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The present study was focused on the technical feasibility of using immobilized hybrid biomass of Pleurotos sajor-caju and sunflower for Pb(II) removal from the contaminated water. After preliminary evaluation, it was found that immobilized hybrid biomass of Pleurotos sajor-caju and sun-flower effectively removed Pb(II) from wastewater at pH 4.5. The effect of various experimental parameters on Pb(II) uptake by hybrid biosorbent was systematically evaluated in a batch biosorption system. The optimized biosorbent dose, contact time, initial metal concentration and temperature were 0.05 g/100 cm 3, 180 min, 800 mg/dm3 and 60 °C. Dynamics of the adsorption process were studied, and the values of rate constants of pseudo first order and pseudo second order kinetic models were calculated. Equilibrium isotherms for the adsorption of Pb(II) were analyzed by the Langmuir and Freundlich isotherm models. The sorption of Pb(II) followed the pseudo second order kinetic model. The Langmuir sorption isotherm fitted well to Pb(II) concentration data. The results revealed that this new hybrid biosorbent system was a promising candidate for eliminating Pb(II) from contaminated aquatic environment.
Czasopismo
Rocznik
Tom
Strony
5--15
Opis fizyczny
Bibliogr. 23 poz., tab., rys.
Twórcy
autor
- Department of Chemistry and Biochemistry, University of Agriculture, Faisalabad-38040-Pakistan
autor
- Department of Chemistry and Biochemistry, University of Agriculture, Faisalabad-38040-Pakistan
autor
- Department of Chemistry and Biochemistry, University of Agriculture, Faisalabad-38040-Pakistan
autor
- Department of Chemistry and Biochemistry, University of Agriculture, Faisalabad-38040-Pakistan
autor
- Department of Chemistry, Bahauddin Zakariya University, Multan, Pakistan
Bibliografia
- [1] SHAN UM-E-A., IKRAM N., Heavy metals in human scalp hair and nail samples from Pakistan: influence of working and smoking habits, Int. J. Chem. Biochem. Sci., 2012, 1, 54.
- [2] ALAM M., NADEEM R., JILANI M.I., Pb(II) removal from wastewater using Pomegranate waste biomass, Int. J. Chem. Biochem. Sci., 2012, 1, 48
- [3] SAG Y.I., TATAR B., KUTSAL T., Biosorption of Pb(II) and Cu(II) by activated sludge in batch and continuous-owstirred reactors, Bioresource Technol., 2003, 87, 27.
- [4] KASHEFI M., SALARYAN P., HAZERI N., VALIZADEH J., ABDI A., MOHAMMADNIA M.S., Biosorption of Cr(VI) from aqueous solutions using carum copticum stem, Int. J. Chem. Biochem. Sci., 2012, 1, 48.
- [5] SAIFUDDIN N., RAZIAH A.Z., Removal of heavy metals from industrial effluent using Saccharomyces cerevisiae (baker’s yeast) immobilized in chitosan/lignosulphonate matrix, J. Appl. Sci. Res., 2007, 3 (12), 2091.
- [6] NASIR H.M., NADEEM R., AKHTER K., HANIF M.A., KHALID A.M., Efficacy of modified distillation sludge of rose (Rosa centifolia) petals for lead(II) and zinc(II) removal from aqueous solutions, J. Hazard. Mater., 2007, 147, 1006.
- [7] TUNALI S., CABUK A., AKAR T., Removal of Pb(II) and Cu (II) ions from aqueous solutions by bacterial strains isolated from soil, Chem. Eng., 2006, 115, 203.
- [8] CHEN Z.J., TAO X.C., XU J., ZHANG T., LIU Z.L., Biosorption of lead, cadmium and mercury by immobilized microcystis aeruginosa in a column, Process Biochem., 2005, 40, 3675.
- [9] HANIF M.A., NADEEM R., BHATTI H.N., AHMAD N.R., ANSARI T.M., Ni(II) biosorption by Cassia fistula (Golden Shower) biomass, J. Hazard. Mater., 2007, 139, 345.
- [10] ANSARI T.M., HANIF M.A., ABIDA M., IJAZ U., KHAN M.A., NADEEM R., ALI M., Immobilization of rose waste biomass for uptake of Pb(II) from aqueous solutions, Biotechnol. Res. Int., 2011, 2011, 1.
- [11] IQBAL M., EDYVEAN R.G.J., Biosorption of lead, copper and zinc ions on loofa sponge immobilized biomass of Phanerochaete chrysosporium, Miner. Eng., 2004, 17, 217.
- [12] IFTIKHAR A.R., BHATTI H.N., HANIF M.A., NADEEM R., Kinetic and thermodynamic aspects of Cu(II) and Cr(III) removal from aqueous solution using rose waste biomass, J. Hazard. Mater., 2009, 161, 941.
- [13] BHATTI H.N., KHALID R., HANIF M.A., Dynamic biosorption of Zn(II) and Cu(II) using pretreated Rosa gruss an Teplitz (red rose) distillation sludge, Chem. Eng. J., 2008, 52, 564.
- [14] MANTHAR S.F., OLVERA E.A., ROLLEMBERY M.C., Removal of metal ion from aqueous solution by sorption on to rice bran, J. Hazard. Mater., 2005, 117, 207.
- [15] NADEEM R., ANSARI T.M., KHALID A.M., Fourier transform infrared spectroscopic characterization and optimization of Pb(II) biosorption by fish (Labeo rohita) scales, J. Hazard. Mater., 2008, 156, 64.
- [16] NADEEM R., HANIF M.A., SHAHEEN F., PERVEEN S., ZAFAR M.N., IQBAL T., Physical and modification of distillery sludge for Pb(II) biosorption, J. Hazard. Mater., 2007, 150, 335.
- [17] ARSHAD M., ZAFAR M.N., YOUNIS S., NADEEM R., The use of Neem biomass for the biosorption of zinc from aqueous solution, J. Hazard. Mater., 2008, 157, 534.
- [18] JNR M.H., SPIFF A.I., Effect of metal ion concentration on the biosorption of Pb(II) and Cd (III) by Caladium bicolor (wild cocoyam), Afr. J. Biotechnol., 2005, 4 (2), 191.
- [19] XUE-JIANG W., SI-QING X., Biosorption of cadmium II and lead II ion from aqueous solution onto dried activated sludge, J. Env. Sci., 2006, 18 (5), 840.
- [20] BHATTI H.N., MUMTAZ B., HANIF M.A., NADEEM R., Removal of Zn(II) ions from aqueous solution using Moringa oleifera Lam (horse radish tree) biomass, Process Biochem., 2007, 42, 547.
- [21] RIAZ M., NADEEM R., HANIF M.A., ANSARI TM., REHMAN K.U., Pb(II) biosorption from hazardous aqueous streams using Gossypium hirsutum (cotton) waste biomass, J. Hazard. Mater., 2009, 161, 88.
- [22] JAVED A.M., BHATTI H.N., HANIF M.A., NADEEM R., Kinetic and equilibrium modeling of Pb(II) and Co(II) sorption onto rose waste biomass, Sep. Sci. Technol., 2007, 42, 3641.
- [23] SARI A., TUZEN M., ULUUOZLU O.D., SOYLAK M., Biosorption of Pb(II) and Ni(II) from aqueous solution by licken (Cladonia furcata) biomass, Biochem. Eng. J., 2007, 37, 151.
Typ dokumentu
Bibliografia
Identyfikator YADDA
bwmeta1.element.baztech-94d32d1f-5044-49c8-bc3c-1a4ac61c4e3c