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Enthalpy of isopropanol adsorption on zeolite

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Warianty tytułu
Języki publikacji
EN
Abstrakty
EN
The enthalpy of isopropanol adsorption on ZSM-5 (Zeolite Socony Mobil Framework Type MFI) was determined by the static adsorption method at the temperature range from 20°C to 100°C. Langmuir and Huttig models of equilibrium adsorption have been used to calculate the enthalpy of isopropanol adsorption at these conditions. Adsorption isotherms determined by the flow method at 20°C and 30°C have been also used in the calculations. The obtained values of isopropanol adsorption enthalpy were compared with the values of isopropanol evaporation enthalpy and with the results obtained from isopropanol and water desorption measurements with thermogravimetry and differential scanning calorimetry methods.
Słowa kluczowe
Rocznik
Strony
58--65
Opis fizyczny
Bibliogr. 14 poz., rys., tab.
Twórcy
  • West Pomeranian University of Technology, Department of Organic and Physical Chemistry, Al. Piastów 42, 71-065, Szczecin, Poland
  • West Pomeranian University of Technology, Department of Organic and Physical Chemistry, Al. Piastów 42, 71-065, Szczecin, Poland
  • West Pomeranian University of Technology, Department of Organic and Physical Chemistry, Al. Piastów 42, 71-065, Szczecin, Poland
  • West Pomeranian University of Technology, Department of Organic and Physical Chemistry, Al. Piastów 42, 71-065, Szczecin, Poland
  • West Pomeranian University of Technology, Department of Organic and Physical Chemistry, Al. Piastów 42, 71-065, Szczecin, Poland
  • West Pomeranian University of Technology, Department of Inorganic and Analytical Chemistry, Al. Piastów 42, 71-065, Szczecin, Poland
autor
  • West Pomeranian University of Technology, Department of Inorganic and Analytical Chemistry, Al. Piastów 42, 71-065, Szczecin, Poland
  • West Pomeranian University of Technology, Institute of Chemical and Environment Engineering, Al. Piastów 42, 71-065, Szczecin, Poland
Bibliografia
  • 1. Arnaut L. Formosinho S. & Burrows H. (2007). Chemical Kinetics From Molecular Structure to Chemical Reactivity. pp. 251–272. Elsevier B.V.
  • 2. Saha D. & Grappe H.A. (2017). Adsorption properties of activated carbon fibers. Activated Carbon Fiber and Textiles A volume in Woodhead Publishing Series in Textiles pp. 143–165 DOI:10.1016/B978-0-08-100660-3.00005-5.
  • 3. Nastaj J. & Aleksandrzak T. (2012). Comparison of static and dynamic methods of adsorption isotherms determination. 20th International Congress of Chemical and Process Engineering CHISA 2012 and the 15th Conference on Process Integration Modelling and Optimisation for Energy Saving and Pollution Reduction PRES 2012 Prague Czech Republic.
  • 4. Downarowicz D. (2015). Adsorption characteristics of propan-2-ol vapours on activated carbon Sorbonorit 4 in electrothermal temperature swing adsorption process. Adsorption. 21 1–2 pp 87–98 DOI: 10.1007/s10450-015-9652-1.
  • 5. Nastaj, J., Ambrożek, B., Witkiewicz, K. & Rudnicka, J. (2016). Adsorption Isotherms of Propan-2-ol, Methylbenzene, and Tetrachloromethane on Selected Activated Carbons. J. Chem. & Engin. Data, 61(10), 3559–3569, DOI: 10.1021/acs. jced.6b00488.
  • 6. Prestianni, A., Cortese, R. & Duca, D. (2013). Propan- 2-ol dehydration on H-ZSM-5 and H-Y zeolite: a DFT study. Reaction Kinetics, Mechanisms and Catalysis. 108(2), pp. 565–582. DOI: 10.1007/s11144-012-0522-5.
  • 7. Chang F.T. Lin Y.C. Hsunling B. & Bau-Shei P. (2003). Adsorption and desorption characteristics of semiconductor volatile organic compounds on the thermal swing honeycomb zeolite concentrator. J. Air & Waste Manage. Assoc. 53(11) pp. 1384–1390.
  • 8. Nastaj J. & Aleksandrzak T. (2013). Adsorption Isotherms of Water Propan-2-ol and Methylbenzene Vapors on Grade 03 Silica Gel Sorbonorit 4 Activated Carbon and HiSiv 3000 Zeolite. J. Chem. Engine. Data pp. 2629–2641 DOI:10.1021/je400517c.
  • 9. UOP LLC advertising materials Retrieved July 15 2019 from https://www.chemia.ch/upload/files/pdf/gb%20industrie/1445/PD_HiSiv3000.pdf
  • 10. Bläker Ch. Pasel Ch. Luckas M. Dreisbach F. & Bathen D. (2017). Investigation of load-dependent heat of adsorption of alkanes and alkenes on zeolites and activated carbon Microporous and Mesoporous Materials 241 pp. 1–10 DOI: 10.1016/j.micromeso.2016.12.037.
  • 11. Carlone D. Rickard B. & Scaccia A. (2010). Zeolite Catalyzed Ozonolysis A Major Qualifying Project Proposal submitted to the Faculty and Staff of Worcester Polytechnic Institute for requirements to achieve the Degree of Bachelor of Science in Chemical Engineering.
  • 12. Harlick P.J.E. & Teze F.H. (2004). An experimental adsorbent screening study for CO2 removal from N2 Microporous and Mesoporous Materials. 76 (1–3) pp. 71–79 DOI: 10.1016/j.micromeso.2004.07.035.
  • 13. Yaw’s C.L. (2009). Yaw’s Handbook of Thermodynamic Properties for Hydrocarbons and Chemicals Knovel Retrieved July 15 2019 from https://app.knovel.com/web/.
  • 14. Jabłoński M. & Paderewski M. (1981). Extension of the Huttig isotherm on mixed gas adsorption. Monatshefte fur Chemie 112 pp. 533–536.
Typ dokumentu
Bibliografia
Identyfikator YADDA
bwmeta1.element.baztech-952becae-d73d-4a1f-81b0-3a6ed173a5ba
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