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Effect of the Addition of Extractives on The Reduction Of Vocs Emissions from Lacquers in the liquid state

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Języki publikacji
EN
Abstrakty
EN
The aim of this study was to determine the effect of the addition of extractive substances on the VOC emission of lacquer products in the liquid state. Three water-soluble acrylic resin products were investigated using the stationary phase microextraction technique in combination with gas chromatography coupled with mass spectrometry (SPME-GC/MS). The extraction of volatile compounds was analysed at three temperatures: 22 ℃, 35 ℃ and 45 ℃. 20 μg of an extract obtained from the leaves, branches and bark of black cherry (Prunus serotina Erhr.) were added to commercial products. Flavonoids accounted for almost 75% of the total phenols in the used extract. The spectrum of volatile compounds emitted by the liquid coating products selected for the studies was examined before and after adding the extract to them. It was found that the addition of black cherry extract caused a significant reduction in the emissions of volatile compounds emitted by the researched products. The compounds, whose amounts did not decrease under the influence of the addition of the extract, were esters of propenoic acid. The applied extract was a source of emissions from an additional compound: benzaldehyde. The total VOC emissions of the investigated liquid coating products was reduced by 8-55% and depended on the extraction temperature. The paper also proposes the mechanism of chemical reactions between phenolics and VOC, which may cause the reduction in VOC emissions from lacquer products. The IBM RXN tool was utilised to find possible reactions.
Rocznik
Strony
Art. no. 1644--3985.437.04
Opis fizyczny
Bibliogr. 29 poz., rys., tab., wykr.
Twórcy
  • Department of Chemical Wood Technology, Poznan University of Life Sciences, Poznań, Poland
  • Department of Chemical Wood Technology, Poznan University of Life Sciences, Poznań, Poland
  • Department of Biochemistry and Biotechnology, Poznan University of Life Sciences, Poznan, Poland
  • Department of Chemical Wood Technology, Poznan University of Life Sciences, Poznań, Poland
Bibliografia
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  • Kefeli, V. I., Kalevitch, M. V., Borsari, B. [2003]. Phenolic cycle in plants and environment. J. Cell Mol. Biol, 2(1): 13-18.
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Typ dokumentu
Bibliografia
Identyfikator YADDA
bwmeta1.element.baztech-a0b06820-b9cb-4e48-a475-1baec3cc1fb4
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