Novel High-Nitrogen Content Energetic Compounds with High Detonation and Combustion Performance for use in Plastic Bonded Explosives (PBXs) and Composite Solid Propellants

• Autorzy: Keshavarz M. H. , Abadi Y. H. , Esmaeilpour K. , Damiri S. , Oftadeh M.

Identyfikatory

DOI

10.22211/cejem/78091

• Języki publikacji: EN

Abstrakty

EN

Five novel high-nitrogen content (N>50%) derivatives of tetrazole are introduced in the study reported here. The assessment of various properties of these compounds were performed, which include physicothermal properties (crystal density, condensed phase heat of formation, melting point, enthalpy of fusion and entropy of fusion), detonation performance (velocity and pressure of detonation, detonation temperature and power), sensitivity with respect to external stimuli (impact, shock, friction and electric spark) and combustion performance (specific impulse). The predicted results of these compounds are compared with dihydroxylammonium 5,5’-bistetrazole-1,1’-diolate (TKX-50) and octanitro-1,3,5,7-tetranitro-1,3,5,7-tetrazocine (HMX) as a high performance ionic salt and a neutral explosive, respectively. The novel energetic compounds were found to have higher detonation and combustion performance than either TKX-50 or HMX. The new explosives are therefore good candidates to obtain high detonation and combustion performance in plastic bonded explosives (PBXs) and composite solid propellants, respectively.

Słowa kluczowe

EN

tetrazoles derivatives; detonation performance; combustion performance; sensitivity

• Wydawca: Sieć Badawcza Łukasiewicz - Instytut Przemysłu Organicznego
• Czasopismo: Central European Journal of Energetic Materials
• Rocznik: 2018
• Tom: Vol. 15, no. 2
• Strony: 364--375
• Opis fizyczny: Bibliogr. 50 poz., rys., tab.

Twórcy

autor

Keshavarz M. H.

• Malek-ashtar University of Technology, 83145/115 Shahin-shahr, Islamic Republic of Iran

autor

Abadi Y. H.

• Malek-ashtar University of Technology, 83145/115 Shahin-shahr, Islamic Republic of Iran

autor

Esmaeilpour K.

• Malek-ashtar University of Technology, 83145/115 Shahin-shahr, Islamic Republic of Iran

autor

Damiri S.

• Malek-ashtar University of Technology, 83145/115 Shahin-shahr, Islamic Republic of Iran

autor

Oftadeh M.

• Chemistry Department, Payame Noor University, 19395-4697 Tehran, Islamic Republic of Iran

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Uwagi

Opracowanie rekordu w ramach umowy 509/P-DUN/2018 ze środków MNiSW przeznaczonych na działalność upowszechniającą naukę (2019).