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Citric acid is a small-molecule organic acid, which can be used as an inhibitor for the flotation of Mg2+ activated quartz. Methods such as flotation experiments, zeta potential, FTIR qualitative and quantitative calculations, and solution chemistry calculations were used in this study to conduct systematic research to study activation and inhibition mechanisms. The results show that adding only a quarter of citric acid under the optimal conditions of Mg2+ activated quartz produces the best inhibitory effect. Mg2+ and citric acid affect the zeta potential of the quartz surface in the zeta potential experiment. FTIR qualitatively found that under the action of Mg2+, sodium oleate was adsorbed on the quartz surface in the form of physical adsorption; quantitative analysis clearly explained that after the chemical reaction between citric acid and Mg2+, it desorbed from the quartz surface into the water system. According to the chemical calculation of the solution during the flotation process, it is found that the reaction product of citric acid and Mg2+ has no inhibitory effect; only the amount of Mg2+ is consumed, thereby reducing the number of activating factors and cutting off the medium of sodium oleate adsorbed on the surface of the quartz.
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1--11
Opis fizyczny
Bibliogr. 11 poz., rys. kolor.
Twórcy
autor
- School of Materials and Metallurgy, Inner Mongolia University of Science and Technology, Baotou, 014010, China
- School of Mining and Coal, Inner Mongolia University of Science and Technology, Baotou, 014010, China
autor
- School of Materials and Metallurgy, Inner Mongolia University of Science and Technology, Baotou, 014010, China
autor
- School of Mining and Coal, Inner Mongolia University of Science and Technology, Baotou, 014010, China
- School of Materials and Metallurgy, Inner Mongolia University of Science and Technology, Baotou, 014010, China
autor
- School of Mining and Coal, Inner Mongolia University of Science and Technology, Baotou, 014010, China
- School of Materials and Metallurgy, Inner Mongolia University of Science and Technology, Baotou, 014010, China
autor
- School of Mining and Coal, Inner Mongolia University of Science and Technology, Baotou, 014010, China
- School of Materials and Metallurgy, Inner Mongolia University of Science and Technology, Baotou, 014010, China
autor
- School of Mining and Coal, Inner Mongolia University of Science and Technology, Baotou, 014010, China
- School of Materials and Metallurgy, Inner Mongolia University of Science and Technology, Baotou, 014010, China
Bibliografia
- FANG, J., GE, Y., LIU, S., YU, J., LIU, CH., 2021. Investigations on a novel collector for anionic reverse flotation separation of quartz from iron ores. Physicochem Probl. Miner. Process, 57(1), 136–155
- LIU, Q., GAO, N., DU, Z., LI, J. CHEN, CH., ZHANG, Z., 2017. Quantitative detection method of infrared spectroscopy based on second derivative spectrum and characteristic absorption window. Spectroscopy and Spectral Analysis, 37(06), 1765-1770.
- LIU, R., LI, J., SU, W., ZHANG, X., LI, J., MENG, L., 2020. Comparison of the activation mechanism of Ca~(2+), Fe~(3+) on quartz by infrared spectroscopy and XPS analysis, Spectroscopy and Spectral Analysis, 40(06), 1876-1882.
- M.C. FUERSTENAU, A. LOPEZ-VALBRVIIESO, D.W. FUERSTENAU, WANG BOWEN. 1989. The influence of hydrolyzed cations on the natural hydrophobicity of talc, Foreign Non-metallic Minerals, 18-21.
- WANG YUBIN, WEN KAN, WANG WANGBO, 2019. The inhibitory mechanism of citric acid on the floatability of muscovite. The Chinese Journal of Process Engineering, 19(02), 338-344.
- WANG, D., HU, Y, 1988. Flotation solubilization, 138-142, 285-287.
- WENG, S., XU, Y., 2010. Fourier Infrared Spectroscopy Analysis. 394-395.
- WHITE, A.F., BRANTLEY, S.L. 1995. Chemical Weathering Rates of Silicate Minerals. De Gruyter, 12-15.
- WU, W., SUN, CH., ZHU, Y., .2007. Inhibition of organic chelating agents on activated quartz and its mechanism of action. Metal Mine, 02, 33-37.
- YIN, R., CHEN, L., HOU, Q., YUAN, Y, LIU, T., 2013. Study on the mechanism of magnesium ion activated quarto flotation. Functional Materials, 44(15), 2193-2196.
- ZHIQIANG, ZHANG, CH., DUAN, S., 2019. Study on the activation mechanism of Mg~(2+) on sodium oleate capture quartz. Metal Mine, 5, 84-87.
Typ dokumentu
Bibliografia
Identyfikator YADDA
bwmeta1.element.baztech-9707270f-0e61-430f-9534-a2ff1cac50eb