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Electrorefining of High Carbon Ferromanganese in Molten Salts to Produce Pure Ferromanganese

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EN
Abstrakty
EN
High carbon ferromanganese is used as a starting material to prepare pure ferromanganese by electrorefining in molten salts. High carbon ferromanganese was applied as the anode, molybdenum was the cathode and Ag/AgCl was the reference electrode. The anodic dissolution was investigated by linear polarization in molten NaCl-KCl system. Then potentiostatic electrolysis was carried out to produce pure ferromanganese from high carbon ferromanganese. The cathodic product was determined to be a mixture of manganese and iron by x-ray diffraction (XRD). The content of carbon in the product was analyzed by carbon and sulfur analyzer. The post-electrolysis anode was characterized by scanning electron microscope (SEM). The mechanism of the anode dissolution and the distribution of the main impurity of carbon and silicon after electrolysis were discussed.
Twórcy
autor
  • School of Metallurgy Engineering, Anhui University of Technology, Maanshan 243032, China
autor
  • School of Metallurgy Engineering, Anhui University of Technology, Maanshan 243032, China
autor
  • School of Metallurgy Engineering, Anhui University of Technology, Maanshan 243032, China
autor
  • School of Metallurgy Engineering, Anhui University of Technology, Maanshan 243032, China
Bibliografia
  • [1] O. Grassel, L. Krüger, G. Frommeyer, L. W. Meyer, International Journal of Plasticity 16, 1391-1409 (2000).
  • [2] J. Lu, D. Dreisinger, T. Glück, Hydrometallurgy 141, 105-116 (2014).
  • [3] C. Song, Master thesis, South Centual University, Hunan, China, (2013) (in Chinese).
  • [4] J. Safarian, L. Kolbeinsen, INFACON XIII, Almaty, Kazakhstan. Conference proceedings 175 (2013).
  • [5] G. Hils, A. Newirkowez, M. Kroker, U. Grethe, R. Schmidt-Jürgensen, J. Kroos, K.H. Spitzer, Steel research international 86, 411-42 (2015).
  • [6] C. Tao, S. Fei, Z. Liu, J. Du, X. Fan, M. Li, Y. Chen, China’s Manganese Industry 29, 1-5 (2011).
  • [7] A. J. Godsell, D. J. Fray, Metallurgical Transactions B 21, 217-228 (1990).
  • [8] B. Cartwright, S. F. Ravitz, Transactions of The Electrochemical Society 89, 373-382 (1946).
  • [9] F. R. Cattoir, T. A. Sullivan, Bureau of Mines, (1969).
  • [10] K. P. V. Lei, T. A. Sullivan, Bureau of Mines, (1971).
  • [11] M. Selecka, A. Salak, Powder Metallurgy Progress 9, 97-114 (2009).
Uwagi
PL
Opracowanie rekordu w ramach umowy 509/P-DUN/2018 ze środków MNiSW przeznaczonych na działalność upowszechniającą naukę (2018).
Typ dokumentu
Bibliografia
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bwmeta1.element.baztech-9e2c2595-0b82-49c9-a2f6-bcf90e732e8e
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