Research of Fluorinated Acrylate Copolymer on Flax Fabric

• Autorzy: Sui Z. , Yang K. , Chen J. , Zhao X. , Gao S.

Identyfikatory

DOI

10.5604/01.3001.0010.5376

Warianty tytułu

PL

Badania wpływu emulsji kopolimeru akrylanowego zawierającej fluor na właściwości tkanin lnianych

• Języki publikacji: EN

Abstrakty

EN

A fluorine-containing acrylate copolymer emulsion was prepared in this study, which was applied to finishing linen fabric. Dodecafluloroheptry methacrylate (G04) was used as a modified monomer, butylacrylate (BA) and methylacrylate (MMA) as soft and hard monomers.respectively, and acrylic acid as a functional monomer. Structure and properties of the products were characterised and analyzed by FTIR, TEM, PSD and CA measurements, respectively. The water and air permeability as well as the breaking force of the fabric treated were also investigated. The results showed that the fluorine-containing acrylate copolymer emulsion obtained had a core-shell structure, and the microsphere was of nanoscale size. Because of the latex film on the fabric surface, it became smooth and flat. And the increase in G04 was beneficial to the mechanical properties, waterproofness and antifouling ability of the linen fabric. When the content of G04 were increased from 0% to 20%, the water in the linen sample and hexadecane contact angles to the copolymer film increased from 113.02° to 136.08° and from 65.1° to 87.6°,respectively. Furthermore the breaking force of the linen samples was enhanced from 648 N to 721N. However, the increasing content of G04 had negative effects on the flexural rigidity as well as water and air permeability of the fabric, which were essential requirements for the fabric’s application. However, the wash resistance was excellent and the wear-resistance of the finished linen fabric was better than the unfinished linen fabric.

PL

W pracy przygotowano emulsję kopolimeru akrylanowego zawierającą fluor, którą następnie zastosowano do wykańczania tkanin lnianych. Jako modyfikowany monomer zastosowano metakrylan dodekafluoroheptan (G04), a jako miękkie i twarde monomery użyto akrylan butylu (BA) i akrylan metylu (MMA), a kwas akrylowy jako monomer funkcjonalny. Strukturę i właściwości produktów scharakteryzowano i przeanalizowano za pomocą pomiarów FTIR, TEM, PSD i CA. Przebadano również przepuszczalność wody i powietrza oraz siłę zrywania tkaniny poddanej obróbce. Wyniki wykazały, że otrzymana fluorowa emulsja kopolimeru akrylanowego miała strukturę rdzeń-otoczka, a mikrosfera miała rozmiar w nanometrach. Ze lateksowej powłoce tkanina stała się gładka i matowa. Stwierdzono, że wzrost G04 wpływa korzystnie na właściwości mechaniczne, wodoodporność i zdolność przeciwporostową tkaniny lnianej. Zwiększenie zawartości G04 spowodowało wzrost kąta zwilżania, a siła zrywania próbek zwiększyła się z 648 do 721 N. Jednak wzrastająca zawartość G04 miała negatywny wpływ na sztywność zginania, a także przepuszczalność wody i powietrza tkaniny, które były zasadniczymi cechami wymaganymi dla aplikacji tkaniny. Jednakże odporność na pranie i zużycie była lepsza w przypadku próbek powleczonych.

Słowa kluczowe

EN

fluorine-containing acrylate; core-shell polymerisation; linen fabric; finishing agent; hydrophobicity; lipophobicity

PL

fluor; akrylan; polimeryzacja rdzeń-otoczka; tkanina lniana; hydrofobowość; lipofobowość

• Wydawca: Sieć Badawcza Łukasiewicz - Łódzki Instytut Technologiczny
• Czasopismo: Fibres & Textiles in Eastern Europe
• Rocznik: 2017
• Tom: Vol. 25, no. 6 (126)
• Strony: 83--88
• Opis fizyczny: Bibliogr. 20 poz., rys., tab.

Twórcy

autor

Sui Z.

• Qiqihar University, School of Light Industry and Textile, Qiqihar 161006, P.R. China

autor

Yang K.

• Qiqihar University, School of Light Industry and Textile, Qiqihar 161006, P.R. China

autor

Chen J.

• Qiqihar University, School of Light Industry and Textile, Qiqihar 161006, P.R. China

autor

Zhao X.

• Qiqihar University, School of Light Industry and Textile, Qiqihar 161006, P.R. China

autor

Gao S.

• Qiqihar University, School of Light Industry and Textile, Qiqihar 161006, P.R. China

Bibliografia

• 1. Chengbo Cao, Jianwei Yan, Danning Xing, etc. Research progress of fluorine-containing finishing agent. Journal of Leather Science and Engineering 2015; 25(40): 26-30.
• 2. Mengyi Liu, Jiangping He, Ke Ma. The synthesis and application of fluorinated- containing acrylate waterproof agent. Textile Dyeing and Finishing Journal 2014; 36(1) 41-44.
• 3. De Witte P G Dams R. Fluorochemical intermediates surfactants and their use in coating. Journal of Surface coating International 1995; 78(2): 58-64.
• 4. Lei Zhang, Qun Chen, Ying Mu, et.al. The research progress of core-shell structure acrylate emulsion. Journal of Shanghai Coatings 2012; 50(6): 30-34.
• 5. C Y Zhao, J J Ren, Y T Zhang, et al. Preparation of high solid content emulsion with core-shell structure. Polym-Plastics Technol Eng. 2011; 50(4): 397.
• 6. Teruyuki Fukuda, Akihiko Ueda, shigeru Marulyama. Fluorine-containing polymer and aqueous treatment Agent [P]. US, 8586184. 2013-11-19.
• 7. Wei Xu, Qiufeng An, Lifen Hao. et al. Synthesis of Self-crosslinking Fluorinated Polyacrylate Soap-free Latex and Its Waterproofing Application on Cotton Fabrics. Fibers and Polymers 2014; 15(3): 457-464.
• 8. Xiaowu Yang, Liewei Qiu, Peizhi Li, et.al. A Study on the Water and Oil Repellency of the Textile Finishing Agent of Fluorinated Polyacrylate Soap-Free Emulsion. Journal of fine chemical industry 2014; 31(4): 496-499.
• 9. Guilong Xu, Changyun Deng, Lei Xing, et al. Preparation and properties of siloxane- modified styrene-acrylate latex particles with core-shell structure. International Journal of Polymeric Materials and Polymeric Biomaterials 2013; 62(9): 488-492.
• 10. Xianfei Chen, Peng Qi, Yanjun Liu. Preparation and application of the water-solubility fluoroacrylate copolymer for stone protective agent. New Chemical Materials 2012; 40(9): 135-137.
• 11. Jianhua Zhou, Xin Chen, Hao Duan, et al. Synthesis and characterization of nano-SiO2 modified fluorine-containing polycrylate emulsifier-free emulsion. Applied Surface Science 2015; 504-511.
• 12. Monica Periolatto, Franco Ferrero. Cotton and polyester surface modification by methacrylic silane and fluorinated alkoxysilane via sol-gel and UV-curing coupled process. Surface & Coating Technology 2015; 271, 165-173.
• 13. Yan Zhang, Yuhong Qi, Zhanping Zhang. et al. Synthesis of fluorinated acrylate polymer and preparation and properties of antifouling coating. J. Coat. Technol. Res. 2015; 12 (1) 215–223.
• 14. Edja F. Assanvo, Shashi D. Baruah. Synthesis and properties of Ricinodendron heudelotii oil based hybrid alkyd-acrylate latexes via miniemulsion polymerization. Progress in Organic Coatings 2015; 86: 25-32.
• 15. Ye H H, Li Z X, Chen G Q. Preparation and properties of acryloyloxy carboxylic perfluorooctyl ester copolymer for liquid repellent finishing of cotton. Fibers and Polymers 2014; 15(5): 908-913.
• 16. Jalal Rahmatinejad, Akbar Khoddami, and Ozan Avinc1. Innovative Hybrid Fluorocarbon Coating on UV/Ozone Surface Modified Wool Substrate. Fibers and Polymers; 2015, 2416-2425.
• 17. Zhihui Sui, Weiwei, Pang Jia Song, Lei Zhang and Xin Zhao. The Preparation of silicone-modified acrylic ester emulsion adhesive with core - shell structure [J]. Asian Journal of Chemistry 2014; 26 (14): 4435-4438.
• 18. Zhifang Zhao, Xiao Li, Peizhi Li, et al. Study on properties of waterborne fluorinated polyurethane/acrylate hybrid emulsion and films. J Polym Res. 2014; 21:460.
• 19. Shin MS, Lee YH, Rahman MM, Kim HD. Synthesis and properties of water fluorinated polyurethane-acrylate using a solvent-/emulsifier-free method. Polymer 2013; 54: 4873– 4882.
• 20. Long Li, Guanzhong Sheng. Analysis on crystalline structure of cellulose fiber from cotton-straw bast by X-ray diffraction method. Journal of cellulose science and technology 2009; 17 (4) 37-40.

Uwagi

PL

Opracowanie rekordu w ramach umowy 509/P-DUN/2018 ze środków MNiSW przeznaczonych na działalność upowszechniającą naukę (2018).