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This paper presents initial findings from research into the possibility of using gypsum binders in quartz moulding sand that could be used in the production of casting moulds and cores. For the purposes of the research two commercial types of gypsum were used as binders: building gypsum and gypsum putty. Dry components of moulding sand i.e. medium quartz sand and gypsum were mixed in proportion of 89/11 parts by weight. In order to achieve bonding properties for the binders, 5 parts by weight of water was added to the mixture of dry components. After 24 hours of adding water and mixing all the components, the moulding sand, naturally hardened, was subjected to high temperature. The moulding sand thus produced, i.e. with cheap and environmentally-friendly gypsum binders, was eventually analysed after heating (at temperatures of 300oC, 650oC and 950oC) and cooling in order to determine changes in the following parameters: LOI – loss on ignition, chemical composition and pH. Moreover, investigated were bonding bridges, before and after the moulding sand was roasted. The research results revealed differences in the structure of bonding bridges and the occurrence of automatic adhesive destruction for both types of gypsum binders. For two types of moulding sands under the investigation of the LOI exceeded 2.59wt.% (with building gypsum) or 2.84wt.% (with putty gypsum) and pH increased to ca. 12 as a result of increasing roasting temperature from 300oC to 650oC. Next, roasting at 950oC decrease value of LOI in both types of moulding sands. Moulding sand with builoding gypsum roasted at 950oC revealed a return to the value of pH parameter measured prior to annealing.
Słowa kluczowe
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Tom
Strony
81--86
Opis fizyczny
Bibliogr. 25 poz., rys., tab.
Twórcy
autor
- Wroclaw University of Technology, Department of Foundry Engineering, Plastics and Automation, Wrocław, Poland
autor
- Wroclaw University of Technology, Department of Foundry Engineering, Plastics and Automation, Wrocław, Poland
autor
- Wroclaw University of Technology, Department of Foundry Engineering, Plastics and Automation, Wrocław, Poland
Bibliografia
- [1] Dolina Nidy (June 2017). History of gypsum application. Retrieved June 21, 2017, from http://www.dolinanidy.com.pl/historia-stosowania-gipsu.html. (in Polish).
- [2] Akerman, K. (1964). Gypsum and anhydrite. Warszawa: PWN. (in Polish).
- [3] Bartoszek, A. & Obłąg, L. (2012). Installation of wet flue gas desulphurisation in EC Siekierki. POL-EMIS 2012, 35-44. (in Polish).
- [4] Smakowski, T., Ney, R. & Galos, K. (2014). Balance of mineral resources management in Poland and the World 2012. Warszawa: Państwowy Instytut Geologiczny Państwowy Instytut Badawczy. (in Polish).
- [5] Mika-Gabała, A., Winnicki, T. & Pieniążek, T. 1980. Patent No. 121 063. Wrocław. PRL Patent Office. (in Polish).
- [6] Panchenko, A.I. & Kozlov, N. (2016). Water resistant gypsum binder. In International Scientific Conference IPICSE – 2016, 17 November 2016. Moscow, Russia: MATEC eb of Conferences 86.
- [7] Bajkow, A.A. (1948). Sobranie trudow, t. 5. Moskwa: AN SSSR.
- [8] PN-EN 13279-1:2009
- [9] Chłądzyński, S. & Pichniarczyk, P. (2006). Gypsum and gypsum products in European standards. Materiały Budowlane. 6(10), 42-46. (in Polish).
- [10] Zhang, Q., Kasai, E. & Saito, F. (1996). Mechanochemical changes in gypsum when dry ground with hydrated minerals. Powder Technology. 96(87), 67-71.
- [11] Matalkah, F., Bharadwaj, H., Balachandra, A. & Soroushian, P. (2017). Development and Charakterization of Gypsum-Based Binder. European Journal of Advances in Engineering and Technology. 4(3), 153-157.
- [12] Mehta, K.V., Jani, S.S. & Acharya, G.D. (2016). Influence of sulphur diffusion on the surface of furan no bake casting – a review. Trends in Mechanical Engineering & Technology. 16(6) 72-78.
- [13] Hosadyna, M., Dobosz, St.M. & Major-Gabryś, K. (2011). Influence of the hardener type on the sulphur diffusion from moulding sand to the casting surface. Archives of Foundry Engineering. 11(2), 87-92.
- [14] Dobosz, St.M. & Hosadyna, M. (2009). Method of limiting diffusion of sulfur from molding to casting. XXXIII Scientific Conference on the occasion of the national foundry day, 11 grudnia 2009. Kraków, Poland. (in Polish).
- [15] Hosadyna, M., Dobosz, St.M. & Jelinek, P. (2009). The diffusion of sulphur fro, moulding sand to cast and methods of its elimination. Archives of Foundry Engineering. 9(4), 73-76.
- [16] Qing, J., Lekakh, S. & Richards, V. (2013). No-Bake S- and Potential Application. American Foundry Society. Issue 2013.
- [17] Macioszczyk, A. & Dobrzyński, D. (2007). Hydrogeochemistry. Zones for active exchange of groundwater. Warszawa: PWN. (in Polish).
- [18] BN-70/4024-15.
- [19] Lewandowski, J.L. (1997). Materials for moulds. Cracow: Scientific Publishing House Akapit (in Polish).
- [20] Izdebska-Szanda, I. (2008). The study of correlation between the type and amount of modifier and high-temperature transformation sand residual strength of the masses with the modified sodium silicate. Prace Instytutu Odlewnictwa, Tom XLVIII, Sheet 1. (in Polish).
- [21] Dobosz, St.M., Jelinek, P. & Major-Gabryś, K. (2011). Development tendencies of moulding and core sands. China foundry. 8(4):438-446.
- [22] Blajerska, P. (2015). Influence of physico-chemical properties of sand grains of molding sand, heating in microwave, on electrical properties, deciding efficiency of process. Unpublished engineering thesis, Wroclaw: University of Science and Technology, Wrocław, Poland. (in Polish).
- [23] BN-89 6733-12.
- [24] Dolina Nidy company catalog (2013 Juli). Technical data sheet. Retrieved Januar 7, 2016, from http://www.dolina-nidy.com.pl/images/stories/pdf/gb.pdf.
- [25] Paduchowicz, P., Stachowicz, M. & Granat, K. (2017). Effect of Microwave Heating on Moulding Sand Properties with Gypsum Binder. Archives of Foundry Engineering. 17(3), 97-102.
Uwagi
PL
Opracowanie rekordu w ramach umowy 509/P-DUN/2018 ze środków MNiSW przeznaczonych na działalność upowszechniającą naukę (2018)
Typ dokumentu
Bibliografia
Identyfikator YADDA
bwmeta1.element.baztech-9d279ca7-4d2b-4843-a128-fc33eaadb2ac