Kinetics of electrooxidation of phenol on polycrystalline platinum

• Autorzy: Pierożyński B. , Piotrowska G. , Mikołajczyk T.

Identyfikatory

DOI

10.1515/pjct-2015-0040

• Języki publikacji: EN

Abstrakty

EN

This work reports on kinetics of phenol electrooxidation reaction (PhER), examined at polycrystalline Pt electrode in 0.5 M H₂SO₄ and 0.1 M NaOH supporting solutions. Important aspects of PhER kinetics were analysed based on potential-dependent, a.c. impedance-derived values of charge-transfer resistance and capacitance parameters. Special attention was also given to the influence of supporting electrolyte ions on the process of phenol oxidation (pH dependence of the PhER), in relation to an important role of anion adsorption on the Pt catalyst surface.

Słowa kluczowe

EN

Phenol electrooxidation; PhER; polycrystalline Pt; electrochemical impedance spectroscopy

• Wydawca: West Pomeranian University of Technology. Publishing House
• Czasopismo: Polish Journal of Chemical Technology
• Rocznik: 2015
• Tom: Vol. 17, nr 2
• Strony: 126--130
• Opis fizyczny: Bibliogr. 17 poz., rys., tab., wz.

Twórcy

autor

Pierożyński B.

• University of Warmia and Mazury in Olsztyn, Department of Chemistry, Faculty of Environmental Management and Agriculture, Plac Łódzki 4, 10-957 Olsztyn, Poland

autor

Piotrowska G.

• University of Warmia and Mazury in Olsztyn, Department of Chemistry, Faculty of Environmental Management and Agriculture, Plac Łódzki 4, 10-957 Olsztyn, Poland

autor

Mikołajczyk T.

• University of Warmia and Mazury in Olsztyn, Department of Chemistry, Faculty of Environmental Management and Agriculture, Plac Łódzki 4, 10-957 Olsztyn, Poland

Bibliografia

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