Effect of calcinated halloysite on structure and properties of rigid poly(vinyl chloride) composites

Wieczorek, Martina; Tomaszewska, Jolanta; Bajda, Tomasz; Długosz, Jacek

doi:10.24425/cpe.2022.142281

Artykuł - szczegóły

Tytuł artykułu

Effect of calcinated halloysite on structure and properties of rigid poly(vinyl chloride) composites

Autorzy

Wieczorek Martina , Tomaszewska Jolanta , Bajda Tomasz , Długosz Jacek

Treść / Zawartość

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Identyfikatory

DOI

10.24425/cpe.2022.142281

Warianty tytułu

Języki publikacji

Abstrakty

Halloysite is a filler which may be used to produce composites with thermoplastic polymer matrix. This work summarized the results of investigations of processing, structural, mechanical, and thermal properties of the composites with poly(vinyl chloride) (PVC) matrix and raw halloysite (HA) as well as its calcined product (KHA). The effectiveness of calcination was confirmed with X-ray diffraction, Fourier-transform infrared spectroscopy, scanning electron microscopy, and nitrogen adsorption method. The PVC composites with HA as well as KHA were processed in the molten state in the Brabender mixer chamber. The reduction of gelation time and simultaneous increase in maximum torque with filler content were found based on the results of plastographometric analysis. SEM images of PVC/halloysite composites showed a homogeneous distribution of the filler in the polymer matrix. The introduction of halloysite leads to a slight increase in Young’s modulus and tensile strength compared to neat PVC, where the increase of both parameters is greater when KHA is used. The incorporation of 1% KHA led to an increase in impact strength, an effect which may be attributed to toughening of the polymer. A slight improvement of the Vicat softening temperature of 2.7 degrees C for PVC/HA and heat deflection temperature of 2.4 C for PVC/KHA was also ascertained for PVC modified with 10 wt% of filler.

Słowa kluczowe

polymer composites mechanical properties thermal properties halloysite poly(vinyl chloride)

kompozyty polimerowe właściwości mechaniczne właściwości termiczne haloizyt chlorek winylu

Wydawca

Komitet Inżynierii Chemicznej i Procesowej Polskiej Akademii Nauk

Czasopismo

Chemical and Process Engineering

Rocznik

2022

Tom

Vol. 43, nr 3

Strony

383--–404

Opis fizyczny

Bibliogr. 57 poz., rys., tab.

Twórcy

autor

Wieczorek Martina

Bydgoszcz University of Science and Technology, Faculty of Chemical Technology and Engineering, Al. Prof. S. Kaliskiego 7, 85-796 Bydgoszcz, Poland

https://orcid.org/0000-0001-6294-5542

autor

Tomaszewska Jolanta

jolanta.tomaszewska@pbs.edu.pl

Bydgoszcz University of Science and Technology, Faculty of Chemical Technology and Engineering, Al. Prof. S. Kaliskiego 7, 85-796 Bydgoszcz, Poland

https://orcid.org/0000-0003-1361-7942

autor

Bajda Tomasz

AGH University of Science and Technology, Faculty of Geology, Geophysics and Environmental Protection, Al. A. Mickiewicza 30, 30-059, Kraków, Poland

https://orcid.org/0000-0003-3849-5558

autor

Długosz Jacek

Bydgoszcz University of Science and Technology, Faculty of Agriculture and Biotechnology, Al. Prof. S. Kaliskiego 7, 85-796 Bydgoszcz, Poland

https://orcid.org/0000-0002-3403-0588

Bibliografia

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