Adsorption behavior of Zn(II) onto natural minerals in wastewater. A comparative study of bentonite and kaolinite

• Autorzy: Chai W. , Huang Y. , Su S. , Han G. , Liu J. , Cao Y.

Identyfikatory

DOI

10.5277/ppmp170122

• Języki publikacji: EN

Abstrakty

EN

In order to remove the harmful metal ions in lead-zinc mineral processing wastewater, two natural clay minerals (bentonite and kaolin) were used as adsorbents and Zn(II) ions were the emphasis in this work. The adsorption behaviors including kinetics and isotherms were investigated by batch experiments. In addition, the adsorption mechanisms were studied by means of zeta potential testing, optical microscope and XRD analysis. The results show that the adsorption process can be best described as the pseudo-second order kinetic model. The adsorption equilibrium data of bentonite and kaolinite can be respectively fitted best by Langmuir and Freundlich models. Thermodynamic studies display that the adsorption of Zn(II) onto clays is non-spontaneous and endothermic. The maximum capacity of Zn(II) adsorbed on bentonite and kaolinite respectively reaches to 79.2 mg·g-1 and 6.35 mg·g-1 at 25 °C. The structural differences of bentonite and kaolinite result in the differences in adsorption behavior and mechanism. The interaction mechanisms of Zn(II) with bentonite and kaolinite involve electrostatic attraction, cation exchange, surface complex and precipitation. Bentonite as adsorbent has the potential to remove Zn2+ better than kaolinite.

Słowa kluczowe

EN

adsorption; Zn(II); wastewater; clay minerals; structural properties

• Wydawca: Oficyna Wydawnicza Politechniki Wrocławskiej
• Czasopismo: Physicochemical Problems of Mineral Processing
• Rocznik: 2017
• Tom: Vol. 53, iss. 1
• Strony: 264--278
• Opis fizyczny: Bibliogr. 47 poz., rys., tab.

Twórcy

autor

Chai W.

• School of Chemical Engineering and Energy, Zhengzhou University, Zhengzhou, P.R. China

autor

Huang Y.

• School of Chemical Engineering and Energy, Zhengzhou University, Zhengzhou, P.R. China

autor

Su S.

• School of Chemical Engineering and Energy, Zhengzhou University, Zhengzhou, P.R. China

autor

Han G.

• School of Chemical Engineering and Energy, Zhengzhou University, Zhengzhou, P.R. China

autor

Liu J.

• School of Chemical Engineering and Energy, Zhengzhou University, Zhengzhou, P.R. China

autor

Cao Y.

• School of Chemical Engineering and Energy, Zhengzhou University, Zhengzhou, P.R. China

Bibliografia

• ALVAREZ-AYUSO E. and GARCIA-SANCHEZ A., 2003, Removal of heavy metals from waste waters by natural and Na-exchanged bentonites. Clay. Clay Miner. 51: 475-480.
• APRILE F. and LORANDI R., 2012. Evaluation of cation exchange capacity (CEC) in tropical soils using four different analytical methods. J. Agric. Sci. 4: 278–289.
• ARIAS F., SEN T.K., 2009, Removal of zinc metal ion (Zn2+) from its aqueous solution by kaolin clay mineral: A kinetic and equilibrium study. Colloids Surf., A 348: 100-108.
• BEREKET G., ARO A.Z. and OZEL M.Z., 1997, Removal of Pb(II), Cd(II), Cu(II), and Zn(II) from Aqueous Solutions by Adsorption on Bentonite. J. Colloid Interface Sci. 187: 338-43.
• BHATTACHARYYA K.G., GUPTA S.S., 2011, Removal of Cu(II) by natural and acid-activated clays: An insight of adsorption isotherm, kinetic and thermodynamics. Desalination 272: 66-75.
• BINGHAM F.T., PAGE A.L., SIMS J.R., 1964, Retention of cu and zn by H-Montmorillonite. Soil Sci. Soc. Am. J. 28: 351-354.
• BLANES P., CONG C., CORTADI A., FRASCAROLI M., GATTUSO M., GARCIA S., GONZÁLEZ J., HARADA M., MATULEWICZ C., NIWA Y., PRADO H., SALA L., 2011, Biosorption of trivalent chromium from aqueous solution by red seaweed polysiphonia nigrescens. J. Water Resour. Prot. 03: 832-843.
• CHAKIR A., BESSIERE J., KACEMI K.E., MAROUF B., 2002, A comparative study of the removal of trivalent chromium from aqueous solutions by bentonite and expanded perlite. J. Hazard. Mater. 95: 29-46.
• CHEN J., LIU R., SUN W., QIU G., 2009, Effect of mineral processing wastewater on flotation of sulfide minerals. T. Nonferr. Metal. Soc. 19: 454-457.
• CHEN Q., LUO Z., HILLS C., XUE G., TYRER M., 2009, Precipitation of heavy metals from wastewater using simulated flue gas: Sequent additions of fly ash, lime and carbon dioxide. Water Res. 43: 2605-2614.
• DUKIC A.B., KUMRIĆ K.R., VUKELIC N.S., DIMITRIJEVIC M.S., BASCAREVIC Z.D., KURKO S.V., MATOVIĆ L.L., 2015, Simultaneous removal of Pb2+, Cu2+, Zn2+ and Cd2+ from highly acidic solutions using mechanochemically synthesized montmorillonite-kaolinite/TiO2 composite. Appl. Clay Sci. 103: 20-27.
• EL-ASHTOUKHY E.S.Z., AMIN N.K., ABDELWAHAB O., 2008, Removal of lead (II) and copper (II) from aqueous solution using pomegranate peel as a new adsorbent. Desalination 223: 162-173.
• FU F., WANG Q., 2011, Removal of heavy metal ions from wastewaters: A review. J. Environ. Manage. 92: 407-418.
• FUTALAN C.M., KAN C., DALIDA M.L., HSIEN K., PASCUA C., WAN M., 2011, Comparative and competitive adsorption of copper, lead, and nickel using chitosan immobilized on bentonite. Carbohyd. Polym. 83: 528-536.
• GERENTE C., LEE V.K.C., CLOIREC P.L., MCKAY G., 2007, Application of chitosan for the removal of metals from wastewaters by adsorption-mechanisms and models review. Crit. Rev. Env. Sci. Tec. 37: 41-127.
• GU X., EVANS L.J., 2007, Modelling the adsorption of Cd(II), Cu(II), Ni(II), Pb(II), and Zn(II) onto Fithian illite. J. Colloid Interf. Sci. 307: 317-325.
• GU X., EVANS L.J., 2008, Surface complexation modelling of Cd(II), Cu(II), Ni(II), Pb(II) and Zn(II) adsorption onto kaolinite. Geochim. Cosmochim. Ac. 72: 267-276.
• GU X., EVANS L.J., BARABASH S.J., 2010, Modeling the adsorption of Cd (II), Cu (II), Ni (II), Pb (II) and Zn (II) onto montmorillonite. Geochim. Cosmochim. Ac. 74: 5718-5728.
• HUANG Y., HAN G., LIU J., WANG W., 2016, A facile disposal of Bayer red mud based on selective flocculation desliming with organic humics. J Hazard Mater, 301: 46-55.
• HUANG Y., HAN G., LIU J., CHAI W., WANG W., YANG S., SU S., 2016, A stepwise recovery of metals from hybrid cathodes of spent Li-ion batteries with leaching-flotation-precipitation process. J Power Sources, 325: 555-564
• KAYA A., OREN A.H., 2005, Adsorption of zinc from aqueous solutions to bentonite. J. Hazard. Mater. 125: 183-189.
• HUMPOLA P.D., ODETTI H.S., FERTITTA A.E., VICENTE J.L., 2013, Thermodynamic analysis of adsorption models of phenol in liquid phase on different activated carbons. J. Chil. Chem. Soc. 58: 1541-1544.
• JACKSON M., 1962. Soil Chemical Analysis. New York: Prentice-Hall Inc.
• JIANG M., JIN X., LU X., CHEN Z., 2010, Adsorption of Pb(II), Cd(II), Ni(II) and Cu(II) onto natural kaolinite clay. Desalination 252: 33-39.
• KAYA A., OREN A.H., 2005, Adsorption of zinc from aqueous solutions to bentonite. J. Hazard. Mater. 125: 183-189.
• KUBILAY S., GURKAN R., SAVRAN A. and SAHAN T., 2007, Removal of Cu(II), Zn(II) and Co(II) ions from aqueous solutions by adsorption onto natural bentonite. Adsorption 13: 41-51.
• LOLLINO G., GIORDAN D., THURO K., CARRANZA-TORRES C., WU F., MARINOS P., DELGADO C., YE W.M., HE Y., CHEN Y.G., CHEN B., CUI Y.J., 2015, Adsorption, Desorption and competitive adsorption of heavy metal ions from aqueous solution onto GMZ01 bentonite. Applied Geology for Major Engineering Projects. Springer International Publishing, 533-536.
• MAVROV V., STAMENOV S., TODOROVA E., CHMIEL H., ERWE T., 2006, New hybrid electrocoagulation membrane process for removing selenium from industrial wastewater. Desalination 201: 290-296.
• MELICHOVA Z., HROMADA L., 2013, Adsorption of Pb2+ and Cu2+ ions from aqueous solutions on natural bentonite. Pol. J. Environ. Stud. 22: 457-464.
• MELLAH A., CHEGROUCHE S., 1997, The removal of zinc from aqueous solutions by natural bentonite. Water Res. 31: 621-629.
• MOHAN D., CHANDER S., 2006, Removal and recovery of metal ions from acid mine drainage using lignite-a low cost sorbent. J. Hazard. Mater. 137: 1545-1553.
• MUSSO T.B., PAROLO M.E., PETTINARI G., FRANCISCA F.M., 2014, Cu(II) and Zn(II) adsorption capacity of three different clay liner materials. J. Environ. Manage. 146: 50-58.
• NIGHTINGALE JR., E.R., 1959, Phenomenological theory of ion solvation. Effective radii of hydrated ions. J. Phys. Chem. 63: 1381-1387.
• NIRIELLA D. and CARNAHAN R.P., 2006, Comparison study of zeta potential values of bentonite in salt solutions. J. Disper. Sci. Technol. 27: 123-131.
• NUÑEZ P., HANSEN H.K., AGUIRRE S., MAUREIRA C., 2011, Electrocoagulation of arsenic using iron nanoparticles to treat copper mineral processing wastewater. Sep. Purif. Technol. 79: 285-290.
• POLAT H., ERDOGAN D., 2007, Heavy metal removal from waste waters by ion flotation. J. Hazard. Mater. 148: 267-273.
• SEN T.K., GOMEZ D., 2011, Adsorption of zinc (Zn2+) from aqueous solution on natural bentonite. Desalination 267: 286-294.
• SHETA A.S., FALATAH A.M., AL-SEWAILEM M.S., KHALED E.M., SALLAM A.S.H., 2003, Sorption characteristics of zinc and iron by natural zeolite and bentonite. Micropor. Mesopor. Mat. 61: 127-136.
• SINGANAN M., 2011, Removal of lead(II) and cadmium(II) ions from wastewater using activated biocarbon. Science Asia 37: 115-119.
• SRIVASTAVA P., SINGH B., ANGOVE M., 2005, Competitive adsorption behavior of heavy metals on kaolinite. J. Colloid Interf. Sci. 290: 28-38.
• UDO E.J., BOHN H.L., TUCKER T.C., 1970, Zinc adsorption by calcareous soils. Soil Sci. Soc. Am. J. 34: 405-407.
• VELI S., ALYUZ B., 2007, Adsorption of copper and zinc from aqueous solutions by using natural clay. J. Hazard. Mater. 149: 226-233.
• WANG S., PENG Y., 2010, Natural zeolites as effective adsorbents in water and wastewater treatment. Chem. Eng. J. 156: 11-24.
• WANG S., TERDKIATBURANA T., TADE M.O., 2008, Adsorption of Cu(II), Pb(II) and humic acid on natural zeolite tuff in single and binary systems. Sep. Purif. Technol. 62: 64-70.
• ZHANG X., LIN S., CHEN Z., MEGHARAJ M., NAIDU R., 2011, Kaolinite-supported nanoscale zero-valent iron for removal of Pb2+ from aqueous solution: Reactivity, characterization and mechanism. Water Res. 45: 3481-3488.
• ZHANG X., LIN S., LU X., CHEN Z., 2010, Removal of Pb(II) from water using synthesized kaolin supported nanoscale zero-valent iron. Chem. Eng. J. 163: 243-248.
• ZHANG X., YANG L., LI Y., LI H., WANG W., YE B., 2012, Impacts of lead/zinc mining and smelting on the environment and human health in China. Environ. Monit. Assess. 184: 2261-2273.

Uwagi

Opracowanie ze środków MNiSW w ramach umowy 812/P-DUN/2016 na działalność upowszechniającą naukę (zadania 2017).