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This work presents the development of a safer processing route for hard metals. Traditional processing of fine particles under organic solvents presents significant explosion risks. The milling under dichloromethane (DCM) reduces the risks associated with fire hazards. After milling and drying, the samples have been sintered in an industrial sintering furnace under a vacuum at 1380°C. The materials’ characterisation has been done by X-ray diffraction, scanning electron microscopy, particle size analysis, optical microscopy, and by magnetic measurements. The present work results reveal the powders’ appropriate properties after milling and drying and the desired biphasic (Co-WC) phases obtained after sintering, thus proving the feasibility of such a route, therefore the diminishing of specific fire hazards.
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Tom
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541--545
Opis fizyczny
Bibliogr. 23 poz., fot., rys.
Twórcy
autor
- Technical University of Cluj-Napoca, Materials Science and Engineering Department, 103-105 Muncii Avenue, 400641 Cluj-Napoca, Romania
- Gühring Romania, 32 Constructorilor Street, 407035 Apahida, Romania
autor
- Technical University of Cluj-Napoca, Materials Science and Engineering Department, 103-105 Muncii Avenue, 400641 Cluj-Napoca, Romania
autor
- Technical University of Cluj-Napoca, Materials Science and Engineering Department, 103-105 Muncii Avenue, 400641 Cluj-Napoca, Romania
- Gühring Romania, 32 Constructorilor Street, 407035 Apahida, Romania
autor
- Technical University of Cluj-Napoca, Materials Science and Engineering Department, 103-105 Muncii Avenue, 400641 Cluj-Napoca, Romania
- Gühring Romania, 32 Constructorilor Street, 407035 Apahida, Romania
autor
- Technical University of Cluj-Napoca, Materials Science and Engineering Department, 103-105 Muncii Avenue, 400641 Cluj-Napoca, Romania
autor
- Technical University of Cluj-Napoca, Materials Science and Engineering Department, 103-105 Muncii Avenue, 400641 Cluj-Napoca, Romania
Bibliografia
- [1] J. García, V. Collado Ciprés, A. Blomqvist, B. Kaplan, Cemented Carbide Microstructures: A Review, International Journal of Refractory Metals and Hard Materials Elsevier Ltd 80, 40-68, (2019).
- [2] V.I. Stanciu, V. Vitry, F. Delaunois, Influence of the milling parameters on the sintering behaviour of WC-Co Composites, Mater. Manuf. Process 35, 7, 811-816 (2020).
- [3] S. Norgren, J. García, A. Blomqvist, L. Yin, Trends in the P/M hard metal industry, International Journal of Refractory Metals and Hard Materials, Elsevier Ltd 48. 31-45, (2015).
- [4] H.F. Chicinaş et al., Preparation and characterisation of WC-10Co powders obtained by aqueous milling, Ceram. Int. 44, 18, 22935-22942 (2018).
- [5] H.F. Chicinaş, T.F. Marinca, P. Götze, A. Eckert, C.O. Popa, Influence of aqueous milling duration on the sintered WC-10Co hard metal powders, J. Mater. Sci. 53, 4, (2018).
- [6] A.S. Kurlov, A.I. Gusev, Tungsten carbides, Springer Ser. Mater. Sci. 184, 34-6 (2013).
- [7] H.F. Chicinaş et al., Influence of milling media on the structure and agglomeration behaviour of some hardmetal powder, Powder Metall. 61, 4, 342-347 (2018).
- [8] S.A. Hewitt, K.A. Kibble, Effects of ball milling time on the synthesis and consolidation of nanostructured WC-Co composites, Int. J. Refract. Met. Hard Mater. 27, 6, 937-948 (2009).
- [9] R.M. Raihanuzzaman, T.S. Jeong, R. Ghomashchi, Z. Xie, S.-J. Hong, Characterisation of short-duration high-energy ball milled WC-Co powders and subsequent consolidations, SI ISMANAM 2013, 615, Suppl, pp. S564-S568 (2014).
- [10] O.D. Jucan, R.V. Gădălean, H.F. Chicinaş, M. Hering, N. Bâlc, C.O. Popa, Study on the indirect selective laser sintering (SLS) of WC-Co/PA12 powders for the manufacturing of cemented carbide parts, Int. J. Refract. Met. Hard Mater. 96, 105498, (2021).
- [11] K.M. Andersson, L. Bergström, Oxidation and dissolution of tungsten carbide powder in water. Int. J. Refract. Met. Hard Mater. 18, 2-3, 121-129 (2020).
- [12] H.F. Chicinaş et al., Influence of milling media on the properties of some hard metal powders, Int. J. Refract. Met. Hard Mater. 96, 105470 (2021).
- [13] E. Laarz, L. Bergström, Dispersing WC-Co powders in aqueous media with polyethylenimine, Int. J. Refract. Met. Hard Mater. 18, 6, 281-286 (2020).
- [14] “Common Chemistry - Substance Details - 75-09-2: Methane, dichloro-.” [Online]. Available: http://www.commonchemistry.org/chemicalDetail.aspx?ref=75-09-2&terms=dichloromethane. [accessed: 02-Jul-2018].
- [15] V.I. Stanciu, V. Vitry, F. Delaunois, Tungsten carbide powder obtained by direct carburisation of tungsten trioxide using mechanical alloying method, J. Alloys Compd. 659, 302-308 (2016).
- [16] A. Formisano, F. Capece Minutolo, A. Caraviello, L. Carrino, M. Durante, A. Langella, Influence of Eta-Phase on Wear Behavior of WC-Co carbides, Adv. Tribol. 2016 (2016).
- [17] H. Moumeni, S. Alleg, J.M. Greneche, Structural properties of Fe50Co50 nanostructured powder prepared by mechanical alloying, J. Alloys Compd. 386, 1-2, 12-19 (2005).
- [18] B.V. Neamţu, H.F. Chicinaş, T.F. Marinca, O. Isnard, I. Chicinaş, Preparation and characterisation of Co-Fe-Ni-M-Si-B (M = Zr, Ti) amorphous powders by wet mechanical alloying, J. Alloys Compd. 673 (2016).
- [19] J. Sun, L. Gao, Dispersing SiC powder and improving its rheological behaviour, J. Eur. Ceram. Soc. 21, 13, 2447-2451(2001).
- [20] R. Ramachandra Rao, H.N. Roopa, T.S. Kannan, Effect of the pH on the dispersability of silicon carbide powders in aqueous media, Ceram. Int. 25, 223-230 (1999).
- [21] K. Kendall, Agglomerate strenght, Powder Metall. 31, 28-31 (1988).
- [22] C.M. Fernandes, A.M.R. Senos, Cemented carbide phase diagrams: a review, Int. J. Refract. Met. Hard Mater. 29, 4, 405-418 (2011).
- [23] G.S. Upadhyaya, 4 - Consolidation of Cemented Carbides, G.S. Upadhyaya, ed. Westwood, NJ: William Andrew Publishing pp. 89-137 (1998).
Uwagi
1. This paper was supported by the project POCU/380/6/13/123927 - ANTREDOC, “Entrepreneurial competencies and excellence research in doctoral and postdoctoral study programs” co-funded from the European Social Fund through the Human Capital Operational Program 2014-2020. Besides this, the infrastructure available from the European Development Fund and the Romanian Government through the Competitiveness Operational Programme 2014-2020, project ID P 34 466, MySMIS code 121349, contract no.5/05.06.2018 is highly acknowledged.
2. Opracowanie rekordu ze środków MEiN, umowa nr SONP/SP/546092/2022 w ramach programu "Społeczna odpowiedzialność nauki" - moduł: Popularyzacja nauki i promocja sportu (2022-2023).
Typ dokumentu
Bibliografia
Identyfikator YADDA
bwmeta1.element.baztech-9527a7cd-117d-4eeb-9566-ff89a75f007c