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An Energetic Binder for the Formulation of Advanced Solid Rocket Propellants

Treść / Zawartość
Identyfikatory
Warianty tytułu
Języki publikacji
EN
Abstrakty
EN
Many promising elastomers and energetic binders are reported in the literature for their probable application in propellant formulations. However, their application in actual systems is still restricted due to many inherent limitations. Therefore, an attempt has been made to study the performance of an advanced energetic solid propellant based on an energetic binder comprising a polyol with high hydroxyl functionality plasticized with 1,2,4-butanetriol trinitrate (BTTN). In order to examine the physico-chemical properties of the BTTN/Polyol binder system, the polyol and a series of binders have been formulated and cured with different di-isocyanates viz. TDI, IPDI and H12MDI, and the cured binder sheets were evaluated for their mechanical properties, decomposition temperatures and glass transition temperatures (Tg). The pot life of a representative binder system with various di-isocyanates has also been determined using a gelation timer apparatus. The overall result of this study establishes that the energetic binder system under study has potential applications in the formulation and processing of advanced energetic solid propellant compositions for case bonded rocket motors, offering higher density, higher energy and better low temperature strain capability as compared to conventional HTPB-based composite propellants.
Rocznik
Strony
145--158
Opis fizyczny
Bibliogr. 15 poz., tab.
Twórcy
autor
  • High Energy Materials Research Laboratory, Sutarwadi, Pune 411021, India
  • High Energy Materials Research Laboratory, Sutarwadi, Pune 411021, India
autor
  • High Energy Materials Research Laboratory, Sutarwadi, Pune 411021, India
  • Indira Gandhi National Open University, Maidan Garhi, New Delhi 110068, India
Bibliografia
  • [1] Davenas A., Solid Rocket Propulsion Technology, Pergamon Press, Oxford, 1993, pp. 477-485.
  • [2] Doriath G., Energetic Insensitive Propellants for Solid and Ducted Rockets, J. Propul. Power, 1995, 11(4), 870-882.
  • [3] Sutton G.P., Rocket Propulsion Elements, Willey, New York, 2001, pp. 497-502.
  • [4] Colclough M.E., Desai H., Millar R.W., Paul N.C., Stewart M.J., Golding P., Energetic Polymers as Binders in Composite Propellants and Explosives, Polym. Adv. Technol., 1994, 5, 55-560.
  • [5] Cliff M.D., Cunliffe A.V., Plasticized polyGLYN Binders for Composite Energetic Materials, Int. Annu. Conf. ICT, 30th, Karlsruhe, Germany, 1999.
  • [6] Leach C., Flower P., Hollands R., Flynn S., Marshall E., Kendrick J., Plasticizers in Energetic Materials Formulations − A UK Overview, 29th Int. Annu. Conf. ICT, Karlsruhe, Germany, 1998.
  • [7] Russell R.J., Ciaramitaro D.A., High Energy Propellant with Reduced Pollution, US Patent 6 805 760, 2004.
  • [8] Urbanski T., Chemistry and Technology of Explosives, Pergamon Press, Oxford, 1984, Vol. 4, p. 404.
  • [9] Chan M.L., Energetic Binder Explosive, US Patent 5 316 600, 1994.
  • [10] Meyer R., Kohler J., Homburg A., Explosives, Wiley-VCH, Weinheim, 2007.
  • [11] Chan M.L., Turner A.D., Minimum Signature Propellant, US Patent 0 047 260, 2003.
  • [12] Ang H.G., Pisharath S., Energetic Polymers, Willey-VCH, Weinheim, 2012.
  • [13] Pande S.M., Sadavarte V.S., Bhowmik D., Singh H., NG Plasticized PE-PCP Binderbased Advanced Solid Rocket Propellants: Studies on Mechanical Properties, Int. J. Energ. Mater. Chem. Propul., 2012, 11(2), 123-134.
  • [14] Pande S.M., Sadavarte V.S., Bhowmik D., Gaikwad D.D., Singh H., Ballistic Modification of Nitramine Propellants with Special Reference to NG-PE-PCPBased High Energy Propellants, Propellants Explos. Pyrotech., 2012, 37, 1-6.
  • [15] Politzer P.A., Murray J.S., Energetic Materials, Part 1. Decomposition, Crystal and Molecular Properties, in: Theoretical and Computational Chemistry, Vol. 12, Elsevier, 2003, p. 342.
Typ dokumentu
Bibliografia
Identyfikator YADDA
bwmeta1.element.baztech-98bc795f-3fcd-4a08-9855-d57a0cdf95c3
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