Oxalate Intercalated Mg/Cr Layered Double Hydroxide as Adsorbent of Methyl Red and Methyl Orange from Aqueous Solution

• Autorzy: Badri Arini Fousty , Juleanti Novie , Palapa Neza Rahayu , Hanifah Yuliza , Mohadi Risfidian , Mardiyanto , Lesbani Aldes

Identyfikatory

DOI

10.12912/27197050/135509

• Języki publikacji: EN

Abstrakty

EN

Mg/Cr layered double hydroxide (LDH) has been successfully synthesized by means of the coprecipitation method followed by the intercalation process using oxalate to form Mg/Cr-oxalate. The materials were characterized using XRD, BET, and FTIR and then applied as an adsorbent of anionic dyes i.e. methyl red (MR) and methyl orange (MO). MR and MO adsorption was studied through variations of adsorption time, concentration, temperature, desorption process, and adsorbent regeneration. The XRD characterization results showed an increase in the interlayer distance from 7.62 Å to 11.35 Å after the intercalation process. The increase of interlayer space of Mg/Cr-oxalate is also equal to the BET data, which shows an increase in surface area from 21.511 m²/g to 49.270 m²/g. The kinetics and isotherm parameters of MR and MO adsorption using Mg/Cr LDH and Mg/Cr-oxalate showed the same results following the PFO kinetics model and Langmuir isotherm model with R² close to one. Mg/Cr LDH has the adsorption capacity for MR and MO up to 61.728 mg/g 54.645 mg/g, respectively. In turn, the highest adsorption capacity is achieved by Mg/Cr-oxalate for MR adsorption at 81.235 mg/g and MO at 71.429 mg/g. The thermodynamic parameters of MR and MO adsorption using Mg/Cr LDH and Mg/Cr-oxalate indicate that the adsorption process is endothermic and spontaneous.

Słowa kluczowe

EN

layered double hydroxide; dyes; adsorption; intercalation; kinetic; thermodynamic

• Wydawca: Lubelski Oddział Polskiego Towarzystwo Inżynierii Ekologicznej ; Lublin University of Technology ; WNGB Wydawnictwo Naukowe
• Czasopismo: Ecological Engineering & Environmental Technology
• Rocznik: 2021
• Tom: Vol. 22, iss. 3
• Strony: 71--81
• Opis fizyczny: Bibliogr. 24 poz., rys., tab.

Twórcy

autor

Badri Arini Fousty

• Graduate School of Mathematics and Natural Sciences, Universitas Sriwijaya, Jl. Raya Palembang-Prabumulih, Km. 32, Ogan Ilir 30662, South Sumatra, Indonesia

• https://orcid.org/0000-0001-9735-3547

autor

Juleanti Novie

• Department of Chemistry, Faculty of Mathematics and Natural Sciences, Universitas Sriwijaya, Jl. Raya Palembang Prambumulih Km. 32, Ogan Ilir 30662, South Sumatra, Indonesia

• https://orcid.org/0000-0002-3334-4139

autor

Palapa Neza Rahayu

• Graduate School of Mathematics and Natural Sciences, Universitas Sriwijaya, Jl. Raya Palembang-Prabumulih, Km. 32, Ogan Ilir 30662, South Sumatra, Indonesia

• https://orcid.org/0000-0003-3857-2680

autor

Hanifah Yuliza

• Research Center of Inorganic Materials and Complexes, Faculty of Mathematics and Natural Sciences, Universitas Sriwijaya, Palembang 30139, Indonesia

• https://orcid.org/0000-0003-4152-5367

autor

Mohadi Risfidian

• Department of Chemistry, Faculty of Mathematics and Natural Sciences, Universitas Sriwijaya, Jl. Raya Palembang Prambumulih Km. 32, Ogan Ilir 30662, South Sumatra, Indonesia
• Research Center of Inorganic Materials and Complexes, Faculty of Mathematics and Natural Sciences, Universitas Sriwijaya, Palembang 30139, Indonesia

• https://orcid.org/0000-0003-4974-4329

autor

Mardiyanto

• Department of Pharmacy, Faculty of Mathematics and Natural Sciences, Universitas Sriwijaya, Jl. Raya Palembang-Prabumulih, Km. 32, Ogan Ilir 30662, South Sumatra, Indonesia

• https://orcid.org/0000-0002-7782-4417

autor

Lesbani Aldes

• Graduate School of Mathematics and Natural Sciences, Universitas Sriwijaya, Jl. Raya Palembang-Prabumulih, Km. 32, Ogan Ilir 30662, South Sumatra, Indonesia
• Research Center of Inorganic Materials and Complexes, Faculty of Mathematics and Natural Sciences, Universitas Sriwijaya, Palembang 30139, Indonesia

• https://orcid.org/0000-0001-5054-2324

Bibliografia

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Uwagi

Opracowanie rekordu ze środków MNiSW, umowa Nr 461252 w ramach programu "Społeczna odpowiedzialność nauki" - moduł: Popularyzacja nauki i promocja sportu (2021).