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In recent years, Polymer Bonded Explosives (PBX) have been used in a wide variety of military applications. Many different kinds of polymers are used for such explosive formulations. This component determines both the preparation method and the properties of a PBX. In this paper, results are presented of studies on the preparation and testing of explosive compositions based on pentaerythritol tetranitrate (PETN, penthrite) and silicone rubber. These studies were undertaken to obtain elastic formulations of PBXs. Therefore, the possibility of applying a silicone rubber as a component of the composition was checked. In the first stage of this study, several compositions were prepared in order to choose the optimal mixture ratio with respect to cohesion of the explosive. For this purpose, a new method using the Brookfield Texture Analyser was developed. Subsequently, compatibility tests using thermal analysis methods were carried out. The best of composition was subjected to tests for determining its physicochemical and explosive characteristics.
Słowa kluczowe
Rocznik
Tom
Strony
545--569
Opis fizyczny
Bibliogr. 27 poz., rys., tab.
Twórcy
autor
- Military Institute of Armament Technology, 7 Prymasa Stefana Wyszyńskiego Street, 05-220 Zielonka, Poland
autor
- Military Institute of Armament Technology, 7 Prymasa Stefana Wyszyńskiego Street, 05-220 Zielonka, Poland
autor
- Military Institute of Armament Technology, 7 Prymasa Stefana Wyszyńskiego Street, 05-220 Zielonka, Poland
autor
- Łukasiewicz Research Network – Institute of Industrial Organic Chemistry, 6 Annopol Street, 03-236 Warsaw, Poland
Bibliografia
- [1] Kaye, S.M. Encyclopedia of Explosives and Related Items; Vol. 8, US Arradcom Dover- New Jersey, 1978.
- [2] Liu, R.; Han, Y.; Li, M.; Jiang, Z.; He, S. Shock Ignition and Growth of HMXBased PBXs under Different Temperature Conditions. Cent. Eur. J. Energ. Mater. 2019, 16(1): 21-32.
- [3] Zhang, Q.; Shu, Y.; Liu, N.; Lu, X.; Shu, Y.; Wang, X.; Mo, H.; Xu, M. Hydroxyl Terminated Polybutadiene: Chemical Modification and Application of These Modifiers in Propellants and Explosives; Cent. Eur. J. Energ. Mater. 2019, 16(2): 153-194.
- [4] Li, Y.; Wu, P.; Hua, C.; Wang, J.; Huang, B.; Chen, J.; Qiao, Z.; Yang, G. Determination of the Mechanical and Thermal Properties, and Impact Sensitivity of Pressed HMX-Based PBX. Cent. Eur. J. Energ. Mater. 2019, 16(2): 299-235.
- [5] Dai, X.; He, S.; Huang, X.; Yang, Z.; Wen, Y.; Li, M. Experimental Investigation of the Effect of Polymers and Crystalline Qualities on the Safety Performance of LLM-105-Based PBXs under Dynamic Compression and Shear. Cent. Eur. J. Energ. Mater. 2020, 17(2): 201-222.
- [6] Singh, A.; Sharma, T.C.; Kumar, M. Effect of the Molecular Structure and Molecular Weight of Poly (Vinylidene Fluoride-Chlorotrifluoroethylene) Copolymers on the Characteristic Properties of TATB-Based Composites. Cent. Eur. J. Energ. Mater. 2020, 17(3): 428-450.
- [7] Persson, I. Water Resistant Elastic Explosive Mixture. US Patent 5238512, 1993.
- [8] Cooper, P. Explosives Engineering; Wiley-VCH, New York, 1996.
- [9] Meyer, R.; Köhler, J.; Homburg, A. Explosives; Wiley-VCH, Weinheim, 2002.
- [10] Anderson, P.E.; Cook, P.; Davis, A.; Mychajlonka, K.; Mileham, M. Silicon Fuel in High Performance Explosives. Propellants Explos. Pyrotech. 2014, 39(1): 74-78.
- [11] Chyłek, Z.; Jurkiewicz, R. Investigation of the Properties of Polymer Bonded Explosives Based on 1,1-Diamino-2,2-Dinitroethene (FOX-7) and 1,3,5,7-Tetranitro-1,3,5,7-Tetraazacyclooctane (HMX). Cent. Eur. J. Energ. Mater. 2016, 13(4): 859-870.
- [12] Elbeih, A.; Zeman, S.; Jungova, M.; Akstein, Z. Effect of Different Polymeric Matrices on the Sensitivity and Performance of Interesting Cyclic Nitramines. Cent. Eur. J. Energ. Mater. 2012, 9(2): 131-138.
- [13] Lee, J.S.; Jaw, K.S. Thermal Decomposition Properties and Compatibility of CL-20, NTO with Silicone Rubber. J. Therm. Anal. Calorim. 2006, 2(85): 463-467.
- [14] Lee, J.S.; Hsu, C.K.; Chang, C.L. A Study on the Thermal Decomposition Behaviors of PETN, RDX, HNS and HMX. Thermochim. Acta 2002, 392-393: 173-176.
- [15] Jaw, K.S.; Lee, J.S. Thermal Behaviors of PETN Based Polymer Bonded Explosives. J. Therm. Anal. Calorim. 2008, 93(3): 953-957.
- [16] Tai, A.; Bianchini, R.; Jachowicz, J. Texture Analysis of Cosmetic/Pharmaceutical Raw Materials and Formulations. Int. J. Cosmet. Sci. 2014, 36(4): 291-304.
- [17] McAteer, D.; Weaver, M.; Blair, L.H.; Flood, N.; Gaulter, S. Compatibility Assessment of Thermoplastic Formulations. Proc. 19th Semin. New Trends Res. Energ. Mater. 2016, 401-409.
- [18] Stanković, M.; Dimić, M.; Blagojević, M.; Petrović, S.; Mijin, D. Compatibility Examination of Explosive and Polymer Materials by Thermal Methods. Sci.-Tech. Rev 2003, 53: 25-29.
- [19] Singh, A.; Kumar, R.; Soni, P.K.; Singh, V. Compatibility and Thermal Decomposition Kinetics between HMX and Some Polyester-Based Polyurethanes. J. Therm. Anal. Calorim. 2020: 1-13.
- [20] Myburgh, A. Standardization on Stanag Test Methods for Ease of Compatibility and Thermal Studies. J. Therm. Anal. Calorim. Springer, 2006, 85(1): 135-139.
- [21] Vogelsanger, B. Chemical Stability, Compatibility and Shelf Life of Explosives. Chim. Int. J. Chem. 2004, 58(6): 401-408.
- [22] NATO STANAG 4147: Chemical Compatibility of Ammunition Components with Explosives (Non-Nuclear Applications). Edition 2, 2001.
- [23] PN-V-04011-21:1998: Military High Explosives – Methods of Testing – Determination of the Stability. (in Polish) 1998.
- [24] Jaffe, I.; Price, D. Determination of the Critical Diameter of Explosive Materials. ARS J. 1962, 32(7): 1060-1065.
- [25] Smith, L.C. On Brisance, and a Plate-Denting Test for the Estimation of Detonation Pressure. Technical Raport. Los Alamos Scientific Lab., NM, 1963.
- [26] EN-13631-4:2002: High Explosives for Civil Uses – High Explosives Determination of Sensistiveness to Impact of Explosives. 2002.
- [27] EN-13631-3:2004: High Explosives for Civil Uses – High Explosives Determination of Sensistiveness to Friction of Explosivese. 2004.
Typ dokumentu
Bibliografia
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