Ultra-rapid determination of andrographolide and dehydroandrographolide in Andrographis Herba by solid phase extraction and liquid chromatography with mass spektrometry

• Autorzy: Qian Zhengming , Chen Jing , Lei Qinggui , Li Da , Tan Guoying , Xie Juying , Li Wenqing

Identyfikatory

DOI

10.1556/1326.2023.01156

• Języki publikacji: EN

Abstrakty

EN

An ultra-rapid analytical method for determination of andrographolide and dehydroandrographolide in Andrographis Herba (AH) was developed by liquid chromatography with mass spectrometry (LC-MS). The sample was ultrasonically extracted with 10 mL 40% (v/v) methanol, and then purified with a C18 solid phase extraction column. The LC separation was performed on a Poroshell 120 EC-C18 column (3032.1 mm, 2.7 μm) and eluted with 0.5 mmol L1 ammonium acetate aqueous solution and acetonitrile (65:35) at a flow rate of 0.7 mL min1, and detected by mass spectrometry (MS). The LC-MS analytical time was less than 1 min. The new developed method presented a good linearity (r > 0.9900), precision and repeatability (RSD < 2.0%). The recoveries for andrographolide and dehydroandrographolide were 93.5% (RSD 5 2.2%) and 97.7% (RSD 5 2.4%), respectively. The developed method was successfully applied in determination of andrographolide and dehydroandrographolide in seven batches of AH samples, and the contents of analytes in all samples were complied with the relative acceptance criteria in Chinese Pharmacopeia (>0.8%). This new developed LC-MS method is an ultrarapid assay method for AH, which will help to improve the efficiency and reduce the cost of AH sample test.

Słowa kluczowe

EN

solid phase extraction; LC-MS; Andrographis Herba; andrographolide; dehydroandrographolide

• Wydawca: University of Silesia in Katowice ; Akademiai Kiado
• Czasopismo: Acta Chromatographica
• Rocznik: 2024
• Tom: Vol. 36, no. 3
• Strony: 279--–285
• Opis fizyczny: Bibliogr. 26 poz., rys., wykr.

Twórcy

autor

Qian Zhengming

• College of Medical Imaging Laboratory and Rehabilitation, Xiangnan University, Chenzhou 423000, P. R. China
• Dongguan HEC Cordyceps R&D Co., LTD, Dongguan, Guangdong 523850, P. R. China

autor

Chen Jing

• College of Medical Imaging Laboratory and Rehabilitation, Xiangnan University, Chenzhou 423000, P. R. China

autor

Lei Qinggui

• Dongguan HEC Cordyceps R&D Co., LTD, Dongguan, Guangdong 523850, P. R. China

autor

Li Da

• Hong Zheng Dao (China) Traditional Chinese Medicine Research Co., LTD, Guangzhou, Guangdong 510665, P. R. China

autor

Tan Guoying

• Dongguan HEC Cordyceps R&D Co., LTD, Dongguan, Guangdong 523850, P. R. China

autor

Xie Juying

• College of Medical Imaging Laboratory and Rehabilitation, Xiangnan University, Chenzhou 423000, P. R. China

• https://orcid.org/0000-0002-6763-7183

autor

Li Wenqing

• Dongguan HEC Cordyceps R&D Co., LTD, Dongguan, Guangdong 523850, P. R. China

• https://orcid.org/0000-0002-5713-1269

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