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Flotation behaviour and surface characteristic of anosovite in a sodium oleate solution

Treść / Zawartość
Identyfikatory
Warianty tytułu
Języki publikacji
EN
Abstrakty
EN
Properties of anosovite in titanium slag, anosovite flotation response in a collector solution of sodium oleate, and adsorption behaviour of sodium oleate on the mineral surface were studied in the present work using XRD, Raman spectra, flotation tests, zeta potential analysis, FTIR and XPS. The results show that the anosovite crystal contains magnesium, and its chemical composition is Mg0.09Ti2.91O5. The chemical bonds on the anosovite surface mainly comprise Ti-O bonds. Micro-flotation tests indicate that anosovite has better floatability at a wide pH range and the recovery reaches 88% at pH=6, when the dosage of sodium oleate is only 4·10−6 mol/dm3. The point of zero charge of anosovite was determined near pH 3.2 by the zeta potential measurement. In the flotation process, chemical adsorption occurs between the carboxyl of sodium oleate and the titanium sites on the anosovite surface.
Słowa kluczowe
Rocznik
Strony
714--723
Opis fizyczny
Bibliogr. 15 poz., rys., tab.
Twórcy
autor
  • State Key Laboratory of Complex Nonferrous Metal Resources Clean Utilization, Kunming University of Science and Technology, Kunming 650093, China
autor
  • State Key Laboratory of Complex Nonferrous Metal Resources Clean Utilization, Kunming University of Science and Technology, Kunming 650093, China
autor
  • Institute of Mineral Resource Comprehensive Utilization, Chinese Academy of Geological Sciences, Chengdu 610041, China
autor
  • State Key Laboratory of Complex Nonferrous Metal Resources Clean Utilization, Kunming University of Science and Technology, Kunming 650093, China
autor
  • State Key Laboratory of Complex Nonferrous Metal Resources Clean Utilization, Kunming University of Science and Technology, Kunming 650093, China
autor
  • Faculty of Foreign Languages and Cultures, Kunming University of Science and Technology, Kunming 650093, China
Bibliografia
  • ALBRECHT T.W.J., ADDAI-MENSAH J., FORNASIERO D., 2016, Critical copper concentration in sphalerite flotation: Effect of temperature and collector, International Journal of Mineral Processing 146, 15-22.
  • BAHRI Z., REZAI B., KOWSARI E., 2016, Selective separation of gallium from zinc using flotation: Effect of solution pH value and the separation mechanism, Minerals Engineering 86, 104-113.
  • ESKANDARLOO H., HASHEMPOUR M., VICENZO A., FRANZ S., BADIEI A., BEHNAJADY M.A., 2016, Bestetti M. High-temperature stable anatase-type TiO2 nanotube arrays: A study of the structure-activity relationship, Applied Catalysis B: Environmental 185, 119-132.
  • HOANG S., BERGLUND S.P., HAHN N.T., BARD A.J., MULLINS C.B., 2012, Enhancing visible light photo-oxidation of water with TiO2 nanowire arrays via cotreatment with H2 and NH3: Synergistic effects between Ti3+ and N, Journal of the American Chemical Society 134, 3659-3662.
  • KANG J., OKABE T.H., 2013, Removal of iron from titanium ore through selective chlorination using magnesium chloride, Materials Transactions 54, 1444-1453.
  • LIU C., FENG Q.M., ZHANG G.F., 2015, Electrokinetic and flotation behaviors of hemimorphite in the presence of sodium oleate, Minerals Engineering 84, 74-76.
  • LIU J., DUAN X.L., ZHANG Y., LI Z.Q., YU F.P., JIANG H.D., 2016, Growth, electronic structure and properties of Rb2Ti1.95Yb0.05(PO4)3 crystals, Journal of Alloys & Compounds 660, 356-360.
  • LIU W.J., ZHANG J., WANG W.Q., DENG J., CHEN B.Y., YAN W., XIONG S.Q., HUANG Y., LIU J., 2015, Flotation behaviors of ilmenite, titanaugite, and forsterite using sodium oleate as the collector, Minerals Engineering 72, 1-9.
  • NÁJERA J.J., 2007, Phase transition behaviour of sodium oleate aerosol particles, Atmospheric Environment 41, 1041-1052.
  • TANDON P., RAUDENKOLB S., NEUBERT R.H.H., RETTIG W., WARTEWIG S., 2001, X-ray diffraction and spectroscopic studies of oleic acid-sodium oleate, Chemistry & Physics of Lipids 109, 37-45.
  • WANG J., CHENG H.W., ZHAO H.B., QIN W.Q., QIU G.Z., 2014, Flotation behavior and mechanism of rutile in presence of sodium oleate, The Chinese Journal of Nonferrous Metals 24, 820-825.
  • XIAO P., ZHENG S.B., YOU J.L., JIANG G.C., CHEN H., ZENG H., 2007, Structure and Raman spectra of titanium oxides, Spectroscopy and Spectral Analysis 27, 936-939.
  • ZHANG J., LIU W.J., WANG W.Q., XIONG S.Q., WANG D.Z., YAN W., DENG J., 2015, Flotation characteristics of two different types of ilmenite with sodium oleate, Mineralogy & Petrology 109, 299-306.
  • ZHANG W.S., ZHU Z.W., CHENG C.Y., 2011, A literature review of titanium metallurgical processes, Hydrometallurgy 108, 177-188.
  • ZHU Y.G., ZHANG G.F., FENG Q.M., YAN D.C., WANG W.Q., 2011, Effect of surface dissolution on flotation separation of fine ilmenite from titanaugite, Transactions of Nonferrous Metals Society of China 21, 1149-1154.
Typ dokumentu
Bibliografia
Identyfikator YADDA
bwmeta1.element.baztech-96e44f5d-802c-4a5b-b512-9df54914d773
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