Investigation on growth, optical and thermal properties of stilbazolium derivative crystal: 4-N,N-dimethylamino-40-N0-methylstilbazolium 2,4-dimethylbenzenesulfonate

• Autorzy: Md Zahid I. , Kalaiyarasi S. , Kumar M. K. , Ganesh T. , Jaisankar V. , Kumar R. M.

Identyfikatory

DOI

10.1515/msp-2016-0113

• Języki publikacji: EN

Abstrakty

EN

Metathesis ionic exchange reaction process was used to synthesize a novel nonlinear optical material: 4-N,N-dimethylamino-4′- N′-methylstilbazolium 2,4-dimethylbenzenesulfonate (DSDMS). The growth of DSDMS single crystals was carried out by adopting the solution growth technique. The crystal perfection and lattice parameters were elucidated from single XRD and powder XRD, respectively and its morphology was interpreted by WinXMorph program. FT-IR and Raman spectral analyses confirmed the existence of functional groups and their corresponding vibrational modes. UV-Vis spectral studies revealed the optical transmission region. Mechanical stability of the crystal was determined from Vickers microhardness number H_v, Meyer’s index n and elastic stiffness constant C₁₁. Dielectric and thermal behavior of the grown crystal were elucidated by using impedance analyser and thermogravimetric analysis.

Słowa kluczowe

EN

ionic; crystals; DSDMS; solution; growth; technique; nonlinear; optical material

• Wydawca: De Gruyter
• Czasopismo: Materials Science Poland
• Rocznik: 2016
• Tom: Vol. 34, No. 4
• Strony: 811--818
• Opis fizyczny: Bibliogr. 25 poz., rys., tab.

Twórcy

autor

Md Zahid I.

• Department of Physics, Presidency College, Chennai, 600 005, India

autor

Kalaiyarasi S.

• Department of Physics, Presidency College, Chennai, 600 005, India

autor

Kumar M. K.

• Department of Physics, Kalasalingam University, Krishnankoil, 626 126, India

autor

Ganesh T.

• Department of Physics, Presidency College, Chennai, 600 005, India

autor

Jaisankar V.

• Department of Chemistry, Presidency College, Chennai, 600 005, India

autor

Kumar R. M.

• Department of Physics, Presidency College, Chennai, 600 005, India

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Uwagi

Opracowanie ze środków MNiSW w ramach umowy 812/P-DUN/2016 na działalność upowszechniającą naukę (zadania 2017).