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Studies on Viscoelastic, Thermal and Morphological Properties of Vinyl Ester - Mixed Diluents System

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Języki publikacji
EN
Abstrakty
EN
Vinyl ester resin networks formed by using mixture of diluents were prepared. Methyl methacrylate (MMA) diluent was mixed in various proportions with vinyl ester resin which was already premixed with styrene diluent (45 wt. %). Weight ratios e.g. 80:20, 70:30 and 60:40 of VE resin: MMA diluents were studied. Viscoelastic properties of the cross-linked resin were studied by dynamic mechanical analyzer in terms of storage modulus and tanδ. Thermal analysis was performed using non-isothermal mode of Differential scanning calorimetry. The samples with mixed diluents, showed higher modulus, and glass transition temperature in comparison to that of the pure vinyl ester-styrene resin cross-linked in presence of styrene only. The difference in thermal stability between vinyl ester-styrene and vinyl ester-MMA-styrene was checked. Vinyl Ester – 20 wt. % MMA-Styrene samples have the best thermal property among all other prepared samples. Multiphase morphology was formed for the thermoset crosslinked with mixed diluents in contrast to that formed with single diluent. With increase in MMA content in the resin dispersed domain size increased.
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Twórcy
autor
  • Department of Chemical Engineering, Birla Institute of Technology, Jharkhand-835215, India
  • Department of Chemical Engineering, Birla Institute of Technology, Jharkhand-835215, India
autor
  • Department of Chemical Engineering, Birla Institute of Technology, Jharkhand-835215, India
Bibliografia
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  • [7] R. E. Young, Unsaturated Polyester Technology, 1976, P. E. Bruins (Eds.), Gordon and Breach. New York.
  • [8] R. P. Brill, G. R. Palmese, J. Appl. Polym. Sci. 2784-2792 (2006).
  • [9] G. Odian, Principle of Polymerization, 1982, Wiley: New York.
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Uwagi
PL
Opracowanie rekordu w ramach umowy 509/P-DUN/2018 ze środków MNiSW przeznaczonych na działalność upowszechniającą naukę (2018).
Typ dokumentu
Bibliografia
Identyfikator YADDA
bwmeta1.element.baztech-9be1733f-65e1-42cb-abf0-5b3334cfca6f
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