Development of a simple HPLC procedure for the determination of prochloraz residues in mushrooms

• Autorzy: Csutoras Csaba , Misz Andras , Nagy-Koteles Csaba , Bakos-Barczi Nora , Racz Laszlo

Identyfikatory

DOI

10.1556/1326.2021.00928

• Języki publikacji: EN

Abstrakty

EN

A simple HPLC-UV procedure is described in our paper which is suitable for the rapid and cost-efficient determination of prochloraz in mushrooms. Prochloraz is the only fungicide in EU which use is allowed in mushroom production. The aim of our work was the development of a simple method that is suitable for the control of this pesticide in everyday analyses during mushroom production. The procedure involves a simple sample preparation method based on solid-liquid extraction (modified QuEChERS extraction method EN 15662) followed by an HPLC-UV determination (recovery: 97–99%; limit of detection LOD: 0.01 mg/kg; limit of quantification LOQ: 0.05 mg/kg).

Słowa kluczowe

EN

pesticide analysis; prochloraz; liquid chromatography; cultivated mushrooms; Agaricus Bisporus

• Wydawca: University of Silesia in Katowice ; Akademiai Kiado
• Czasopismo: Acta Chromatographica
• Rocznik: 2022
• Tom: Vol. 34, no. 3
• Strony: 373--375
• Opis fizyczny: Bibliogr. 8 poz., tab.

Twórcy

autor

Csutoras Csaba

• Department of Food Science, Eszterhazy Karoly University, Eszterhazy sqr. 1, H-3300, Eger, Hungary

• https://orcid.org/0000-0001-6794-1778

autor

Misz Andras

• New Champignons Ltd. 1224, Bartok Bela Road 162, Budapest, Hungary

autor

Nagy-Koteles Csaba

• New Champignons Ltd. 1224, Bartok Bela Road 162, Budapest, Hungary

autor

Bakos-Barczi Nora

• New Champignons Ltd. 1224, Bartok Bela Road 162, Budapest, Hungary

autor

Racz Laszlo

• Department of Food Science, Eszterhazy Karoly University, Eszterhazy sqr. 1, H-3300, Eger, Hungary

Bibliografia

• 1. Williams, K. J.; James, C. R.; Thorpe, S. A.; Reynolds, S. L. Two analytical methods for the measurement of 2,4-D in oranges: an ELISA screening procedure and a GC-MS confirmatory procedure. J. Pestic. Sci. 1997, 50, 135–40.
• 2. Ramírez Restrepo, A.; Gallo Ortiz, A. F.; Hoyos Ossa, D. E.; Penuela Mesa, G. A. QuEChERS GC–MS validation and monitoring of pesticide residues in different foods in the tomato classification group. Food Chem. 2014, 158, 153–61.
• 3. Xu, L.; Luan, F.; Liu, H.; Gao, Y. Dispersive liquid-liquid micro-extraction combined with non-aqueous capillary electrophoresis for the determination of imazalil, prochloraz and thiabendazole in apples, cherry tomatoes and grape juice. J. Sci. Food Agric. 2015, 95, 745–51.
• 4. Veneziano, A.; Vacca, G.; Arana, S.; De Simone, F.; Rastrelli, L. Determination of carbendazim, thiabendazole and thiophanate-methyl in banana (Musa acuminate) samples imported to Italy. Food Chem. 2004, 87, 383–6.
• 5. Michel, M.; Buszewski, B. Optimization of a matrix solid-phase dispersion method for the determination analysis of carbendazim residue in plant material. J. Chromatogr. B 2004, 800, 309–14.
• 6. Wang, S.; Xu, Y.; Pan, C.; Jiang, S.; Liu, F. Application of matrix solid-phase dispersion and liquid chromatography–mass spectrometry to fungicide residue analysis in fruits and vegetables. Anal. Bioanal. Chem. 2007, 387, 673–85.
• 7. Sack, C.; Vonderbrink, J.; Smoker, M.; Smith, R. E. Determination of acid herbicides using modified QuEChERS with fast switching ESI+/ESI-LC-MS/MS. J. Agric. Food Chem. 2015, 63, 9657–65.
• 8. Anastassiades, M.; Lehotay, S. J.; Stajnbaher, D.; Schenck, F. J. Fast and easy multiresidue method employing acetonitrile extraction/partitioning and “dispersive solid-phase extraction” for the determination of pesticide residues in produce. J. AOAC Int. 2003, 86, 412–31.

Uwagi

Opracowanie rekordu ze środków MEiN, umowa nr SONP/SP/546092/2022 w ramach programu "Społeczna odpowiedzialność nauki" - moduł: Popularyzacja nauki i promocja sportu (2022-2023).