PL EN


Preferencje help
Widoczny [Schowaj] Abstrakt
Liczba wyników
Tytuł artykułu

Thermodynamic Assessment of Mushy Zone in Directional Solidification

Treść / Zawartość
Identyfikatory
Warianty tytułu
Języki publikacji
EN
Abstrakty
EN
Solidification of AlSiFe alloys was studied using a directional solidification facility and the CALPHAD technique was applied to calculate phase diagrams and to predict occurring phases. The specimens solidified by electromagnetic stirring showed segregation across, and the measured chemical compositions were transferred into phase diagrams. The ternary phase diagrams presented different solidification paths caused by segregation in each selected specimen. The property diagrams showed modification in the sequence and precipitation temperature of the phases. It is proposed in the study to use thermodynamic calculations with Thermo-Calc which enables us to visualize the mushy zone in directional solidification. 2D maps based on property diagrams show a mushy zone with a liquid channel in the AlSi7Fe1.0 specimen center, where significant mass fraction (33%) of β-Al5FeSi phases may precipitate before α-Al dendrites form. Otherwise liquid channel occurred almost empty of β in AlSi7Fe0.5 specimen and completely without β in AlSi9Fe0.2. The property diagrams revealed also possible formation of α–Al8Fe2Si phases.
Rocznik
Strony
101--109
Opis fizyczny
Bibliogr. 16 poz., rys., wykr.
Twórcy
  • Institute of Materials Technology, Poznan University of Technology, Piotrowo 3, 60-965 Poznan, Poland
autor
  • Institut für Werkstoff-Forschung, German Aerospace Center DLR, Linder Höhe, 51147 Köln, Germany
Bibliografia
  • [1] Massalski, T.B., Okamoto, H. (1990). Binary alloy phase diagrams. Materials Park, Ohio, ASM International, 1990. ISBN-13: 978-0871704030.
  • [2] Kaufman, L., Bernstein, H. (1970). Computer Calculation of Phase Diagrams with Special Reference to Refractory Metals. Academic Press, New York, NY, 1970.
  • [3] Lukas, H., Fries, S.G., Sundman, B. (2007). Computational Thermodynamics – The Calphad Method. Cambridge University Press 2007. ISBN 978-0-521-86811.
  • [4] Hillert, M. (1998). Phase Equilibria, Phase Diagrams and Phase Transformations – Their Thermodynamic Basis. Cambridge University Press 1998. ISBN 978-0-521-85351-4.
  • [5] Shi, P., Sundman, B. (2013). Thermo-Calc Software System – Thermodynamic Framework and Data. Thermo-Calc Software AB.
  • [6] Junga, H., Mangelinck-Noëlb, N., Nguyen-Thi, N. & Billia, B. (2009). Columnar to equiaxed transition during directional solidification in refined Al-based alloys. Journal of Alloys and Compounds. 484(1-2), 739-746. DOI: dx.doi.org/10.1016/j.jallcom.2009.05.029.
  • [7] Ruvalcaba, D., Mathiesen, R.H., Eskin, D.G., Arnberg, L. & Katgerman, L. (2007). In situ observations of dendritic fragmentation due to local solute-enrichment during directional solidification of an aluminum alloy. Acta Materialia. 55(13), 4287-4292. DOI: dx.doi.org/10.1016/j.actamat.2007.03.030.
  • [8] Tomaszewski, P.E. (2002). Jan Czochralski - Father of the Czochralski method. Journal of Crystal Growth. 236, 1-4. DOI: dx.doi.org/10.1016/S0022-0248(01)02195-9.
  • [9] Duffar, T., Serrano, M.D., Moore, C.D., Camassel, J., Contreras, S. & Tanner, B.K. (1998). Bridgman solidification of GaSb in space. Journal of Crystal Growth. 192, 63-72. DOI:dx.doi.org/10.1016/S0022-0248(98)00421-7.
  • [10] Alkemper, J., Sous, S., Stoker, C. & Ratke L. (1998). Directional solidification in an aerogel furnace with high resolution optical temperature measurements. Journal of Crystal Growth. 191, 252-260. DOI: dx.doi.org/10.1016/S0022-0248(98)00114-6.
  • [11] Steinbach, S., Ratke, L. (2004). In situ optical determination of fraction solid. Scripta Materialia. 50, 1135-1138. DOI: dx.doi.org/10.1016/j.scriptamat.2004.01.023.
  • [12] Steinbach, S. (2005). The influence of fluid flow on the microstructure evolution of directional solidified Al-Si and Al-Si-Mg alloys (in German). Ph.D. Thesis. RWTH, Germany.
  • [13] Thermo-Calc 4.1 – Software package from Thermo-Calc Software AB. Stockholm, Sweden. www.thermocalc.se.
  • [14] Mikolajczak, P. & Ratke, L. (2013). Effect of stirring induced by rotating magnetic field on beta-Al5FeSi intermetallic phases during directional solidification in AlSi alloys. Int. J. Cast Met. Res.. 26, 339-353. DOI: dx.doi.org/10.1179/1743133613Y.0000000069.
  • [15] Mikolajczak, P. & Ratke, L. (2015). Interplay Between Melt Flow and the 3D Distribution and Morphology of Fe-Rich Phases in AlSi Alloys. Metall. Mater. Trans. A. 46A, 1312-1327. DOI: dx.doi.org/10.1007/s11661-014-2692-4.
  • [16] Hainke, M. (2004). Computation of Convection and Alloys Solidification with the Software Package CrysVUn. Ph.D. Thesis, Technical Faculty Erlangen-Nuremberg, Germany.
Typ dokumentu
Bibliografia
Identyfikator YADDA
bwmeta1.element.baztech-9e02b557-5994-47bb-ae60-23dc38d1e163
JavaScript jest wyłączony w Twojej przeglądarce internetowej. Włącz go, a następnie odśwież stronę, aby móc w pełni z niej korzystać.