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Effects of Oxygen Partial Pressure and slag Basicity on the Behavioral Characteristics of Ni in Slag Drying Smelting

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EN
Abstrakty
EN
This study was intended to investigate the effects of basicity and oxygen partial pressure on the distribution behavior of Ni in the nickel smelting process using nickel oxide ore, the raw material of nickel, among natural ores. Experiments were conducted in a vertical tube furnace using Fe-Ni metal and FeO-MgO-SiO2 ternary slag, which simulated the composition of natural ore. An equilibrium experiment was conducted to observe the distribution ratio of Ni, and thermodynamic data required for this experiment was calculated through Factsage. As a result, it was found that as the oxygen partial pressure increased, the Ni content in the slag increased linearly. The Ni content in the slag increased as the basicity moved away from 0.60.
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Twórcy
  • Pukyong National University, Department of Metallurgical Engineering, Busan 48547, Republic of Korea
  • Pukyong National University, Department of Metallurgical Engineering, Busan 48547, Republic of Korea
autor
  • Pukyong National University, Department of Marine Convergence Design Engineering (Advanced Materials Engineering), Division of Convergence Materials Engineering, Major of Metallurgical Engineering, Busan 48547, Republic of Korea
Bibliografia
  • [1] D. Larcher, J. M. Tarascon, Nat. Chem. 7, 19 (2015).
  • [2] B. Dunn, H. Kamath, J.-M. Tarascon, Science 334, 928 (2011).
  • [3] M.M. Thackeray, C. Wolverton, E.D. Isaacs, Energy Environ. Sci. 5, 7854 (2012).
  • [4] J.B. Goodenough, Y. Kim, Chem. Mater. 22, 587 (2010).
  • [5] Korea Resources Information Service https://www.nirs.go.kr/eng//
  • [6] A.D. Dalvi, W.G. Bacon, R.C. Osborne, The Past and the Future of Nickel Laterit, PDAC 2004 International Convention.
  • [7] H.S. Shon, Current Status of Nickel Smelting Technology, Resources Recycling 30, 2, 3-13 (2021).
  • [8] K.S. Kim et al., A Study on Separation of Limonite and Saprolite from Nickel Laterite Ores, J. of Korean Inst. of Resources Recycling 23, 6, 12-21 (2014).
  • [9] Romeo U. Pagador, Mitsuhisa Hino, Kimio Itagaki, IAMP in Tohoku University, Solubility of Ni, Cu and Minor Elements in Feox-SiO2-MgO Slag Equilibrating with Nickel Alloy, Molten Slags, Fluxes and Salts ’97 Conference 327.
  • [10] Y. Takeda, S. Kanesaka, A. Yazawa, 25th Annual Conference of Metallurgists, 185 (1986).
  • [11] S.H. Lee, D. J. Min. Metall. Mater. Trans. B 33, 55 (2002).
Uwagi
This subject is supported by Korea Ministry of Environment (MOE) as “Advanced Technology Program for Environmental Industry (2020003100003)
Typ dokumentu
Bibliografia
Identyfikator YADDA
bwmeta1.element.baztech-97b06943-2b33-4569-ad2b-900c2d2df784
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