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Mechanical strength and reliability of the porous materials used as adsorbents/catalysts and the new development trends

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Języki publikacji
EN
Abstrakty
EN
Purpose: This paper aims to provide an understanding on some aspects of the porous material strength and reliability and to present future trends of the research on the mechanical properties of this solid porous materials. Design/methodology/approach: It shows that a multitest approach must be designed in order to measure the particle strength and then optimise the production process to enhance its strength. This approach combines measurements reproducing the different types of stress generated in the separation or catalytic process with an extensive characterisation of the physical and mechanical properties of the porous solid, such as hardness, fracture toughnes, brittle, crushing, attrition, etc. The methodology outlined here on alumina single particle or bulk goes beyond the common practice of evaluating mechanical strength based on a comparative study using a single-crushing test and a bulk-crushing test. Findings: Some recent developments on the basic mechanics of solid porous materials are shown. The main concepts presented are the brittle fracture which leads to the mechanical failure of the porous materials, the measurement and statistical properties of the strength data, the mechanical reliability of the porous material pellets, the mechanical properties of the adsorbent or catalyst packed beds, etc. The use and use limitations of inorganic binders for increasing the mechanical strength is discussed and the most binder systems are presented. Research limitations/implications: The scientific basis for the issues on the adsorbent/ catalyst mechanical properties calls yet for further elucidation and development. Practical implications: It is pointed out that porous materials used as adsorbents/ catalysts, with a high and uniform distributed mechanical strength are beneficial to industrial, energetic and environmental applications. Originality/value: A new route for improving mechanical strength of adsorbents/catalysts will become an unavoidable task not only for their manufacturing but also for to improve the efficiency of separation and catalysis processes
Rocznik
Strony
5--17
Opis fizyczny
Bibliogr. 28 poz.
Twórcy
autor
  • National Institute for Research and Development for Cryogenic & Isotopic Technologies, P.O Râureni; P.O. Box 7; 240050 Rm. Valcea, Romania
Bibliografia
  • [1] J.T. Richardson, Principles of Catalyst Development, Plenum Press, New York, 1989
  • [2] C.R. Bemrose, J.A. Bridgwater, A review of attrition and attrition test methods, Powder Technology 49 (1987) 97-126.
  • [3] J.W. Fulton, Catalyst handling procedures, Chemical Engineering 94 (1987) 99-101.
  • [4] E.R. Beaver, Mechanical testing of catalysts, Che- mical engineering progress 71 (1975) 44-45.
  • [5] Y.D. Li, L. Chang, Z. Li, Measurement methods and reliability analyses for mechanical strength of solid oxide catalysts, Journal of Tianjin University 3 (1989) 9-17.
  • [6] Y.D. Li, D.F. Wu, J.P. Zhang, L. Chang, D.H. Wu, Z.P. Fang, Y.H. Shi, Measurement and statistics of single pellet mechanical strength of dierently shaped catalysts, Powder Technology 113 (1–2) (2000) 176-184.
  • [7] W. Weibull, A statistical distribution function of wide applicability. Journal of Applied Mechanics 18/3 (1951) 293-297.
  • [8] D.F. Wu, Y.D. Li, L. Chang, Study on mechanical properties of solid catalysts, Journal of Chemical Industry and Engineering (China) 51 (2000) 291-294.
  • [9] J.W. Fulton, Testing the catalyst, Chemical Engineering Journal 93 (1986) 71-77.
  • [10] C.R. Bemrose, J. Bridgwater, A review of attrition and attrition test methods, Powder Technology 49 (1987) 97-126.
  • [11] ASTM Standard D4179, Single Pellet Crush Strength of Formed Catalyst Shapes, American Society for Testing Materials (1982).
  • [12] I.C. Van den Born, A. Santen, H.D. Hoekstra, J.T.M. Dehosson, Mechanical Strength of Highly Porous Ceramics, Physical Review E 43/4 (1991) 3794-3795.
  • [13] Y. Hiramatsu, Y. Oka, Determination of the Tensile Strength of Rock by a Compression Test of an Irregular Test Piece, International Journal of Rock Mechanics and Mining Sciences 3 (1966) 89-99.
  • [14] S. Griner, M. Spilka, A. Kania, Heterogenity of mechanical properties and fractures of Co-based metallic glass in a low temperature thermal activation process, Journal of Achievements in Materials and Manufacturing Engineering 66/2 (2014) 53-60.
  • [15] M. Konieczny, B. Szwed, Effect of processing parameters on the tensile behaviour of laminated composites synthesized using titanium and aluminium foils, Journal of Achievements in Materials and Manufacturing Engineering 66/2 (2014) 81-87.
  • [16] H. Dinnebier, I. Ehrlich, The effects of severe temperature changes and high humidity on porous CFRP, Journal of Achievements in Materials and Manufacturing Engineering, 67/1 (2014) 14-20.
  • [17] Y.D. Li, D.F. Wu, J.P. Zhang, L. Chang, D.H. Wu, Z.P. Fang, Y.H. Shi, Measurement and statistics of single pellet mechanical strength of differently shaped catalysts, Powder Technology 113 (2000) 176-184.
  • [18] E.R. Beaver, Mechanical testing of catalysts. Chemical Engineering Progress 71 (1975) 44-45.
  • [19] ASTM D4058 Standard, Drum attrition test (Measurement of attrition and abrasion resistance of catalysts), Designation, 1984.
  • [20] A. Hudecki, M. Pawlyta, L.A. Dobrza ski G. Chladek, Micro and ceramic nanoparticles surface properties examination with gas adsorption method and microscopic transmission, Journal of Achievements in Materials and Manufacturing Engineering 61/2 (2013) 257-262.
  • [21] B.Ya. Venhryn, I.I. Grygorchak, Z.A. Stotsko, B.P. Bakhmatyuk, S.I. Mudry, Yu.O. Kulyk, Effect of ultrasonic treatment of activated carbon on capacitive and pseudocapacitive energy storage in electro chemical supercapacitors, Journal of Achievements in Materials and Manufacturing Engineering 60/2 (2013) 59-65.
  • [22] N. Keshavarzi, F. Akhtar, L. Bergström, Chemical durability of hierarchically porous silicalite-I membrane substrates in aqueous media, Journal of Material Research 28 (2013) 2253-2259.
  • [23] F. Rezaei, P. Webley, Structured adsorbents in gas separation processes, Separation and Purification Technology 70 (2010) 243-56.
  • [24] F. Rezaei, P.A. Webley, Optimal design of engineered gas adsorbents: pore-scale level, Chemical Engineering Science 69 (2012) 270-278.
  • [25] N. Hedin, L. Andersson, L. Bergström, J. Yan, Adsorbents for the post-combustion capture of CO2 using rapid temperature swing or vacuum swing adsorption, Applied Energy 104 (2013) 418-433.
  • [26] F. Rezaei, A. Mosca, P.A. Webley, J. Hedlund, P. Xiao, Comparison of traditional and structured adsorbents for CO2 separation by vacuum-swing adsorption, Industrial & Engineering Chemistry Research 49 (2010) 4832-4841.
  • [27] F. Rezaei, M. Grahn, Thermal management of structured adsorbents in CO2 capture processes, Industrial & Engineering Chemistry Research 51 (2012) 4025-4034.
  • [28] F. Brandani, A. Rouse, S. Brandani, D.M. Ruthven, Adsorption kinetics and dynamic behaviour of a carbon monolith, Adsorption 10 (2004) 99-109.
Typ dokumentu
Bibliografia
Identyfikator YADDA
bwmeta1.element.baztech-93be8a12-02f0-4e20-b3f1-d64bef843169
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