Identyfikatory
Warianty tytułu
Powstawanie polifazowej asamblaży minerałów z grupy platynowców w masywie dunitowo-szonkinitowym Inagli w Aldan Shield na platformie syberyjskiej
Języki publikacji
Abstrakty
The Inagli massif is a concentric-zonal ring massif consisting of a dunite core bordered by a sequential series of peridotites, pyroxenites and shonkinites. In dunites, there are densely disseminated accumulations of chromspinelides, as well as schlieren and veined particles of massive chromitites, to which polyphase growths of platinum-group minerals (PGM) are confined. The Inagli intrusive, like the well-known Konder massif, belongs to an independent "Aldan" type of platinum-bearing deposits. The Aldan type of ring intrusions is a platform analogue of the "Ural-Alaskan" zonal dunite-gabbro massifs of orogenic regions. In placers, dunites and chromitites of the Inagli massif, PGM are mainly represented by isoferroplatinum (Pt3Fe) with an admixture of iridium up to 8 wt %. In isoferroplatinum, symplektitic iridium particles and small inclusions of osmium, laurite, ehrlichmanite, malanite, as well as other sulfides and arsenides of platinum-group elements (PGE) are often observed. The bulk composition of such polymineral aggregates can be calculated based on the volume ratios and chemical composition of individual phases. The results obtained in this way show that the compositions of the initial polycomponent solid solutions vary from Pt-Ir-Fe to Ir-Os-Ru-Rh-Pt-Pd-Fe alloys. Polycomponent homogeneous solid solutions, which composition gradually changes from Ru-Rh-Ir-Os minerals to Fe-Pt alloys, are known in the Witwatersrand placers. A similar series of solid solutions of PGE is identified in the placers of the Guli massif on the Siberian platform. Unlike the placers of the Witwatersrand and Guli massif, where PGM are mainly represented by Os-Ir alloys, Inagli minerals have mainly a Pt-Ir-Fe composition with a low proportion of Os. The structures of most natural polyphase PGM aggregates are similar to those of artificial alloys, therefore, the former are also products of crystallization of multicomponent metal melts and their subsequent solid-phase transformations. The limits of solubility between PGE differ significantly, therefore, depending on the initial composition of metal alloys, both polycomponent solid solutions and polymineral aggregates can be formed. Based on the analysis of combined double and triple diagrams of PGE systems, the author considers possible ways of evolution of phase transformations of alloys of different composition.
Czasopismo
Rocznik
Tom
Strony
125--133
Opis fizyczny
Bibliogr. 23 poz., rys., tab., zdj.
Twórcy
autor
- Diamond and Precious Metal Geology Institute, Siberian Branch, Russian Academy of Sciences (DPMGI SB RAS), 39 Lenin Str, Yakutsk, 677980, Russia
Bibliografia
- 1. I.S. Rozhkov. V.I. Kitsul. L.V. Razin. S.S. Borishanskaya. Platinum of the Aldan Shield (Publishing House of Academy of Sciences USSR. Moscow. 1962).
- 2. I.S. Rozhkov and V.I.Kitsul, “Platinum deposit on the Aldan Shield”. Geologiya Rudnykh Mestorozdenii, No. 4, 74–84 (1960).
- 3. L.V. Razin, “Genesis of platinum mineralization in forsterite dunites”. Geologiya Rudnykh Mestorozhdenii, No. 6, 10–25 (1968).
- 4. L.V. Razin, “Geology and genetic feature of forsterite dunites and their platinum group mineralization”, Econ. Geology 71, 1371-1376 (1976).
- 5. N.S. Rudashevskii, A.G.Mochalov, V.V. Zhdanov, “PGE parageneses in ultramafic rocks”. Zapiski VMO, No. 1, 3–13 (1983).
- 6. A.G. Mochalov, I.V. Zhernovskii, G.G. Dmitrienko, “Composition and abundance of native platinum and iron minerals in ultramafic rocks”. Geologiya Rudnykh Mestorozhdenii, No. 5, 47–58 (1988).
- 7. N.D. Tolstykh, A.P. Krivenko, “Platinum group minerals in the Inagli placer (Aldan Shield)”. Russian Geology and Geophysics 38, 808–817 (1997).
- 8. K.N. Malitch, O.A.R. Thalhammer, “Pt–Fe nuggets derived from clinopyroxenite–dunite massifs, Russia: a structural, compositional and osmium-isotope study”. Can. Mineral. 40, 395–418 (2002).
- 9. A.V. Okrugin, “Mineralogy, types, and origin of platinum-bearing placer deposits of the Siberian platform”. Int. Geol. Rev. 40, 677–687 (1998).
- 10. A.V. Okrugin, “Mineral parageneses and the origin of isoferroplatinum nuggets from the Inagli placer deposit (Siberian Platform)”. Geol. Ore Deposits 43, 239–250 (2001).
- 11. A.V. Okrugin, “Origin of platinum-group minerals in mafic–ultramafic rocks: from dispersed elements to nuggets”. Can. Mineral. 49, 1397–1412 (2011).
- 12. A.V. Okrugin. A.S. Borisenko. A.I. Zhuravlev. A.V. Travin. “Mineralogical. geochemical. and age characteristics of the rocks of the Inagli dunite–clinopyroxenite–shonkinite massif with platinum–chromite and Cr-diopside mineralization (Aldan Shield)”. Russian Geology and Geophysics 59, 1301–1317 (2018).
- 13. A.V. Okrugin. “Crystallization–liquation model of formation of PGE–chromite ores in mafic–ultramafic complexes”. Tikhookeanskaya Geologiya 23, 63–75 (2004).
- 14. L.J. Cabri and C.Z. Feather, “Platinum-iron alloys: a nomenclature based on study of natural and sinthetic alloys // Can. Miner. 13, 117-126 (1975).
- 15. D.C. Harris and L.J. Cabri, “Nomenclature of platinum-group-element alloys: review and revision”. Can. Mineral. 29, 231-237 (1991).
- 16. L.J. Cabri, T. Oberthur, D. Schumann, “The mineralogy of Pt-Fe alloys and phase relations in the Pt–Fe binary system”. The Canadian Mineralogist 60, 1-9 (2022).
- 17. C.E. Feather, “Mineralogy of platinum-group minerals in the Witwatersrand, South Africa”. Economic Geology, 71, 1399–1428 (1976).
- 18. K.N. Malitch, R.K. Merkle, “Ru–Os–Ir–Pt and Pt–Fe alloys from the Evander Goldfield, Witwatersrand basin, South Africa: detrital origin inferred from compositional and osmium-isotope data”. Can.Mineral. 42, 631-650 (2004).
- 19. K.N. Malitch, Platinum-group elements in the clinopyroxenite-dunite massifs of the East Siberia (geochemistry, mineralogy, and genesis) (VSEGEI Press, St. Petersburg, 1999).
- 20. S.Y. Stepanov, R.S. Palamarchuk, A.V. Kozlov et al., “Morphology, composition, and ontogenesis of platinum-group minerals in chromitites of zoned clinopyroxenite–dunite massifs of the Middle Urals”. Russian Geology and Geophysics, 61, 47-67 (2020).
- 21. A.G. Mochalov, G.G. Dmitrenko, N.S. Rudashevsky, I.V. Zhernovsky, M.M. Boldyreva, “Hexaferrum–(Fe, Ru), (Fe, Os), (Fe, Ir) – new mineral”. Zapiski VMO. 127, 5, 41-51 (1998).
- 22. E. Slansky, Z. Johan, M. Ohnenstetter et al. “Platinum mineralization in the Alaskan type intrusive complexes near Fifield, N. S. W., Australia”. Miner. and Petrol. 43, 161-180 (1991).
- 23. H. Okamoto, “Arsenic-Platinum”. Bull Alloy Phase Diagrams 11, 508-511(1990).
Uwagi
Opracowanie rekordu ze środków MNiSW, umowa nr SONP/SP/546092/2022 w ramach programu "Społeczna odpowiedzialność nauki" - moduł: Popularyzacja nauki i promocja sportu (2024).
Typ dokumentu
Bibliografia
Identyfikator YADDA
bwmeta1.element.baztech-9905f7d5-fdc4-4eec-b357-79b02b05f9f8