Thermal Decomposition Kinetics of Hexanitrohexaazaisowurtzitane/Ammonium Perchlorate

• Autorzy: Zhu Y.-L. , Wang K.-K. , Shan M.-X. , Zheng X.-D. , Jiao Q.-J. , Wang J.-S.
• Języki publikacji: EN

Abstrakty

EN

The thermal decomposition kinetics of hexanitrohexaazaisowurtzitane/ ammonium perchlorate (HNIW/AP) have been investigated by thermogravimetrydifferential scanning calorimetry-mass spectrometry (TG-DSC-MS) simultaneous analysis. TG showed that there were three weight loss processes for the thermal decomposition of the HNIW/AP mixture. The first was ascribed mainly to the thermal decomposition of HNIW, while the second and third were assigned to that of AP. The presence of AP has little effect on the thermal decomposition process of the HNIW component. The apparent activation energy of the thermal decomposition of the HNIW component, calculated by the Kissinger method, was little changed compared to that of neat HNIW. The addition of HNIW to AP caused the onset and end temperatures of the thermal decomposition to be decreased and the decomposition process to be shortened. The high-temperature and lowtemperature decomposition processes of AP became blurred in the presence of HNIW, and this was supported by the MS results.

Słowa kluczowe

EN

hexanitrohexaazaisowurtzitane; ammonium perchlorate; thermal analysis; thermal decomposition kinetics

• Czasopismo: Central European Journal of Energetic Materials
• Rocznik: 2016
• Tom: Vol. 13, no. 1
• Strony: 149--159
• Opis fizyczny: Bibliogr. 24 poz., rys., tab.

Twórcy

autor

Zhu Y.-L.

• State Key Laboratory of Explosive Science and Technology, Beijing Institute of Technology, South Street 5, Zhongguancun, Haidian District, Beijing, 100081, China

autor

Wang K.-K.

• State Key Laboratory of Explosive Science and Technology, Beijing Institute of Technology, South Street 5, Zhongguancun, Haidian District, Beijing, 100081, China

autor

Shan M.-X.

• State Key Laboratory of Explosive Science and Technology, Beijing Institute of Technology, South Street 5, Zhongguancun, Haidian District, Beijing, 100081, China

autor

Zheng X.-D.

• State Key Laboratory of Explosive Science and Technology, Beijing Institute of Technology, South Street 5, Zhongguancun, Haidian District, Beijing, 100081, China

autor

Jiao Q.-J.

• State Key Laboratory of Explosive Science and Technology, Beijing Institute of Technology, South Street 5, Zhongguancun, Haidian District, Beijing, 100081, China

autor

Wang J.-S.

• State Key Laboratory of Explosive Science and Technology, Beijing Institute of Technology, South Street 5, Zhongguancun, Haidian District, Beijing, 100081, China

Bibliografia

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Uwagi

Opracowanie ze środków MNiSW w ramach umowy 812/P-DUN/2016 na działalność upowszechniającą naukę.