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Kinetics of extraction of phenolic compounds and flavonoids from Carlina acaulis

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EN
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EN
The study of the kinetics of extraction of phenolic compounds and flavonoids from crushed roots of Carlina acaulis using 40% and 70% of water-ethanol mixture by infusion method is described in the article. The total value of the mass transfer coefficient and the value of the transfer coefficient through the cell wall, in the intercellular space and the volume of the extractant were determined. Particles of Carlina acaulis roots of different sizes (0.2, 0.3, 0.5 mm) were studied; different concentrations of ethyl alcohol were used - 40% and 70%; the ratio of raw materials: extractant was 1:10. The analytical dependence of the mass transfer coefficient k and the leaching coefficient A on the solid particle size d and the concentration of the extractant was obtained, which allows to predict the extraction process and to design equipment for the technological process in production. Kinetic equations of the process of extraction of phenolic compounds and flavonoids from Carlina acaulis roots by infusion method are derived. The obtained equations allow to determine the concentrations of phenolic compounds and flavonoids in the extracts at a given point in time with a particle size of the solid phase from 1 to 10 mm, as well as to determine the optimal diameter of the solid phase particles for maximum extraction of the target substance.
Twórcy
  • Lviv Polytechnic National University, Lviv, Ukraine
  • Lviv Polytechnic National University, Lviv, Ukraine
  • Lviv Polytechnic National University, Lviv, Ukraine
  • Lviv Polytechnic National University, Lviv, Ukraine
Bibliografia
  • 1. Semenyshyn Ye., Trotskyy V., et. al. 1991. Kinetics of extraction of components from plants raw materials, Pharmaceutical Journal, No5, pp. 60-64. [in Ukrainian].
  • 2. Semenyshyn Ye., Kobylnik I., Bodnar P. 1991. Problems of extraction of target components from plant and mineral raw materials, in Proceedings of the VIII Republics. conf. "Increasing the efficiency of improving the processes and devices of chemical production", Dniepropetrovsk, p. 63 [in Russian].
  • 3. Semenyshyn Ye., Trotskyy V., Bodnar P. 1993. Extraction of target components from plant and mineral raw materials, Journal of Applied Chemistry, Vol. 66. Iss. 10, pp. 2311–2314 [in Russian].
  • 4. Semenyshyn E. M., Trotsky V. I., Bodnar P. N. 1992. The problem оf the desired components extraction from vegetable raw and minerals, ISECOS-92 conferens papers Voroneg Technological Institute, Vol. 2, pp. 83–84.
  • 5. Semenyshyn Ye. 1983. Theoretical Foundations of Solid Phase Extraction from Porous Structures, Doctoral thesis, Lviv, 367 p. [in Ukrainian]. 6. Semenishyn E., Huglich J., Trocki W., Broda O. 1995. Model matematyczna procesu ekstrakcji w aparatach odzialany uciaglym, in Proceedings of the XV Scientific conference in chemical and processes engineering, Gdansk, Vol. III, pp. 71–75 [in Polish].
  • 7. Semenyshyn Ye., Trotskyy V. Fedorchuk-Moroz V. 2002. Mathematical model of countercurrent extraction of target components from beet pulp, Bulletin of the Lviv Polytechnic National University: Chemistry, technology and their applications Series, No. 461, pp. 211–214 [in Ukrainian].
  • 8. Semenyshyn Ye., Trotskyy V. Petrushka I. Fedorchuk-Moroz V. 2002. Kinetics of extraction of pectins and polysaccharides from beet pulp, Bulletin of the Lviv Polytechnic National University: Chemistry, technology and their applications Series, No. 461, pp. 238–242 [in Ukrainian].
  • 9. Semenyshyn Ye., Trotskyy V. Fedorchuk-Moroz V. 2003. Kinetics of extraction of target components from malt sprouts, The Scientific Bulletin, Lviv, Iss. 13.1, pp. 143–146 [in Ukrainian].
  • 10. Dyachok V. 2001. Mathematical model of the extraction process from plants raw materials, Сhemical industry of Ukraine, Iss.4, pp. 52 –55 [in Ukrainian].
  • 11. Dyachok V. 2001. Kinetics of extraction of a mixture of vegetable raw materials // Pharmaceutical Journal, No. 6, pp. 71–75 [in Ukrainian].
  • 12. Dyachok V. 1998. Influence of temperature on mass transfer coefficient during extraction of plants raw materials, Сhemical industry of Ukraine No. 2, pp. 44–46 [in Ukrainian].
  • 13. Strzemski M., Wójciak-Kosior M., Sowa I., Załuski D., Verpoorte R. 2019. Historical and traditional medical applications of Carlina acaulis L. A critical ethnopharmacological review. Journal of Ethnopharmacology. V. 239. 111842. doi.org/10.1016/j.jep.2019.111842.
  • 14. Dordevic S., Tadic V., Petrovic S., Kukic-Markovic J., Dobric S., Milenkovic M., Hadzifejzovic N. 2012. Bioactivity assays on Carlina acaulis and C. acanthifolia root and herb extracts. Digest Journal of Nanomaterials and Biostructures, Vol. 7, No. 3, pp. 1213–1222.
  • 15. Link P., Roth K., Sporer F., Wink, M. 2016. Carlina acaulis exhibits antioxidant activity and counteracts. A toxicity in Caenorhabditis elegans. Molecules and Cells. Vol. 21(7), pp. 1-10. doi.org/10.3390/molecules21070871
  • 16. Polova, Zh., Popovych P. Glukhovskyy P. 2012. The use of nanosized trace elements as active ingredients in cosmetics, Current issues of pharmaceutical and medical science and practice, No.1 (8), pp. 74-77 [in Ukrainian].
  • 17. Dyachok V. 2010. Scientific and theoretical bases of extraction of medicinal plant raw materials, Doctoral thesis abstact, Kyiv, 41 p.
  • 18. Dyachok V. 2010. Extraction process of intracellular substance, Chemistry & chamical technology, Vol. 4, Issue 2, pp. 163-167.
  • 19. Dyachok V., Malovanyy M., Ilkiv I. 2011. Some kinetic regularites of intracellular substancec extracting, Chemistry & chamical technology, Vol. 6, Issue 4, pp. 469-472.
Uwagi
Opracowanie rekordu ze środków MNiSW, umowa Nr 461252 w ramach programu "Społeczna odpowiedzialność nauki" - moduł: Popularyzacja nauki i promocja sportu (2021).
Typ dokumentu
Bibliografia
Identyfikator YADDA
bwmeta1.element.baztech-99eaf103-aa94-4167-90d5-ebe25c24aca7
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