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Structure and magnetic properties of Fe-based amorphous alloys

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Języki publikacji
EN
Abstrakty
EN
Purpose: This paper presents studies relating to the structure, magnetic properties and thermal stability of the following bulk amorphous alloys: Fe61Co10Ti3-xY6+xB20 (where x = 0 or 1) Design/methodology/approach: The investigated samples were prepared in the form of rods by using the suction-casting method. The material structures were investigated using X-ray diffractometry and Mössbauer spectroscopy. The thermal stability was determined on the basis of Differential Scanning Calorimetry (DSC) plots The magnetic properties were studied using a completely automated set up for measuring susceptibility and its disaccommodation. Findings: It was found that both alloys were amorphous in the as-cast state. The DSC curve obtained for Fe61Co10Ti2Y7B20 alloy exhibited one exothermic peak, while for the Fe61Co10Ti3Y6B20 sample, two peaks were distinguishable, corresponding to the crystallization of the sample. The bifurcation of the maximum on the DSC curve for the Fe61Co10Ti3Y6B20 sample may also testify to the presence of the primary crystallizing phase (FeCo)23B6 [1,2]. Data obtained from the analysis of the magnetic susceptibility disaccommodation curves clearly show that in the Fe61Co10Ti3Y6B20 alloy there is less free volumes than in the second of the investigated alloys, this results in a lesser range of relaxation time. Moreover, Fe61Co10Ti3Y6B20 alloy exhibits the better time and thermal stability of magnetic properties In both of the studied alloys, at low frequencies, the total losses were comparable with those observed in classical silicon-iron alloys. Practical implications: A Ferrometer was used for the determination of core losses. Originality/value: The paper presents some researches of the Fe-based bulk amorphous alloys obtained by the suction-casting method.
Rocznik
Strony
156--162
Opis fizyczny
Bibliogr. 17 poz., rys., tab.
Twórcy
autor
  • Institute of Physics, Faculty of Materials Processing Technology and Applied Physics, Czestochowa University of Technology, Al. Armii Krajowej 19, 42-200 Częstochowa, Poland
Bibliografia
  • [1] M. Stoica, R. Li, A. Reza. Yavari, G. Vaughan, J. Eckert, N. Van Steenberge, D. Ruiz Romera, Thermal stability and magnetic properties of FeCoBSiNb bulk metallic glasses, Journal of Alloys and Compounds 504S (2010) 123-128.
  • [2] S. Lesz, R. Babilas, M. Nabiałek, M. Szota, M. Dośpiał, R. Nowosielski, The characterization of structure, thermal stability and magnetic properties of Fe-Co-B-Si-Nb bulk amorphous and nanocrystalline alloys, Journal of Alloys and Compounds 509S (2011) 197-201.
  • [3] P.I Williams, A.J. Moses, T. Meydan, R.J.D. Tilley, Amorphization of bulk magnetic materials by an arc melting technique,Journal of Magnetism and Magnetic Materials, 17 (2003) 254-255.
  • [4] R. Hasegawa, Soft magnetic properties of metallic glasses, Journal of Magnetism and Magnetic Materials 79 (1984) 41.
  • [5] J. Olszewski, J. Zbroszczyk, K. Sobczyk, W. Ciurzynska, P. Bragiel, M. Nabialek, J. Swierczek, A. Lukiewska, Thermal stability and crystallization of iron and cobalt-based bulk amorphous alloys, Acta Physica Polonica A 114/6 (2008) 1659-1666.
  • [6] M. Lubas, J. Zbroszczyk, M. Nabialek, J. Olszewski, K. Sobczyk, W. Ciurzynska, M. Szota, J. Swierczek, Mechanical and magnetic properties of bulk amorphous Fe59Co15Zr2Y4Me5B15 (Me=Mo or Nb) alloys, Archives of Metallurgy and Materials 53/3 (2008) 861-866.
  • [7] W.S. Sun, T. Kulik, X.B. Liang, J. Ferenc, Thermal stability and magnetic properties of Co-Fe-Hf-Ti-Mo-B bulk metallic glass, Intermetallics 14 (2006) 1066-1068.
  • [8] A. Inoue, A. Makino, T. Mizushima, Ferromagnetic bulk glassy alloys, Journal of Magnetism and Magnetic Materials 246 (2000) 215-216.
  • [9] A. Inoue, bulk amorphous alloys - preparation and fundamental characteristics, Material Science Foundation 6 Trans. Tech. Publications (1998).
  • [10] P. Pawlik, M. Nabiałek, E. Żak, J. Zbroszczyk, J. J. Wysłocki, J. Olszewski, K. Pawlik, Processing of bulk amorphous alloys by suction-casting method, Archives Mateerials Science 25/3 (2004) 177.
  • [11] M. Nabialek, M. Dospial, M. Szota, J. Olszewski, S. Walters, Manufacturing of the bulk amorphous Fe61Co10Zr 2+xHf3-xW2Y2B20 alloys (where x = 1, 2, 3) their microstructure, magnetic and mechanical properties, Journal of Alloys and Compounds 509/Supplement 1 (2011) 155-160.
  • [12] M.G. Nabialek, M.J.Dospial, M. Szota, P. Pietrusiewicz, J. Jędryka, Investigation of the thermal and magnetic properties of Fe61Co10Zr2.5Hf2.5Me2W2B20 (Me = Y, Nb, W, Ti, Mo, Ni) bulk amorphous alloys obtained by an induction suction method, Journal of Alloys and Compounds 509/7 (2011) 3382-3386.
  • [13] W.H. Ciurzyńska, G. Haneczok, J. Zbroszczyk, Magnetic after-effect spectra analysis by applying the lognormal distribution of relaxation Times, Journal of Magnetism and Magnetic Materials 189 (1998) 384.
  • [14] H. Kronmüller, N. Moser, F. Rettenmeier, Micromagnetic analysis of magnetic after-effects in amorphous alloys by two-level systems, IEEE Tranactions on Magnetics 20 (1984) 1388.
  • [15] A. Łukiewska, J. Zbroszczyk, M. Nabiałek, J. Olszewski, J. Świerczek, W. Ciurzyńska, K. Sobczyk, M. Dośpiał, Low and high magnetic field properties of nanocrystalline Fe59Co15Zr2Y4Nb5B20 rods, Archives of Metallurgy and Materials 53/3 (2008) 881.
  • [16] A. Inoue, B. Shen, A. Takeuchi, Fabricationn, properties and applications of bulk glassy alloys in late transitions metal-based system, Materials Science and Engineering A441 (2006) 18-25.
  • [17] B. Wunderlich, Macromolecular physics 2 - crystal nucleation, growth, annealing, Academic Press Inc., New York, San Francisco, London, 1976.
Typ dokumentu
Bibliografia
Identyfikator YADDA
bwmeta1.element.baztech-97b7bc47-0698-4026-972a-3a580ec556b9
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