Preparation of hexamethylol melamine resin with low crystallization water and low viscosity for hexamethylol melamine/polyvinyl alcohol composite membrane

• Autorzy: Liu Xing-Jian , Gu Yan-Wen , Zhen Jian-Fei , Wu Jiang , Hu Bing

Identyfikatory

DOI

10.2478/pjct-2022-0007

• Języki publikacji: EN

Abstrakty

EN

Hexamethylol melamine resins (HMM) with low crystallization water content and low viscosity were prepared by inhibiting the condensation polymerization of low hexamethylol melamine. The effects of catalyst, pH, formalde-hyde/melamine ratio, reaction temperature and time on the synthesis parameters of HMM were investigated. The results showed that the sample (HMM8) synthesized with Na₂CO₃-NaHCO₃ as catalyst had the crystallization water content lower than 10%, being with a viscosity of about 0.26 Pa·s. The melting temperature of HMM8/polyvinyl alcohol (PVA) curing system was about 164.3 oC. It was found that the higher the amount of formaldehyde, the greater the hydroxyl methyl bounded to each triazine ring. Compared with the traditional melamine formaldehyde resin which had the crystallization water content of about 20–30%, the production of this resin was expected to reduce the energy consumption of industrial reaction, while the resin with 10% crystallization water content was more conducive to the development of alloying HMM/PVA composite membrane.

Słowa kluczowe

EN

low crystallization water content; low energy consumption; low viscosity; hexamethylolmelamine/polyvinyl alcohol; composite membrane

• Wydawca: West Pomeranian University of Technology. Publishing House
• Czasopismo: Polish Journal of Chemical Technology
• Rocznik: 2022
• Tom: Vol. 24, nr 1
• Strony: 47--56
• Opis fizyczny: Bibliogr. 44 poz., rys., tab., wz.

Twórcy

autor

Liu Xing-Jian

• Hubei University of Technology, Nano Inorganic Functional Materials Laboratory, Wuhan 430068, Hubei, China

autor

Gu Yan-Wen

• Hubei University of Technology, Nano Inorganic Functional Materials Laboratory, Wuhan 430068, Hubei, China

autor

Zhen Jian-Fei

• Hubei University of Technology, Nano Inorganic Functional Materials Laboratory, Wuhan 430068, Hubei, China

autor

Wu Jiang

• Shanghai University of Electric Power, College of Energy and Mechanical Engineering, Shanghai 200090, China

autor

Hu Bing

• Hubei University of Technology, New Catalytic Technology and Green Chemical Process, Wuhan 430068, Hubei, China

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Uwagi

Opracowanie rekordu ze środków MEiN, umowa nr SONP/SP/546092/2022 w ramach programu "Społeczna odpowiedzialność nauki" - moduł: Popularyzacja nauki i promocja sportu (2022-2023).