From waste to treat waste : exploitation of marble dust as a harmful pollutant to a green adsorbent for dyes and heavy metals from industrial wastewater

• Autorzy: Attia H.A. , Farghaly Mohamed G. , Saleh A.M. , Abdel Khalek M.A.

Identyfikatory

DOI

10.37190/ppmp/154007

• Języki publikacji: EN

Abstrakty

EN

The marble dust as a harmful industrial waste of marble fabrication was evaluated as aneconomical and efficient green adsorbent for Acid Red-1 dye and lead ions. The XRD, XRF, particle size, surface area and zeta-potential measurements were used to characterize the marble dust. The removal efficiency was optimized by studying several parameters such as pH, temperature, contact time, adsorbent dose and initial concentration. The optimum removal was achieved at pH 6, 20°C after 60 min in the presence of 2.5g/L marble dust. The rates of adsorption were found to follow the pseudo-second-order model. The results showed better fitting to Freundlich isotherm. The thermodynamic studies revealed that the adsorption process is spontaneous, exothermic and favorable at low temperature. The free energy (∆G°), enthalpy (∆H°), and entropy (∆S°) changes were calculated to predict the nature of adsorption.The removal efficiency was improved by calcination of the marble at 700°C. Application for textilewastewater showed high removal efficiency up to 99.9%of inorganic and organic pollutants. The product of treatment was used in the concrete and bricks manufactured, so there is nogeneration of second-order pollutants.

Słowa kluczowe

EN

marble dust; pollutant; adsorbent; dye; heavy metals; textile wastewater

• Wydawca: Oficyna Wydawnicza Politechniki Wrocławskiej
• Czasopismo: Physicochemical Problems of Mineral Processing
• Rocznik: 2022
• Tom: Vol. 58, iss. 6
• Strony: art. no. 154007
• Opis fizyczny: Bibliogr. 55 poz., rys., wykr.

Twórcy

autor

Attia H.A.

• Al-Azhar University, Faculty of Engineering, Mining and Petroleum Engineering Department, Qena, Egypt

autor

Farghaly Mohamed G.

• Al-Azhar University, Faculty of Engineering, Mining and Petroleum Engineering Department, Qena, Egypt

autor

Saleh A.M.

• Al-Azhar University, Faculty of Engineering, Mining and Petroleum Engineering Department, Cairo, Egypt

autor

Abdel Khalek M.A.

• Central Metallurgical Research & Development Institute (CMRDI), Helwan, Cairo, Egypt.

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Uwagi

Opracowanie rekordu ze środków MEiN, umowa nr SONP/SP/546092/2022 w ramach programu "Społeczna odpowiedzialność nauki" - moduł: Popularyzacja nauki i promocja sportu (2022-2023).