Rietveld crystal structure refinement of the natural rhombohedral grossular-andradite garnet from Serbia

• Autorzy: Tančić Pavle , Kremenović Aleksandar

Identyfikatory

DOI

10.7306/gq.1639

• Języki publikacji: EN

Abstrakty

EN

Four macroscopically visible B–E (rim) zones of the natural grossular-andradite garnet with Grs_58-64subAdr_36-42>Sps2composition were crystallographically studied. The applied procedure includes the Rietveld refinements of the crystal structures in a series of six space groups, which were followed by the comparative analysis of the R-values, site occupancy factors, and the bond lengths and angles. It was established that it crystallized in the rhombohedral R^-3c space group. Various polyhedral distortions and structural order-disorder variations between the studied zones were also observed, determined and discussed. Therefore, rhombohedral symmetry of the studied grandite could be treated as primary and residual strain as the second cause for its slight optical anisotropy.

Słowa kluczowe

EN

ferric grossular garnet; XRPD; Rietveld method; crystal structure; R‾3c space group; order-disorder

• Wydawca: Państwowy Instytut Geologiczny - Państwowy Instytut Badawczy
• Czasopismo: Geological Quarterly
• Rocznik: 2022
• Tom: Vol. 66, No. 1
• Strony: art. no. 7
• Opis fizyczny: Bibliogr. 37 poz., fot., rys., tab., wykr.

Twórcy

autor

Tančić Pavle

autor

Kremenović Aleksandar

Bibliografia

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Uwagi

Opracowanie rekordu ze środków MEiN, umowa nr SONP/SP/546092/2022 w ramach programu "Społeczna odpowiedzialność nauki" - moduł: Popularyzacja nauki i promocja sportu (2022-2023).