Kinetics of Polymorphic Transitions in Energetic Compounds

• Autorzy: Chukanov N. V. , Zakharov V. V. , Korsunskiy B. L. , Chervonnyi A. D. , Vozchikova S. A.
• Języki publikacji: EN

Abstrakty

EN

Available data on the kinetics of polymorphic transitions (PTs) in energetic compounds under isothermal conditions are summarized and discussed. It is shown that the general kinetic regularities of these processes (stepwise and continuous regimes) depend on their topotactic mode (frontal or quasi-homogeneous, respectively). In reverse PTs, a nucleation stage is not observed, which is explained by the presence of nuclei of the low-temperature polymorph in the preheated sample. The influence of mechanical effects on the kinetics of PTs in molecular crystals is discussed.

Słowa kluczowe

EN

polymorphic transitions; energetic compounds; molecular crystals; kinetics; calorimetry; IR spectroscopy

• Czasopismo: Central European Journal of Energetic Materials
• Rocznik: 2016
• Tom: Vol. 13, no. 2
• Strony: 483--504
• Opis fizyczny: Bibliogr. 41 poz., rys., tab.

Twórcy

autor

Chukanov N. V.

• Institute of Problems of Chemical Physics of Russian Academy of Sciences, Semenov av. 1, Chernogolovka, Moscow region, 142432, Russia

autor

Zakharov V. V.

• Institute of Problems of Chemical Physics of Russian Academy of Sciences, Semenov av. 1, Chernogolovka, Moscow region, 142432, Russia

autor

Korsunskiy B. L.

• Institute of Problems of Chemical Physics of Russian Academy of Sciences, Semenov av. 1, Chernogolovka, Moscow region, 142432, Russia

autor

Chervonnyi A. D.

• Institute of Problems of Chemical Physics of Russian Academy of Sciences, Semenov av. 1, Chernogolovka, Moscow region, 142432, Russia

autor

Vozchikova S. A.

• Institute of Problems of Chemical Physics of Russian Academy of Sciences, Semenov av. 1, Chernogolovka, Moscow region, 142432, Russia

Bibliografia

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Uwagi

Opracowanie ze środków MNiSW w ramach umowy 812/P-DUN/2016 na działalność upowszechniającą naukę.