PL EN


Preferencje help
Widoczny [Schowaj] Abstrakt
Liczba wyników
Tytuł artykułu

Effect of manganese ions addition orders on the flotation behavior of scheelite

Treść / Zawartość
Identyfikatory
Warianty tytułu
Języki publikacji
EN
Abstrakty
EN
In this study, the effect of MnCl2 on scheelite flotation with sodium oleate (NaOL) as a collector and sodium silicate as a depressant was assessed by a combination of flotation experiments, Fouriertransform infrared spectroscopy (FTIR), X-ray photoelectron spectroscopy (XPS), and solution chemistry. The flotation experiments confirmed that the addition of MnCl2 before sodium silicate showed an adverse effect on flotation and the recovery of scheelite gradually decreased as the amount of MnCl2 was increased. When MnCl2 was added afte r sodium silicate, the recovery of scheelite gradually increased with an increase in the amount of MnCl2. The results of FTIR, XPS, and solution chemistry indicated that MnCl2 acted on the surface of scheelite in the form of manganese ions. When MnCl2 was added before sodium silicate, manganese ions adsorbed on the surface of scheelite reacted with sodium silicate to form a hydrophilic silicate, which covers the surface of scheelite and blocks the adsorption of NaOL. However, when MnCl2 was added after sodium silicate, manganese ions are continued to be adsorbed on the surface of scheelite, which increases the cations on the surface of scheelite, and hence the condition becomes conducive for the interaction between scheelite and NaOL.
Słowa kluczowe
Rocznik
Strony
860--873
Opis fizyczny
Bibliogr. 37 poz., rys., tab.
Twórcy
autor
  • Faculty of Land Resource Engineering, Kunming University of Science and Technology, Kunming 650093, China
autor
  • The comprehensive utilization of resources in Xinyu Xingang Technology Co. Ltd
autor
  • Faculty of Land Resource Engineering, Kunming University of Science and Technology, Kunming 650093, China
  • State Key Laboratory of Complex Nonferrous Metal Resources Clean Utilization, Kunming 650093, China
autor
  • Faculty of Land Resource Engineering, Kunming University of Science and Technology, Kunming 650093, China
autor
  • Faculty of Land Resource Engineering, Kunming University of Science and Technology, Kunming 650093, China
  • Faculty of Land Resource Engineering, Kunming University of Science and Technology, Kunming 650093, China
Bibliografia
  • CHENG, L., FENG, Q., ZHAN, G., WEI, C., CHEN, Y., 2016. Effect of depressants in the selective flotation of scheelite and calcite using oxidized paraffin soap as collector. J International Journal of Mineral Processing 157:210-215.
  • CHEN, W., FENG, Q., ZHANG, G., YANG, Q., ZHANG, C., XU, F., 2017. The flotation separation of scheelite from calcite and fluorite using dextran sulfate sodium as depressant, J. Miner. Process, 169, 53–59.
  • CHEN, W., FENG, Q., ZHANG, G., YANG, Q., 2018. Investigations on flotation separation of scheelite from calcite by using a novel depressant: Sodium phytate. J Minerals Engineering 126:116-122.
  • CHEN, R., 2019. The influence of ionic wolframite flotation is unavoidable [D]. Kunming University of Science and Technology.
  • DENG, R., YANG, X., YUAN, H., KU, J., ZUO, W., MA, Y., 2018. Effect of Fe(II) as assistant depressant on flotation separation of scheelite from calcite. J Minerals Engineering 118:133-140.
  • DONG, L., JIAO, F., QIN, W., LIU, W., 2019. Selective flotation of scheelite from calcite using xanthan gum as depressant. J Minerals Engineering 138:14-23.
  • DONG, L., JIAO, F., QIN, W., LIU, W., 2019. Effect of calcium ions on scheelite flotation using mixed collectors. J Separation Science Technology 54(1):153-162.
  • DONG, L., JIAO, F., QIN, W., LIU, W., ZHU, H., JIA, W., 2019. Selective depressive effect of sodium fluorosilicate on calcite during scheelite flotation. Minerals Engineering 131, 262–271.
  • ESPIRITU, E.R.L., NASERI, S., WATERS., K.E., 2018. Surface chemistry and flotation behavior of dolomite, monazite and bastnäsite in the presence of benzohydroxamate, sodium oleate and phosphoric acid ester collectors. J Colloids Surfaces A: Physicochemical Engineering Aspects 546:254-265.
  • FENG, B., LUO, X., WANG, J., WANG, P., 2015. The flotation separation of scheelite from calcite using acidified sodium silicate as depressant. Minerals Engineering 80:45-49.
  • FENG, B., GUO, W., XU, H., PENG, J., LUO, X., ZHU, X., 2016. The combined effect of lead ion and sodium silicate in the flotation separation of scheelite from calcite. Separation Science 52(3):567-573.
  • FLIPPOVA, I.V., FILIPPOV, L.O., LAFHAJ, Z., BARRES, O., DANIEL, F., 2018. Effect of calcium minerals reactivity on fatty acids adsorption and flotation. J Colloids Surfaces A Physicochemical Engineering Aspects 545:157-166.
  • GAO, Y., GAO, Z., SUN, W., HU, Y., 2016. Selective flotation of scheelite from calcite: A novel reagent scheme. J International Journal of Mineral Processing 154(154):10-15.
  • GAO, Z., SUN, W., HU, Y., 2015. New insights into the dodecylamine adsorption on scheelite and calcite: An adsorption model. J Minerals Engineering 79:54-61.
  • HAN, H., HU, Y., SUN, W., LI, D., CAO, C., LIU, R., YUE, T., MENG, X., GUO, Y., WANG, J., GAO, Z., CHEN, P., HUANG, W., LIU, J., XIE, J., CHEN, Y., 2017. Fatty acid flotation versus BHA flotation of tungsten minerals and their performance in flotation practice. International Journal of Mineral Processing. 159, 22-29.
  • HU, Y., GAO, Z., SUN, W., 2012. Anisotropic surface energies and adsorption behaviors of scheelite crystal. J Colloids Surfaces A Physicochemical Engineering Aspects 415(48):439-448.
  • IGNATKINA, V. A., 2017. Experimental investigation of change in the contrast between flotation properties of calcic minerals. J Journal of Mining Science 53(5):897-906.
  • KUPKA, N., RUDOLPH, M., 2018. Froth flotation of scheelite – A review. International Journal of Mining Science Technology 28(3): 373-384.
  • LI, C., LU, Y., 1983. Selective flotation of scheelite from calcium minerals with sodium oleate as a collector and phosphates as modifiers. II. The mechanism of the interaction between phosphate modifiers and minerals. J International Journal of Mineral Processing 10(3):219-235.
  • LI, Y., LI, C., 1983. Selective flotation of scheelite from calcium minerals with sodium oleate as a collector and phosphates as modifiers. I. Selective flotation of scheelite Int. J Miner. Process., 10(3), 205-218.
  • MARINAKIS, K.I., SHERGOLD, H.L., 1985. Influence of sodium silicate addition on the adsorption of oleic acid by fluorite, calcite and barite. J International Journal of Mineral Processing 14(3):177-193.
  • SUN, W., TANG, H., CHEN, C., 2013. Solution chemistry behavior of sodium silicate in flotation of fluorite and scheelite. J Chinese Journal of Nonferrous Metals 23(8):2274-2283.
  • SUN, W., WANG, R., HU, Y., HAN, H., 2018. Activation and new theory of lead ion in minerals flotation process. J Nonferrous Metals (Mineral Processing Section), 70(2): 91−98.
  • TIAN, M., LIU, R., GAO, Z., CHEN, P., HAN, H., L, WANG., ZHANG, C., SUN, W., HU, Y., 2018. Activation mechanism of Fe (III) ions in cassiterite flotation with benzohydroxamic acid collector. J Minerals Engineering 119:31-37.
  • WANG, J., BAI, J., YIN, W., LIANG, X., 2018. Flotation separation of scheelite from calcite using carboxyl methyl cellulose as depressant. J Minerals Engineering. 127, 329-333.
  • WANG, J., MAO, Y., CHENG, Y., XIAO, Y., ZHANG, Y., BAI, J., 2019. Effect of Pb(II) on the flotation behavior of scheelite using sodium oleate as collector. J Minerals Engineering. 136, 161-167
  • WANG, Z., WU, H., XU, Y., SHU, K., Yang, J., LUO, L., XU, L. 2020. Effect of dissolved fluorite and barite species on the flotation and adsorption behavior of bastnaesite. Separation and Purification Technology, 237, 116387.
  • WANG, Z., WU, H., XU, Y., SHU, K., Yang, J., LUO, L., XU, L. 2020. The effect of dissolved calcite species on the flotation of bastnaesite using sodium oleate. Minerals Engineering, 145, 106095.
  • WEI, Z., SUN, W., HAN, H., CAO, J., GUI, X., XING, Y., ZHANG, C., ZOU, J., 2020. Enhanced electronic effect improves the collecting efficiency of benzohydroxamic acid for scheelite flotation. Minerals Engineering. 152, 106308.
  • YANG, S., PENG, T., LI, H., FENG, Q., QIU, X., 2015. Flotation mechanism of wolframite with varied components Fe/Mn. Mineral Processing & Extractive Metallurgy Review, 37:1, 34-41.
  • YAO, W., LI, M., ZHANG, M., CUI, R., SHI, J., NING, J., 2020. Decoupling the effects of solid and liquid phases in a Pbwater glass mixture on the selective flotation separation of scheelite from calcite. Minerals Engineering, 154, 106423.
  • YIN, W., WANG, J., 2014. Effects of particle size and particle interactions on scheelite flotation. J Transactions of Nonferrous Metals Society of China 24(11):3682-3687.
  • ZHANG, Y., LI, Y., CHEN, R., WANG, Y., DENG, J., LUO, X., 2017. Flotation separation of scheelite from fluorite using sodium polyacrylate as inhibitor. J Minerals. 7(6):102.
  • ZHANG, Y., HU, Y., WANG, Y., WEN .S., 2014. Effects of sodium silicate on flotation behavior of calcium-bearing minerals and its mechanism. J Chinese Journal of Nonferrous Metals 24(9):2366-2372.
  • ZHAO, G., WANG, S., ZHONG, H., 2015. Study on the Activation of Scheelite and Wolframite by Lead Nitrate. J Minerals 5(2):247-258.
  • ZHAO, W., HU, Y., HAN, H., SUN, W., WANG, R., WANG, J., 2018. Selective flotation of scheelite from calcite using Al-Na2SiO3 polymer as depressant and Pb-BHA complexes as collector. J Minerals Engineering 80, 45-49.
  • ZHANG, Z., CAO, Y., MA, Z., LIAO, Y., 2019. Impact of calcium and gypsum on separation of scheelite from fluorite using sodium silicate as depressant. Separation and Purification Technology, 215, 249–258.
Typ dokumentu
Bibliografia
Identyfikator YADDA
bwmeta1.element.baztech-94accd74-508f-4cef-8da4-88b7046e6e53
JavaScript jest wyłączony w Twojej przeglądarce internetowej. Włącz go, a następnie odśwież stronę, aby móc w pełni z niej korzystać.