PL EN


Preferencje help
Widoczny [Schowaj] Abstrakt
Liczba wyników
Tytuł artykułu

Ammonium Dodecahydrododecaborate (NH4)2[B12H12]: Hydrogen and Boron Rich Fuel for Jet Propulsion Engines

Treść / Zawartość
Identyfikatory
Warianty tytułu
Języki publikacji
EN
Abstrakty
EN
There is dire need for the exploration of boron (B) substitution in jet propulsion engines for improving their combustion characteristics. In this regard, ammonium dodecahydrododecaborate (NH4)2[B12H12] has been synthesized, characterized and evaluated for its propulsion characteristics. This hydrogen and boron-rich entity was found to be a potential candidate for future applications in propulsion technology.
Słowa kluczowe
Rocznik
Strony
158--167
Opis fizyczny
Bibliogr. 19 poz., rys., tab.
Twórcy
  • High Energy Materials Research Laboratory, Pune 411021, India
autor
  • Institute of Chemical Technology, Indian Oil Odisha Campus, Bhubaneswar 751073, India
  • High Energy Materials Research Laboratory, Pune 411021, India
autor
  • High Energy Materials Research Laboratory, Pune 411021, India
Bibliografia
  • [1] Møller, K.T.; Jensen, T.R.; Akiba, E.; Li, H.-w. Hydrogen ‒ A Sustainable Energy Carrier. Prog. Nat. Sci.: Mater. Int. 2017, 27(1): 34-40.
  • [2] Choubey, G.; Yuvarajan, D.; Huang, W.; Yan, L.; Babazadeh, H.; Pandey, K.M. Hydrogen Fuel in Scramjet Engines ‒ A Brief Review. Int. J. Hydrogen Energy 2020, 45(33): 16799-16815.
  • [3] Agrawal, J.P. Recent Trends in High-Energy Materials. Prog. Energy Combust. Sci. 1998, 24(1): 1-30.
  • [4] Goroshin, S.; Higgins, A.; Kamel, M. Powdered Metals as Fuel for Hypersonic Ramjets. 37th Joint Propulsion Conference and Exhibit, Salt Lake City, US, 2001.
  • [5] Liu, L.-L.; He, G.-Q.; Wang, Y.-H.; Hu, S.-Q. Ignition and Combustion Performance of the Primary Condensed-phase Combustion Products from Boron-based Fuel-rich Propellants. Cent. Eur. J. Energ. Mater. 2017, 14(2): 448-460.
  • [6] Haddad, A.; Natan, B.; Arieli, R. The Performance of a Boron-loaded Gel-fuel Ramjet. In: Progress in Propulsion Physics. Vol. 2, European Conference for AeroSpace Sciences (EUCASS), 2011, pp. 499-518.
  • [7] Xiao, Y.-L.; Xia, Z.; Huang, L.Y.; Ma, L.K.; Yang, D.L. Numerical Simulation of the Flowfield in a Boron-Based Slurry Fuel Ramjet. Combust. Explos. Shock Waves 2019, 55(3): 361-371.
  • [8] Ojha, P.K.; Karmakar, S. Combustion Characteristics of Jet A-1 Droplet Loaded with Aluminum/Magnesium-Decorated Boron Particles. Int. J. Energ. Mater. Chem. Propul. 2020, 19(3): 253-274.
  • [9] Lee, J.G.; Weismiller, M.; Connell, T.L.; Risha, G.A.; Yetter, R.A.; Gilbert, P.D.; Son, S.F. Ammonia Borane-based Propellants. 44th AIAA/ASME/SAE/ASEE Joint Propulsion Conference and Exhibit, Hartford, US, 2008.
  • [10] Sivaev, I.B.; Bregadze, V.I.; Sjöberg, S. Chemistry of Closo-dodecaborate Anion [B12H12]2‒: A Review. Collect. Czech. Chem. Commun. 2002, 67(6): 679-727.
  • [11] Geis, V.; Guttsche, K.; Knapp, C.; Scherer, H., Uzun, R. Synthesis and Characterization of Synthetically Useful Salts of the Weakly-coordinating Dianion [B12Cl12]2−. Dalton Trans. 2009, 15: 2687-2694.
  • [12] Kiruthika, S.; Fjellvåg, H.; Ravindran, P. Amphoteric Behavior of Hydrogen (H+1 and H−1) in Complex Hydrides from van der Waals Interaction ‒ Including Ab Initio Calculations. J. Mater. Chem. A 2019, 7(11): 6228-6240.
  • [13] McBride, B.; Gordon, G. Chemical Equilibrium Program CEA2: NASA Glenn Research Center, Cleveland, OH; 2004. Report NASA RP-1311, Part I, 1994.
  • [14] Yisgedu, T.B.; Huang, Z.; Chen, X.; Lingam, H.K.; King, G.; Hingley, A.; Zhao, J.C. The Structural Characterization of (NH4)2B10H10 and Thermal Decomposition Studies of (NH4)2B10H10 and (NH4)2B12H12. Int. J. Hydrogen Energy 2012, 37(5): 4267-4273.
  • [15] Ivanov, S.V.; Miller, S.M.; Anderson, O.P.; Solntsev, K.A.; Strauss, S.H. Synthesis and Stability of Reactive Salts of Dodecafluoro-closo-dodecaborate(2−). J. Am. Chem. Soc. 2003, 125(16): 4694-4695.
  • [16] Jain, A.; Joseph, K.; Anthonysamy, S.; Gupta, G.S. Kinetics of Oxidation of Boron Powder. Thermochim. Acta 2011, 514(1-2): 67-73.
  • [17] Clark, J.D. Ignition!: An Informal History of Liquid Rocket Propellants. Rutgers University Press, New Brunswick, 1972; ISBN 0-8135-0725-1.
  • [18] Kadosh, H.; Natan, B. Internal Ballistics of a Boron-Containing Solid Fuel Ramjet. Combust. Sci. Technol. 2020, 93(15): 2672-2691.
  • [19] Sun, W.Q.; Wolverton, C.; Akbarzadeh, A.R.; Ozolins, V. First-principles Prediction of High-capacity, Thermodynamically Reversible Hydrogen Storage Reactions based on (NH4)2B12H12. Phys. Rev. B 2011, 83(6) paper 064112.
Typ dokumentu
Bibliografia
Identyfikator YADDA
bwmeta1.element.baztech-9b34be2e-9687-401e-b1ab-e323f5447449
JavaScript jest wyłączony w Twojej przeglądarce internetowej. Włącz go, a następnie odśwież stronę, aby móc w pełni z niej korzystać.