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The presence of Fe-silicides, extremely rare mineral phases were documented in the Permian Cu-bearing ore formation in the Fore-Sudetic Monocline (Polkowice-Sieroszowice and Rudna mines, SW Poland). It is a first report of their occurrence within rocks of Late Palaeozoic age. The Fe-Si alloys forme spherules of various structure and chemical composition. The silicide spherules were found in the flotation concentrates prepared from the copper ore. Their composition varies from FeSi (fersilicite) to Fe2Si3 or Fe4Si9. A dominant constituent is Fe5Si3 (xifengite) with admixtures of P, Ti, Cr and Mn. Native Si and Ti were detected in the marginal part of spherules. The current knowledge do not permit to determine unequivocally whether the Fe-silicide spherules formed as a result of Permian cosmic dust or constitute terrestrial magmatic material of ultramafic character transported into a sedimentary basin from the adjacent terrain.
Słowa kluczowe
Rocznik
Tom
Strony
107--118
Opis fizyczny
Bibliogr. 26 poz., rys., tab.
Twórcy
autor
- Institute of Geological Sciences, University of Wroclaw, Pl. Maksa Borna 9, 50-205 Wroclaw, Poland
Bibliografia
- 1. ANAND M., TAYLOR L.A., NAZAROV M.A., SHU J., MAO H.K., HEMLEY R.J., 2004. Space weathering on airless planetary bodies: Clues from the lunar mineral hapkeite. Proc. Nat. Acad. Sci., 101, 6847–6851.
- 2. BAI W.J., SHI N., FANG Q., LI G., YANG J., XIONG M., RONG H., 2007. Luobusaite – a new mineral. Acta Geologica Sinica 80 (10), 1487–1490. (Chinese with English abstract).
- 3. BAUER J., FIALA J., HRICHOVÁ R., 1963. Natural α-silicon carbide. American Mineralogist. 48. 620–634.
- 4. BERNHARD P., 2008. The Ore Minerals Under the Microscope. Elsevier.
- 5. CRIDDLE A.J., STANLEY C.J., 1993. Quantitative data file for ore minerals. 3rd edition, Chapman & Hall, London-New York-Madras.
- 6. DI PIERRO S., GNOS E., GROBETY B.H., ARMBRUSTER T., BERNASCONI S.M., ULMER P., 2003. Rock-forming moissanite (natural-silicon carbide). American Mineralogist. 2003. 88. 1817–1821.
- 7. GEVORK'YEN V. Ku, 1969. The occurrence of natural ferrosilicon in the northern Azov region. Dokl. Akad. Nauk.S.S.S.R. 85. 4l6–418 (in Russian).
- 8. GEVORK'YEN V. Ku., LITVIN A. L., POVARENNYKH A.S., 1969. Occurrence of the new minerals fersilicite and ferdisilicate. Geol. Zh. (Ukraine) 29, 2. 62–71 (in Russian).
- 9. JAKABSKÁ K., ROZLOŽNĬK L., 1989. Spherical accessories („spherules”) in gemeric granites (West Carpathians – Czechoslovakia). Geol. Zbor. 40. 3. 305–322.
- 10.. JUDIN I.A., KOLOMENSKIJ W.D., 1987. Mineralogy of meteorites. Svierdlovsk. A.N. Uralskij Naucznyj Centr (in Russian).
- 11. KEIL K., BERKLEY J.L., FUCHS L.H., 1982. Suessite, Fe3Si: a new mineral in the North Haig ureilite. American Mineralogist: 67. 126–131.
- 12. MARSHINTSEV V.K., 1990. Nature of silicon carbide in kimberlite rocks of Yakutia. Mineralogicheskiy Zhurnal. 12 (3). 17–26 (in Russian).
- 13. MASON B., 1962. Meteorites. New York. Wiley. 305.
- 14. MUSZER A., 2000. Outline of ore microscopy, University of Wroclaw, Wroclaw (in Polish).
- 15. MUSZER A., 2007. Characteristic of the spherules and accessoric minerals from selected phanerozoic and anthropogenic sediments, Wroclaw, Fundacja Ostoja, (in Polish).
- 16. NOVGORODOVA M.I., BORONIKHIN V.A., GENERALOV M.E., KRAMER H., 1989. On native silicon in association with native gold and other metals. Doklady Akad. Nauk SSSR., 309 (5), 1182–1185 (in Russian).
- 17. NOVOSIELOVA L.H., 1975. Fe-silicides in the Lower Cambrian limestone, Bazaiha (pritok Enisieja).Krasnojarskij kraj. Zap. Wsesojuz. Min., 104 (2), 228-234 (in Russian)
- 18. NOVOSIELOVA L.H., BAGDASAROVA E.A., 1979. New dates about Fe-silicides. Zap. Wsesojuz. Min., 108 (3), 326–333 (in Russian)
- 19. PANKOV V.YU., SPETSIUS Z.V., 1989. Inclusions of iron silicides and native silicon in moissanite from the “Sytykanskaya” kimberlite pipe. Doklady Akad. Nauk SSSR 305, 704–707 (in Russian).
- 20. RAMDOHR P., 1973. The opaque minerals in Stony Meteorites. Berlin.
- 21. RAMDOHR P., 1975. Die Erzmineralien und ihre Verwaachsungen. Berlin.
- 22. ROBINSON P.T., BAI W.J., MALPAS J., YANG J.S., ZHOU M.F., FONG Q.S., HU X., CAMERON S., STAUDIGEL H., 2004. Ultra-high pressure minerals in the Luobusa ophiolite, Tibet, and their tectonic implications. In: Malpas J., Fletcher L.J.N., Ali J.R., Aitchison J.C. (eds.). Aspects of the Tectonic Evolution of China. Geological Society London Special Publications. 226 (1), 247–271.
- 23. SAMUELS L.E., 1982. Metallographic polishing by mechanical methods. American Society for Metals. Metals Park, Ohio.
- 24. UYTENBOGAARDT W., BURKE E.A.J., 1971. Tabeles for Microscopic Identification of Ore Minerals. Elsevier. Amsterdam–London–New York.
- 25. XIONGJIAN Hu, 1991. A preliminary study on ferrosilicium from the Proterozoic, southwestern Zhejiang Province. Acta Mineral. Sinica, 11(3), 285–289 (in Chinese, English abs.).
- 26. ZUXIANG Yu., 1984. Two new minerals gupeiite and xifengite in cosmic dusts from Yanshan. Acta Petrologica Mineralogica et Analytica. 3, 231–238.
Typ dokumentu
Bibliografia
Identyfikator YADDA
bwmeta1.element.baztech-9da0d534-2492-4a46-9b84-acab3dcb9480