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Study on flotation behavior and mechanism of separating chalcopyrite and Molybdenite with ethyl mercaptoglycolate as inhibitor

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Warianty tytułu
Języki publikacji
EN
Abstrakty
EN
The effect of ethyl thioglycolate organic small molecule inhibitors on chalcopyrite molybdenite flotation behaviour is investigated via single mineral micro-flotation tests, zeta potential tests, and X-ray photoelectron spectroscopy (XPS) analysis. Results of the flotation test indicate that ethyl thioglycolate organic small-molecule inhibitors can effectively separate Cu and Mo and selectively inhibit chalcopyrite under weak alkaline conditions. Infrared spectroscopy and XPS analysis show that hydrophilic functional groups C=O and -COOH in the ethyl thioglycolate organic small molecules can chemically adsorb onto the chalcopyrite surface. Moreover, ethyl thioglycolate has no obvious effect on zeta potential of molybdenite. Therefore, ethyl thioglycolate can effectively separate chalcopyrite and molybdenite.
Rocznik
Strony
art. no. 162824
Opis fizyczny
Bibliogr. 20 poz., tab., wykr.
Twórcy
  • Heilongjiang University of Science and Technology School of Mining Engineering
autor
  • Heilongjiang University of Science and Technology School of Mining Engineering
autor
  • Heilongjiang University of Science and Technology School of Mining Engineering
Bibliografia
  • ANASARI, A., PAWLIK, M., 2006, Floatability of chalcopyrite and molybdenite in the presence of lignosulfonates. Part ii. Hallimond tube flotation. Minerals Engineering, 20(6), 609-616.
  • FENG, B., GUO, Y.T., WANG, T., PENG, J.X., NING, X.H., WANG, H.H., 2020, Role and mechanism of xanthan gum in flotation separation of chalcopyrite and sphalerite. Chinese Journal of Nonferrous Metals, 30(05), 1202-1208.
  • HE, W., ZHOU, G., LIU, L., 2013, New synthesis process and application of ethyl thioglycolate. Modern Mining, 29(11). 17-20.
  • HUANG P.L., YANG B.Q., HU Y.J., YAN H., TENG A.P., 2019, Research progress of Cu-Mo separation technology. Nonferrous Metals (Mineral Processing), 05, 50-55. (in Chinese)
  • LI, M.Y., WEO, D.Z., LIU, Q., LIU, W.B., SUN, H.J., 2015, Flotation separation of copper–molybdenum sulfides using chitosan as a selective depressant. Minerals Engineering, 83, 217-222.
  • LI, M.Y., WEI, D.Z., SHEN, Y.B., LIU, W.G., GAO, S.L., LIANG, G.Q., 2015,Selective depression effect in flotation separation of copper−molybdenum sulfides using 2,3-disulfanylbutanedioic acid. Transactions of Nonferrous Metals Society of China, 25(9), 3126-3132.
  • LIN, Q.Q., GU, G.H., WANG, H., LIU, Y.C., 2017, Recovery of molybdenum and copper from porphyry ore via iso-flotability flotation. Transactions of Nonferrous Metals Society of China, 2260-2271.
  • LIU, G.Y., LU, Y.P., ZHONG, H., CAO, Z.F., XU, Z.H., 2012 ,A novel approach for preferential flotation recovery of molybdenite from a porphyry copper–molybdenum ore. Minerals Engineering, 36-38.
  • MITCHELL, T.K., NGUYEN, A.V., EVANS, G.M, 2004, Heterocoagulation of chalcopyrite and pyrite minerals in flotation separation. Advances in Colloid and Interface Science, 114-115, 227-237.
  • QIU, L.N., DAI, H.X.,2009,Flotation process and recent reagents status of molybdenum ore. Modern Mining, vol. 22-23.
  • RATH, R.K., SUBRAMANIAN, S., PRADEEP, T., 2000, Surface chemical studies on pyrite in the presence of polysaccharide-based flotation depressants. Journal of Colloid and Interface Science, 229(1), 82-91.
  • SONG, S.X., ZHANG, X.W., YANG, B.Q., 2012,Flotation of molybdenite fines as hydrophobic agglomerates. Separation and Purification Technology, 98, 451-455.
  • YAN, H., YANG, B., ZENG, M., HUANG, P., TENG, A., 2020, Selective flotation of Cu-Mo sulfides using xanthan gum as a novel depressant. Minerals Engineering, 156.
  • YIN, W.Z., ZHANG, L.R., and XIE, F., 2010, Flotation of Xinhua molybdenite using sodium sulfide as modifier. Transactions of Nonferrous Metals Society of China, 20(4), 702-706.
  • YIN, Z.G., SUN, W., HU, Y.H., GUAN, Q.J., ZHANG, C.H., GAO, Y.S., ZHAI, J.H., 2017, Depressing behaviors and mechanism of disodium bis (carboxymethyl) trithiocarbonate on separation of chalcopyrite and molybdenite. Transactions of Nonferrous Metals Society of China, 27(4), 883-890.
  • YUAN, D., CADIEN, K., LIU, Q., ZENG, H., 2019, Flotation separation of Cu-Mo sulfides by O-carboxymethyl chitosan. Minerals Engineering, 2019, 134, 202-205.
  • YUAN, D., CADIEN, K., LIU, Q., ZENG, H.,2019,Selective separation of copper-molybdenum sulfides using humic acids. Minerals Engineering, 133,43-46.
  • ZANG, C., 2017, Research on the new inhibitor of sulfide copper–molybdenum mine and its mechanism. Jiangxi University of Science and Technology, China.
  • ZENG, J.M., 2012, Selective flotation and first-principles study on copper–molybdenum ore. Center South University, China.
  • ZHENG, M.X., LIAN, F.L., XIONG, Y., LIU, B., ZHU, Y.J., MIAO, S., ZHANG, L.T., ZHENG, B.D., 2019, The synthesis and characterization of a xanthan gum-acrylamide-trimethylolpropane triglycidyl ether hydrogel. Food Chemistry, 272, 574-579.
Uwagi
Opracowanie rekordu ze środków MEiN, umowa nr SONP/SP/546092/2022 w ramach programu "Społeczna odpowiedzialność nauki" - moduł: Popularyzacja nauki i promocja sportu (2022-2023).
Typ dokumentu
Bibliografia
Identyfikator YADDA
bwmeta1.element.baztech-9f8306b9-9bf5-45b9-bfc0-13054bb73316
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