Quick and simple speciation analysis of chromium in cements

• Autorzy: Grabarczyk Malgorzata , Wardak Cecylia

Identyfikatory

DOI

10.37190/ppmp/144445

• Konferencja: Physicochemistry of interfaces - instrumental methods (22-26.08.2021 ; Lublin, Poland)
• Języki publikacji: EN

Abstrakty

EN

The extraction of total Cr(VI) from commercially available cements, based on DTPA + 0.2 mol dm^-3 (NH₄)₂SO₄/NH₄OH mixture solution and subsequent selective determination of Cr(VI) has been proposed. The determination was carried out using the adsorptive voltammetric stripping method. The study was conducted using three different commercially available cement samples. It has been checked that the proposed extraction procedure guaranteed no changes of chromium speciation during cement analysis. For comparison extraction was also carried out with the use of recommended by United States Environmental Protection Agency (EPA) Method 3060A, based on 0.28 mol dm^-3 Na₂CO₃ + 0.5 mol dm^-3 NaOH). Additionally, the extraction process was carried out using only distilled water as an extraction mixture which allows to evaluate concentration of only soluble Cr(VI) forms contained in cement. In all three cements, the content of soluble Cr(VI) was below 2 ppm, i.e. the limit value by European Union Directive 2003/53/EC.

Słowa kluczowe

EN

cement; extraction; chromium speciation; voltammetric determination

• Wydawca: Oficyna Wydawnicza Politechniki Wrocławskiej
• Czasopismo: Physicochemical Problems of Mineral Processing
• Rocznik: 2022
• Tom: Vol. 58, iss. 2
• Strony: art. no. 144445
• Opis fizyczny: Bibliogr. 25 poz., rys. kolor., tab., wykr.

Twórcy

autor

Grabarczyk Malgorzata

• Department of Analytical Chemistry, Institute of Chemical Sciences, Faculty of Chemistry, Maria Curie-Sklodowska University, 20-031 Lublin, Poland

autor

Wardak Cecylia

• Department of Analytical Chemistry, Institute of Chemical Sciences, Faculty of Chemistry, Maria Curie-Sklodowska University, 20-031 Lublin, Poland

Bibliografia

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Uwagi

Opracowanie rekordu ze środków MEiN, umowa nr SONP/SP/546092/2022 w ramach programu "Społeczna odpowiedzialność nauki" - moduł: Popularyzacja nauki i promocja sportu (2022-2023).