Heavy metal adsorption by dewatered iron-containing waste sludge

• Autorzy: Yildiz S. , Sevinç S.

Identyfikatory

DOI

10.1515/eces-2018-0030

Warianty tytułu

PL

Adsorpcja metali ciężkich przez odwodniony osad ściekowy zawierający żelazo

• Języki publikacji: EN

Abstrakty

EN

Drinking water treatment plants produce significant amounts of waste sludge. In this study, removal of Nickel ion by use of wastewater sludge was aimed. The adsorption capability of waste sludge was optimized with varying physical parameters such as pH, adsorbent dosage, adsorbate concentration, contact time, shaking speed and temperature. Initial concentration was set as 25 mg/dm3, absorbent dose was set as 0.3 g/cm3, and temperature was set as 25 °C. Compliance of balance data with Langmuir, Freundlich, Temkin and D-R isotherm models was investigated. The highest R 2 values were obtained with Freundlich isotherm (R 2 = 0.92-0.95). Adsorption kinetics was analysed using pseudo-first order, pseudo-second order, Weber and Morris intraparticle diffusion and Elovich kinetic models, and the system was found to be in a better compliance with pseudo-second order kinetic model. Iron sludge was used as sorbent, and accordingly total iron ion measurements were carried out to determine its possible effects on water. Additionally, SEM, EDX, FTIR spectroscopy, XRD spectrum and atomic force microscope (AFM) measurements were conducted to determine the interaction between the sorbent and metal ions, in addition to characterization of the sorbent. As indicated by research results, drinking water treatment sludge proved to be a potential adsorbent for removal of nickel(II) ions from the solution.

Słowa kluczowe

EN

waste sludge; isotherm study; iron; Ni(II) ions

PL

osad ściekowy; badanie izoterm; żelazo; jony Ni(II)

• Wydawca: Towarzystwo Chemii i Inżynierii Ekologicznej
• Czasopismo: Ecological Chemistry and Engineering. S
• Rocznik: 2018
• Tom: Vol. 25, nr 3
• Strony: 431--456
• Opis fizyczny: Bibliogr. 85 poz., rys., wykr., tab., fot.

Twórcy

autor

Yildiz S.

• Department of Environmental Engineering, Engineering Faculty, Cumhuriyet University, 58140, Sivas, Turkey, phone [phone]

autor

Sevinç S.

• Institute of Science, Cumhuriyet University, 58140, Sivas, Turkey

Bibliografia

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Uwagi

PL

Opracowanie rekordu w ramach umowy 509/P-DUN/2018 ze środków MNiSW przeznaczonych na działalność upowszechniającą naukę (2018).