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Comparative analysis of two processes for desulphurization of battery paste

Wybrane pełne teksty z tego czasopisma
Identyfikatory
Warianty tytułu
Języki publikacji
EN
Abstrakty
EN
Purpose: The paper touches the problem of recycling battery scrap and desulphurization methods. The aim of this paper is to compare sodium method and new amine method for desulphurization of battery paste. Also the comparison of this methods refers to environmental and technological aspects of lead smelting. Design/methodology/approach: Base of the comparison of two different methods were tests of melting of desulphurized battery paste in a rotary-tilting furnace by BJ Industries Company. Findings: Both methods of desulphurization allow to reduce amount of sulphur to less than 1%. The economic considerations determine the degree of desulphurization of battery paste. Amine method allows to reduce sulphur to a degree of about 0,5% maintaining favorable technical and economical parameters. Research limitations/implications: Effectiveness of amine method was confirmed in the pilot-scale tests, but it’s difficult to say what will be the results of desulphurization by this method in industrial scale. Originality/value: The value of this paper lies in demonstrating the possibilities of application of the new amine method of battery paste desulphurization, compared to for commonly used methods.
Rocznik
Strony
855--859
Opis fizyczny
Bibliogr. 14 poz., rys.
Twórcy
autor
  • BIPROMET S.A., ul. Graniczna 29, 40-956 Katowice, Poland
autor
  • BIPROMET S.A., ul. Graniczna 29, 40-956 Katowice, Poland
autor
  • BIPROMET S.A., ul. Graniczna 29, 40-956 Katowice, Poland
autor
  • BIPROMET S.A., ul. Graniczna 29, 40-956 Katowice, Poland
Bibliografia
  • [1] T.T. Chen, J.E. Dutrizac, The mineralogical characterization of lead - acid battery paste, Hydrometallurgy 40 (1996) 223-245.
  • [2] D. Andrews, A. Raychaudhuri, C. Frias, Environmentally sound technologies for recycling secondary lead, Journal of Power Sources 88 (2000) 124-129.
  • [3] D. Malak, Comparative analysis processes for desulphurization of battery paste, M.Sc. Thesis, June, 2010 (in Polish).
  • [4] A. Rodak, Development of conception industrial plant for desulphurisation of battery paste, M.Sc. Thesis, 2010 (in Polish).
  • [5] Report of the desulfurization of battery paste with melting process in the pilot plant scale in BJ furnace, Presentation of Institute of Nonferrous Metals (in Polish).
  • [6] Report of Institute of Nonferrous Metals nr 6670/0/09: The environmental impact of the new amine method of desulphurization battery paste, Gliwice, 2009 (in Polish).
  • [7] Report nr 9 from realization of the project: The new integrated technology of desulphurization battery paste using aqueous amine, Gliwice, 2009 (in Polish).
  • [8] D. Atanasova, N. Lyakov, V. Vassilev, G. Angelov, G. Haralampiev, Desulphurization of lead cake by sodium carbonate and sodium hydroxide, Journal of the University of Chemical Technology and Metallurgy 43/2 (2008) 267-252.
  • [9] M. Olper, M. Maccagni, Pb battery recycling new frontiers in paste desulphurization and lead production, Lead and Zinc (2008) 237-246.
  • [10] European patent specification, EP1140700B1, Process for the recovery of sulphur from lead - acid battery scrap, 1999.
  • [11] V.P. Yanakieva, G.Al. Haralampiev, N.K. Lyakov, Desulphurization of the damped lead battery paste with potassium carbonate, Journal of Power Sources 85/1 (2000) 178-180.
  • [12] D.A Begum, M.F. Islam, R.K. Biswas, A study on the dissolution of lead sulphate from waste batteries with ethanolamines, Hydrometallurgy 22/1-2 (1989) 259-266.
  • [13] M.S. Sonmez, R.V. Kumar, Leaching of waste battery paste components, Leaching and desulphurisation of PbSO4 by citric acid and sodium citrate solution, Hydrometallurgy 95 (2009) 82-86.
  • [14] European patent application Method for desulphurization of battery paste.
Typ dokumentu
Bibliografia
Identyfikator YADDA
bwmeta1.element.baztech-9d68e591-116a-432e-933b-35d0c64eeae9
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