Entry, R.D. Lentz, W.J. Orts, Adv. Agronomy., 2007, 92, 75.
• [4] A.K. Bajpai, S.K. Shukla, S. Bhanu, S. Kankane, Prog. Polym. Sci., 2008, 33, 1088.
• [5] W. Brostow, H.E. Lobland, S. Pal, R.P. Singh, J. Mat. Educ., 2009, 31, 157.
• [6] T. Jesionowski, J. Mater. Sci., 2002, 37, 5275.
• [7] T.F. Tadros, Polymeric Surfactants: Dispersion Stability and Industrial Applications, De Gruyter, Berlin, 2017.
• [8] A. Zdziennicka, B. Jańczuk, Adv. Colloid Interf. Sci., 2020, 284, 102249.
• [9] A. Zdziennicka, B. Jańczuk, J. Molec. Liq., 2017, 243C, 236.
• [10] A. Pawlowska, Z. Sadowski, Microorganisms, 2020, 8, 1725.
• [11] G. Para, J. Łuczyński, J. Palus, J. Jarek, K.A. Wilk, P. Warszyński, J. Colloid Interf. Sci., 2016, 465, 174.
• [12] R. Nagarajan, Polymer-surfactant interactions. In: New horizons: detergents for the new millennium conference invited papers, American Oil Chemists Society and Consumer Specialty Products Association, Fort Myers, Florida, 2001.
• [13] A. Bastrzyk, I. Polowczyk, E. Szeląg, Z. Sadowski, Phys. Prob. Min. Proc., 2008, 42, 261.
• [14] T. Tripathy, B.R. De, J. Phys. Sci., 2006, 19, 93.
• [15] M.E. Jimenez-Castaneda, D.I. Medina, Water, 2017, 9, 235.
• [16] N.A. Negm, H. E. Ali, Eng. Life Sci. 2010, 10, 218.
• [17] L. Shen, X-T Nguyen, N.P. Hankins, Sep. Purif. Tech., 2015, 152, 101.
• [18] L. Liu, W. Li, W. Song, M. Guo, Sci. Total Env., 2018, 633, 206.
• [19] K.S. Palansooriya, S.M. Shaheen, S.S. Chen, D.C.W. Tsang, Y. Hashimoto, D. Houg, N.S. Bolan, J. Rinklebe, Y.S. Ok, Env. Internat., 2020, 134, 105046.
• [20] J. Singh, A.S. Kalamdhad, Internat. J. Res. Chem. Env., 2011, 1, 15.
• [21] B. Cabane, in K.L. Mittal and E. J. Fendler, Editors, Solution Behavior of Surfactants, Vol. 1, Plenum Press, New York, 1982.
• [22] R. Atkin, V.S.J. Craig, S. Biggs, Langmuir, 2000, 16, 9374.
• [23] A. Garcia-Prieto, L. Lunar, S. Rubio, D. Pérez-Bendito, Analyst, 2006, 131, 407.
• [24] J.C.T. Kwak, Polymer–Surfactant Systems, Marcel Dekker, New York, 1998.
• [25] E. Barni, P. Savarino, G. Viscardi, Acc. Chem. Res.,1991, 24, 98.
• [26] M. Bielska, A. Sobczyńska, K. Prochaska, Dyes Pigm., 2009, 80, 201.
• [27] K. Hąc-Wydro, A. Mateja, A. Ożóg, P. Miśkowiec, J. Molec. Liq., 2017, 240, 514.
• [28] M. Wiśniewska, S. Chibowski, T. Urban, Appl. Surf. Sci., 2016, 370, 351.
• [29] M. Wiśniewska, S. Chibowski, T. Urban, Powder Tech., 2016, 302, 357.
• [30] S. Chibowski, M. Paszkiewicz, M. Wiśniewska, Ads. Sci. Tech., 2002, 20, 573.
• [31] S. Chibowski, M. Paszkiewicz, J. Patkowski, Physicochem. Probl. Miner. Process., 2012, 48, 317.
• [32] M. Wiśniewska, M. Wawrzkiewicz, A. Wołowicz, O. Goncharuk, Springer Proceedings in Physics: Nanooptics, Nanophotonics, Nanomaterials, and Their Applications, 2018, 210, Chapter 8, 103.
• [33] M. Wawrzkiewicz, M. Wiśniewska, V.M. Gun’ko, V.I. Zarko, Powder Tech., 2015, 278, 306.
• [34] M. Wawrzkiewicz, M. Wiśniewska, V.M. Gun’ko, Ads. Sci. Tech., 2017, 35, 448.
• [35] M. Wawrzkiewicz, M. Wiśniewska, A. Wołowicz, V.M. Gun’ko, V.I. Zarko, Micropor. Mesopor. Mat., 2017, 250, 128.
• [36] M. Wiśniewska, M. Wawrzkiewicz, E. Polska-Adach, G. Fijałkowska, O. Goncharuk, Appl. Nanosci., 2018, 8, 867.
• [37] M. Wawrzkiewicz, E. Polska-Adach, M. Wiśniewska, G. Fijałkowska, O. Goncharuk, The Europ. Phys. J. Plus, 2019, 134, 108.
• [38] S. Chibowski, M. Wiśniewska, M. Wawrzkiewicz, Z. Hubicki, O. Goncharuk, Physicochem. Probl. Miner. Process., 2020, 56, 6.
• [39] M. Wiśniewska, K. Wrzesińska, M. Wawrzkiewicz, S. Chibowski, T. Urban, O. Goncharuk, V. M. Gun’ko, Physicochem. Probl. Miner. Process., 2020, 56, 178.
• [40] M. Wiśniewska, P. Nowicki, Colloids Surf. A, 2020, 585, 124179.
• [41] D. Sternik, M. Wiśniewska, P. Nowicki, Thermochim. Acta, 2019, 676, 71.
• [42] M. Wiśniewska, P. Nowicki, T. Urban, J. Molec. Liq., 2021, 332, 115872.
• [43] M. Wiśniewska, P. Nowicki, K. Szewczuk-Karpisz, M. Gęca, K. Jędruchniewicz, P. Oleszczuk, Sep. Purif. Tech., 2021, w druku.

Uwagi

Opracowanie rekordu ze środków MNiSW, umowa Nr 461252 w ramach programu "Społeczna odpowiedzialność nauki" - moduł: Popularyzacja nauki i promocja sportu (2021).