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Cleaning and Management of Water Contaminated with Pesticides through the Process of Adsorption in the Natural Clay of Brari

Treść / Zawartość
Identyfikatory
Warianty tytułu
Języki publikacji
EN
Abstrakty
EN
This study aimed to investigate the potential for widespread application of clay in the purification of water polluted with pesticides and water management through the absorption and desorption of dimethoate and methomyl in the natural clay of Brari (Tirana). While the maximum adsorption of methomyl on Brari clay was reached in 12 hours, the maximum adsorption of dimethoate on Brari clay was reached in 48 hours. To compare the adsorption of methomyl and dimethoate on Brari clay, their water degradation time was also taken into account. Dimethoate dissolves quickly; a contact period of 1–2 hours is sufficient to desorb 81.2% of the material. Dimethoate dissolves in water at 25 °C and has a half-life t1/2 = 30 days. Methomyl is desorbed even faster; in just two hours, 96.2% of the material is desorbed. At 25 °C, dimethoate has a half-life of t1/2 = 14 days and a high solubility of 58 g/L in water. Because methomyl and dimethoate bind poorly to clay, they can contaminate surface and groundwater.
Słowa kluczowe
Twórcy
autor
  • Departament of Chemistry, Faculty of Natural and Mathematics Sciences, University of Prishtina, Kosova
  • Departament of Health Managment, Alma Matter Europaea, Campus College” Rezonanca”, Kosova
  • Faculty of Natural Sciences, Department of Chemistry, University of Tirana, Tirana, Albania
autor
  • Faculty of Natural Sciences, Department of Chemistry, University of Tirana, Tirana, Albania
  • Faculty of Natural Sciences, Department of Chemistry, University of Tirana, Tirana, Albania
autor
  • Faculty of Natural Sciences and Mathematics, University of Tetovo, Tetovo, Republic of North Macedonia
  • Faculty of Natural Sciences, Department of Chemistry, University of Tirana, Tirana, Albania
  • Faculty of Veterinary, Medicine Cyril and Methodius University in Skopje, Republic of North Macedonia
autor
  • Faculty of Veterinary, Medicine Cyril and Methodius University in Skopje, Republic of North Macedonia
Bibliografia
  • 1. Behrami E. and Avdiu V. 2023. The process and kinetics of pesticide desorption from clay as a function of cleaning polluted waters. Processes 11 (4): 1180. https://doi.org/10.3390/pr11041180.
  • 2. Behrami E., Xhaxhiu K., Dragusha B., Reka A., Andoni A., Hamiti X., and Drushku S. 2022. The removal of atrazine and benalaxyl by the fly ash released from Kosovo a power plant. International Journal of Analytical Chemistry 2022 (January): 9945199. https://doi.org/10.1155/2022/9945199.
  • 3. Efretuei A., Gooding M., White E., Spink J., and Hackett R. 2016. Effect of nitrogen fertilizer timing on nitrogen use efficiency and grain yield of winter wheat in Ireland. Irish Journal of Agricultural and Food Research 55 (June). https://doi.org/10.1515/ijafr-2016-0006.
  • 4. Guleria S., Singh B. and Shanker A. 2011. Distribution behaviour of dimethoate in tea leaf. Journal of Environmental Protection 2 (April). https://doi.org/10.4236/jep.2011.24056.
  • 5. Guzii S.G., Kurska T., Andronov V., and Adamenko M. 2021. Influence of basic oxides ratio Li2O/Al2O3 , SiO2/Al2O3 and H2O/Al2O3 on physical, rheological and colloidal-chemical properties of lithium containing alumosilicate suspensions in the system xLi2O-Al2O3-nSiO2-mH2O. Materials Science Forum 1038: 193–202. ttps://doi.org/10.4028/www.scientific.net/MSF.1038.193.
  • 6. Jongs L.S., Jock A.A., Ekanem O.E. and Jauro A. 2018. Investigating the industrial potentials of some selected nigerian clay deposits. Journal of Minerals and Materials Characterization and Engineering 6(6): 569–86. https://doi.org/10.4236/jmmce.2018.66041.
  • 7. Khaledian Y., Brevik E., Pereira P., Cerdà A., Fattah M., and Tazikeh H. 2017. Modeling soil cation exchange capacity in multiple countries. Catena 158 (July): 194–200. https://doi.org/10.1016/j.catena.2017.07.002.
  • 8. Khan A.H., Aziz H.A., Khan N.A., Dhingra A., Ahmed S. and Naushad M. 2021. Effect of seasonal variation on the occurrences of high-risk pharmaceutical in drain-laden surface water: A risk analysis of Yamuna River. Science of the Total Environment 794 (Nov): 148484. https://doi.org/10.1016/j.scitotenv.2021.148484.
  • 9. Khan N.A., Bokhari A., Mubashir M., Klemeš J.J., El Morabet R., Khan R.A., Alsubih M., et al. 2022. Treatment of hospital wastewater with submerged aerobic fixed film reactor coupled with tube-settler. Chemosphere 286 (January): 131838. https://doi.org/10.1016/j.chemosphere.2021.131838.
  • 10. Manavi M.A., Nasab M.H.F. and Baeeri M. 2024. Methomyl. In: Encyclopedia of Toxicology (Fourth Edition), edited by Philip J. Wexler, 197–204. Oxford: Academic Press. https://doi.org/10.1016/B978-0-12-824315-2.00451-6.
  • 11. Moreno-Maroto J.M. and Alonso-Azcárate J..2018. What is clay? A new definition of ‘clay’ based on plasticity and its impact on the most widespread soil classification systems. Applied Clay Science 161 (September): 57–63. https://doi.org/10.1016/j.clay.2018.04.011.
  • 12.Reches Y., Thomson K., Helbing M., Kosson D., and Sanchez F. 2018. Agglomeration and reactivity of nanoparticles of SiO2, TiO2, Al2O3, Fe2O3, and clays in cement pastes and effects on compressive strength at ambient and elevated temperatures. Construction and Building Materials 167 (April): 860–73. https://doi.org/10.1016/j.conbuildmat.2018.02.032.
  • 13.Rouabhia F., Nemamcha A. and Moumeni H. 2018. Elaboration and characterization of mulliteanorthite-albite porous ceramics prepared from algerian kaolin. Cerâmica 64 (369): 126–32. https://doi.org/10.1590/0366-69132018643692297.
  • 14. Schackow A., Correia S.L., and Effting C. 2020. Influence of microstructural and morphological properties of raw natural clays on the reactivity of clay brick wastes in a cementitious blend matrix. Cerâmica 66 (May): 154–63. https://doi.org/10.1590/0366-69132020663782852.
  • 15. Sebiomo A., Ogundero V., and Bankole S. 2010. Effect of four herbicides on microbial population, soil organic matter and dehydrogenase activity. African Journal of Biotechnology 10 (September): 770–778.
  • 16. Sipes N.S., Martin M.T., Kothiya P., Reif D.M., Judson R.S., Richard A.M., Houck K.A., Dix D.J., Kavlock R.J., and Knudsen T.B. 2013. Profiling 976 toxcast chemicals across 331 enzymatic and receptor signaling assays. Chemical Research in Toxicology 26 (6): 878–895. https://doi.org/10.1021/tx400021f.
  • 17. Tudi M., Ruan H.D., Wang L., Lyu J., Sadler R., Connell D., Chu C., and Phung D.T. 2021. Agriculture development, pesticide application and its impact on the environment. International Journal of Environmental Research and Public Health 18 (3). https://doi.org/10.3390/ijerph18031112.
Uwagi
Opracowanie rekordu ze środków MNiSW, umowa nr SONP/SP/546092/2022 w ramach programu "Społeczna odpowiedzialność nauki" - moduł: Popularyzacja nauki i promocja sportu (2024).
Typ dokumentu
Bibliografia
Identyfikator YADDA
bwmeta1.element.baztech-998e9295-d3ec-4aa8-95cc-196271566dc0
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