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Leaching of chalcopyrite concentrate in hydrogen peroxide solution

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Identyfikatory
Warianty tytułu
Języki publikacji
EN
Abstrakty
EN
The leaching conditions of chalcopyrite (CuFeS2) concentrate in a hydrogen peroxide medium were investigated by studying the effects of its leaching parameters, such as stirring speed, temperature, hydrogen peroxide concentration and the particle size of the concentrate on Cu extraction. It was found that stirring speed has no effect on the leaching. Copper extraction from chalcopyrite is directly proportional to hydrogen peroxide concentration, but the extraction decreases at temperatures above 60°C. The maximum copper extraction was obtained with the following conditions without stirring: 240 min of leaching time, 3.0 M hydrogen peroxide concentration, 40°C leaching temperature and 53-75 m particle size fraction.
Słowa kluczowe
Rocznik
Strony
657--666
Opis fizyczny
Bibliogr. 29 poz., rys., tab.
Twórcy
autor
  • Selcuk University, Mining Engineering Department, 42075 Konya, Turkey
autor
  • Selcuk University, Mining Engineering Department, 42075 Konya, Turkey
autor
  • Selcuk University, Mining Engineering Department, 42075 Konya, Turkey
autor
  • Inonu University, Mining Engineering Department, 44280 Malatya, Turkey
Bibliografia
  • 1. AKCIL A., CIFTCI H., 2002. A study of the selective leaching of complex sulphides from the Eastern Black Sea Region, Turkey. Minerals Engineering 15 (6), 457–459.
  • 2. AL-HARAHSHEH M., KINGMAN S., AL-HARAHSHEH A., 2008. Ferric chloride leaching of chalcopyrite: Synergetic effect of CuCl2. Hydrometallurgy 91, 89–97.
  • 3. ALTUNDOGAN H.S., BOYRAZLI M., TUMEN F., 2004. A study on the sulphuric acid leaching of copper converter slag in the presence of dichromate. Minerals Engineering 17, 465–467.
  • 4. ANTONIJEVIC M.M., JANKOVIC Z.D., DIMITRIJEVIC M.D., 1994. Investigation of the kinetics of chalcopyrite oxidation by potassium dichromate. Hydrometallurgy 35, 187–201.
  • 5. ANTONIJEVIC M.M., DIMITRIJEVIC M., JANKOVIC Z., 1997. Leaching of pyrite with hydrogen peroxide in sulfuric acid. Hydrometallurgy 46, 71–83.
  • 6. ANTONIJEVIC M.M., JANKOVIC Z.D., DIMITRIJEVIC M.D., 2004. Kinetics of chalcopyrite dissolution by hydrogen peroxide in sulphuric acid. Hydrometallurgy 7, 329–334.
  • 7. AYDOGAN S., UCAR G., CANBAZOGLU M., 2006. Dissolution kinetics of chalcopyrite in acidic potassium dichromate solution. Hydrometallurgy 81, 45–51.
  • 8. BALAZ P., BRIANCIN J., 1990. Leaching and properties of mechanically activated chalcopyrite. Fizykochemiczne problemy mineralurgii 22, 193–200.
  • 9. CORDOBA E.M., MUNOZ J.A., BLAZQUEZ M.L., GONZALEZ F., BALLESTER A., 2008. Leaching of chalcopyrite with ferric ion. Part I: General aspects. Hydrometallurgy 93, 81–87.
  • 10. DOLD B., 2005. Basic Concepts of Environmental Geochemistry of Sulfide Mine-Waste. XXIV Curso Latinoamericano de Metalogenia UNESCO–SEG, Lima, Peru.
  • 11. DUTRIZAC J.E., 1990. Elemental sulfur formation during the ferric chloride leaching of chalcopyrite. Hydrometallurgy 23, 153–176.
  • 12. HABASHI F. 1978. Chalcopyrite, its Chemistry and Metallurgy, McGraw-Hill, New York.
  • 13. HABASHI F., 1999. A Textbook of Hydrometallurgy. Métallurgie Extractive Québec, second edition, 750 p. Canada.
  • 14. HIRATO T., MAJIMA H., AWAKURA Y., 1987. The leaching of chalcopyrite with ferric sulphate. Metall. Trans. B 18B, 489–496.
  • 15. IKIZ D., GULFEN M., AYDIN A.O., 2006. Dissolution kinetics of primary chalcopyrite ore in hypochlorite solution. Minerals Engineering 19, 972–974.
  • 16. LIDDICOAT J., DREISINGER D., 2007. Chloride leaching of chalcopyrite. Hydrometallurgy 89, 323–331.
  • 17. LUNDSTROM M., AROMAA J., FORSEN O., HYVARINEN O., BARKER M.H., 2005. Leaching of chalcopyrite in cupric chloride solution. Hydrometallurgy 77, 89–95.
  • 18. MAHAJAN V., MISRA M., ZHONG K., FUERSTENAU M.C., 2007. Enhanced leaching of copper from chalcopyrite in hydrogen peroxide–glycol system. Minerals Engineering 20, 670–674.
  • 19. NAZARI G., ASSELIN E., 2009. Morphology of chalcopyrite leaching in acidic ferric sulfate media. Hydrometallurgy 96, 183–188.
  • 20. PADILLA R., VEGA D., RUIZ M.C., 2007. Pressure leaching of sulfidized chalcopyrite in sulfuric acid–oxygen media. Hydrometallurgy 86, 80–88.
  • 21. PLUMLEE G.S., 1999. The environmental geology of mineral deposits. In: Plumlee, G. S. and Logsdon, M.J. (Eds.) Reviews in Economic Geology, The environmental geochemistry of ore deposits. Part A: Processes, Techniques, and Health Issues, v. 6A, 71–116.
  • 22. PUVVADA G.V.K., MURTH, D.S.R., 2000. Selective precious metals leaching from a chalcopyrite concentrate using chloride/hypochlorite media. Hydrometallurgy 58, 185–191.
  • 23. SKROBIAN M., HAVLIK T., UKASIK M., 2005. Effect of NaCl concentration and particle size on chalcopyrite leaching in cupric chloride solution. Hydrometallurgy 77, 109–114.
  • 24. SOKIC M.D., MARKOVIC B., ZIVKOVIC D., 2009. Kinetics of chalcopyrite leaching by sodium nitrate in sulphuric acid. Hydrometallurgy 95, 273–279.
  • 25. TCHOUMOU M., ROYNETTE M., 2007. Leaching of complex sulphide concentrate in acidic cupric chloride solutions. Trans. Nonferrous Met. Soc. China 17, 423–428.
  • 26. TURAN M.D., ALTUNDOGAN H.S., 2013. Leaching of chalcopyrite concentrate with hydrogen peroxide and sulfuric acid in an autoclave system. Metallurgical and Materials Transactions 44B, 809–819.
  • 27. VANHANEN M.R., 1999. Finnish expert report on best available techniques in copper production and by-production of precious metals. The Finnish Environment, Finland.
  • 28. YEVENES L.V., MIKI H., NICOL M., 2010. The dissolution of chalcopyrite in chloride solutions: Part 2: Effect of various parameters on the rate. Hydrometallurgy 103, 80–85.
  • 29. YOO K., KIM S., LEE J., ITO, M., TSUNEKAWA M., HIROYOSHI N., 2010. Effect of chloride ions on leaching rate of chalcopyrite. Minerals Engineering 23, 471–477.
Typ dokumentu
Bibliografia
Identyfikator YADDA
bwmeta1.element.baztech-9b35cf1b-e558-4a59-b8b1-362d81261cde
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