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Tytuł artykułu

A preliminary assessment on the preparation of spirulina/PE blends by compression molding

Wybrane pełne teksty z tego czasopisma
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Warianty tytułu
Języki publikacji
EN
Abstrakty
EN
Substituting petrochemical plastics with biobased plastics from natural feedstock offers an environmentally friendly alternative to reduce the carbon footprint. Proteins are promising biopolymers that can be transformed into plastics and sourced from various types of biomass, such as microalgae. Microalgae, particularly spirulina, is considered an excellent renewable resource for bioplastic production due to its high protein content. This study focuses on the characterization of spirulina-polyethylene (PE) composites molded by compression molding technology. Both washed (for salt removal), and unwashed biomass were used in order to explore a potentially more sustainable and cost-effective option. Various loadings of both biomass types (5 % - 30 % by weight) were investigated, and the mechanical (tensile, flexural, and impact resistance) as well as thermal properties (thermogravimetric analysis and differential scanning calorimetry) of the resulting composites were determined. The mechanical properties remained nearly unchanged compared to neat PE when the biomass content was kept under 10 wt.% for both the washed and unwashed biomass. At higher biomass loadings, a reduction in mechanical per formance was observed; however, the molded parts maintained good aesthetics and acceptable properties. Despite the pre dictable adverse changes in thermal behavior, the processability of the materials was not affected. Differential scanning calorimetry indicated that total plasticization of the biomass protein was not achieved during the molding process. Additional ly, no significant differences were found between the washed and unwashed biomass, suggesting that using unwashed biomass could be more economically and environmentally beneficial.
Rocznik
Strony
238--245
Opis fizyczny
Bibliogr. 24 poz., rys., tab.
Twórcy
autor
  • Universidad de Las Palmas de Gran Canaria, Departamento de Ingeniería de Procesos, Edificio de Ingenierías, Campus universitario de Tafira Baja, 35017, Las Palmas de Gran Canaria, Spain
  • Universidad de Las Palmas de Gran Canaria, Departamento de Ingeniería de Procesos, Edificio de Ingenierías, Campus universitario de Tafira Baja, 35017, Las Palmas de Gran Canaria, Spain
autor
  • Universidad de Las Palmas de Gran Canaria, Departamento de Ingeniería Mecánica, Edificio de Ingenierías, Campus universitario de Tafira Baja, 35017, Las Palmas de Gran Canaria, Spain
autor
  • Universidad de Las Palmas de Gran Canaria, Departamento de Ingeniería de Procesos, Edificio de Ingenierías, Campus universitario de Tafira Baja, 35017, Las Palmas de Gran Canaria, Spain
Bibliografia
  • [1] Shanmugam V., Mensah R.A., Försth M. et al., Circular economy in biocomposite development: State-of-the-art, challenges and emerging trends, Compos Part C Open Access 2021, 5, 100138, DOI: 10.1016/j.jcomc.2021. 100138.
  • [2] Zeller M.A., Hunt R., Jones A., Sharma S., Bioplastics and their thermoplastic blends from Spirulina and Chlorella microalgae, J. Appl. Polym. Sci. 2013, 130, 3263-3275, DOI: 10.1002/APP.39559.
  • [3] Zhao X., Wang Y., Chen X. et al., Sustainable bioplastics derived from renewable natural resources for food packaging, Matter 2023, 6, 97-127.
  • [4] Álvarez-Castillo E., Bengoechea C., Felix M., Guerrero A., Protein-Based Bioplastics from Biowastes: Sources, Proces sing, Properties and Applications, In: Bioplastics for Sustaina ble Development, Springer, Singapore 2021, 137-176.
  • [5] Khalis S.A., The Effect of Compatibilizer Addition on Chlorella vulgaris Microalgae Utilization as a Mixture for Bioplastic, E3S Web Conf. 2018, 67, 03047, DOI: 10.1051/ e3sconf/20186703047
  • [6] Zhu N., Ye M., Shi D., Chen M., Reactive compatibilization of biodegradable poly(butylene succinate)/Spirulina microalgae composites, Macromol. Res. 2017, 25, 165-171, DOI: 10.1007/S13233-017-5025-9/METRICS.
  • [7] Dianursanti, Gozan M., Noviasari C., The effect of glycerol addition as plasticizer in Spirulina platensis based bioplastic, E3S Web Conf. 2018, 67, 03048, DOI: 10.1051/ E3SCONF/20186703048.
  • [8] Sabathini H.A., Windiani L., Dianursanti, Gozan M., Mechanical physicial properties of chlorella-PVA based bioplastic with ultrasonic homogenizer, E3S Web Conf. 2018, 67, 03046, DOI: 10.1051/E3SCONF/20186703046.
  • [9] Shi B., Wideman G., Wang J.H., A New Approach of BioCO2 fixation by thermoplastic processing of microalgae, J. Polym. Environ. 2012, 20, 124-131, DOI: 10.1007/ S10924-011-0329-X.
  • [10] Torres S., Navia R., Campbell Murdy R. et al., Green composites from residual microalgae biomass and poly(butyl ene adipate-co-terephthalate): Processing and plasticization, ACS Sustain. Chem. Eng. 2015, 3, 614-624, DOI: 10.1021/ SC500753H/ASSET/IMAGES/LARGE/SC-2014-00753H _0004.JPEG.
  • [11] Ciapponi R., Turri S., Levi M., Mechanical reinforcement by microalgal biofiller in novel thermoplastic biocompo unds from plasticized gluten, Materials (Basel) 2019, 12, DOI: 10.3390/MA12091476.
  • [12] Kim G.M., Chang W.S., Kim Y.K., Biocomposites using whole or valuable component-extracted microalgae blended with polymers: A review, Catalysts 2021, 12, 25, DOI: 10.3390/CATAL12010025.
  • [13] Bhattacharya M., Goswami S., Microalgae - A green multi product biorefinery for future industrial prospects, Biocatal. Agric. Biotechnol. 2020, 25, 101580, DOI: 10.1016/J. BCAB.2020.101580.
  • [14] Díaz S., Romero F., Suárez L. et al., Characterization of microalgae biomass-based composites obtained through rotational molding, polymers (Basel) 2024, 16, 1807, DOI: 10.3390/polym16131807.
  • [15] Chan W.Y., Proteins in the design of sustainable plastics alternatives, MRS Commun. 2023, 13, 1009-1024, DOI: 10.1557/s43579-023-00481-9.
  • [16] Cinar S.O., Chong Z.K., Kucuker M.A. et al., Bioplastic production from microalgae: A review, Int. J. Environ. Res. Public Health 17:3842, 2020, DOI: 10.3390/IJERPH17 113842.
  • [17] Fabra M.J., Martínez-Sanz M., Gómez-Mascaraque L.G. et al., Structural and physicochemical characterization of thermoplastic corn starch films containing microalgae, Carbohydr. Polym. 2018, 186 184-191, DOI: 10.1016/ J.CARBPOL.2018.01.039.
  • [18] Otsuki J., Zhang F., Kabeya H., Hirotsu T., Synthesis and tensile properties of a novel composite of Chlorella and polyethylene, J. Appl. Polym. Sci. 2004, 92, 812-816, DOI: 10.1002/APP.13650.
  • [19] Zhang F., Endo T., Kitagawa R. et al., Synthesis and characterization of a novel blendof polypropylene with Chlorella, J. Mater. Chem. 2000, 10, 2666-2672, DOI: 10.1039/B004489J.
  • [20] Saha P., Aloui H., Yun J.H. et al., Development of a novel composite film based on polyurethane and defatted Chlorella biomass: Physical and functional characterization, J. Appl. Polym. Sci. 2021, 138, 50152, DOI: 10.1002/APP. 50152.
  • [21] Tran D.T., Lee H.R., Jung S. et al., Lipid-extracted algal biomass based biocomposites fabrication with poly(vinyl alcohol), Algal Res. 2018, 31 525-533, DOI: 10.1016/ J.ALGAL.2016.08.016.
  • [22] Guidi F., Gojkovic Z., Venuleo M. et al., Long-term cultivation of a native arthrospira platensis (Spirulina) strain in pozo izquierdo (Gran Canaria, Spain): Technical evidence for a viable production of food-grade biomass, Processes 2021, 9, 1333, DOI: 10.3390/pr9081333.
  • [23] Grewell D., Schrader J., Srinivasan G., Developing protein based plastics, In: ACS Symposium Series, American Chemical Society 2014, 357-370.
  • [24] Hejna A., Barczewski M., Andrzejewski J. et al., Rotational molding of linear low-density polyethylene composites filled with wheat bran, Polymers (Basel) 2020, 12, 1004, DOI: 10.3390/polym12051004.
Uwagi
Opracowanie rekordu ze środków MNiSW, umowa nr POPUL/SP/0154/2024/02 w ramach programu "Społeczna odpowiedzialność nauki II" - moduł: Popularyzacja nauki (2025).
Typ dokumentu
Bibliografia
Identyfikator YADDA
bwmeta1.element.baztech-957fbd01-cc2b-46d0-9777-2e648597bf57
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