The utilization of the mesoporous Ti-SBA-15 catalyst in the epoxidation of allyl alcohol to glycidol and diglycidyl ether in the water medium

• Autorzy: Wróblewska A. , Makuch E. , Dzięcioł M. , Jędrzejewski R. , Kochmański P. , Kochmańska A. , Kucharski Ł.

Identyfikatory

DOI

10.1515/pjct-2015-0064

• Języki publikacji: EN

Abstrakty

EN

This work presents the studies on the optimization the process of allyl alcohol epoxidation over the Ti-SBA-15 catalyst. The optimization was carried out in an aqueous medium, wherein water was introduced into the reaction medium with an oxidizing agent (30 wt% aqueous solution of hydrogen peroxide) and it was formed in the reaction medium during the processes. The main investigated technological parameters were: the temperature, the molar ratio of allyl alcohol/hydrogen peroxide, the catalyst content and the reaction time. The main functions the process were: the selectivity of transformation to glycidol in relation to allyl alcohol consumed, the selectivity of transformation to diglycidyl ether in relation to allyl alcohol consumed, the conversion of allyl alcohol and the selectivity of transformation to organic compounds in relation to hydrogen peroxide consumed. The analysis of the layer drawings showed that in water solution it is best to conduct allyl alcohol epoxidation in direction of glycidol (selectivity of glycidol 54 mol%) at: the temperature of 10–17°C, the molar ratio of reactants 0.5–1.9, the catalyst content 2.9–4.0 wt%, the reaction time 2.7–3.0 h and in direction of diglycidyl ether (selectivity of diglycidyl ether 16 mol%) at: the temperature of 18–33°C, the molar ratio of reactants 0.9–1.65, the catalyst content 2.0–3.4 wt%, the reaction time 1.7–2.6 h. The presented method allows to obtain two very valuable intermediates for the organic industry.

Słowa kluczowe

EN

glycidol; diglycidyl ether; Ti-SBA-15 catalyst; allyl alcohol epoxidation; hydrogen peroxide

• Wydawca: West Pomeranian University of Technology. Publishing House
• Czasopismo: Polish Journal of Chemical Technology
• Rocznik: 2015
• Tom: Vol. 17, nr 4
• Strony: 23--31
• Opis fizyczny: Bibliogr. 33 poz., rys., tab.

Twórcy

autor

Wróblewska A.

• West Pomeranian University of Technology, Szczecin, Institute of Organic Chemical Technology, Pułaskiego 10, 70-322 Szczecin, Poland

autor

Makuch E.

• West Pomeranian University of Technology, Szczecin, Institute of Organic Chemical Technology, Pułaskiego 10, 70-322 Szczecin, Poland

autor

Dzięcioł M.

• West Pomeranian University of Technology, Szczecin, Institute of Organic Chemical Technology, Pułaskiego 10, 70-322 Szczecin, Poland

autor

Jędrzejewski R.

• West Pomeranian University of Technology, Szczecin, Faculty of Mechanical Engineering and Mechatronics, Institute of Materials Science and Engineering, Piastów 19, 70-322 Szczecin, Poland

autor

Kochmański P.

• West Pomeranian University of Technology, Szczecin, Faculty of Mechanical Engineering and Mechatronics, Institute of Materials Science and Engineering, Piastów 19, 70-322 Szczecin, Poland

autor

Kochmańska A.

• 2West Pomeranian University of Technology, Szczecin, Faculty of Mechanical Engineering and Mechatronics, Institute of Materials Science and Engineering, Piastów 19, 70-322 Szczecin, Poland

autor

Kucharski Ł.

• Pomeranian Medical University, Dermatopharmacotherapy Division, Department of Dermatology, Powstańców Wielkopolskich 72, 70-111 Szczecin, Poland

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