Facilitated transport of germanium from acidic medium through supported liquid membrane using Cyanex 301 as mobile carrier

• Autorzy: Kamran Haghighi Hossein , Irannajad Mehdi , Moradkhani Davood

Identyfikatory

DOI

10.5277/ppmp18124

• Języki publikacji: EN

Abstrakty

EN

In this research, a flat sheet supported liquid membrane (FSSLM) system was used to transfer germanium from the acidic medium. The poly-tetra fluoro ethylene (PTFE) membrane filter with the hydrophobic nature and Cyanex 301 were selected as the support and the mobile carrier, respectively. The influence of various parameters being pH of the feed solution (1.5-5), germanium concentration (10-40 mg/dm3), carrier concentration in the solid membrane (10-40 vol%), and sulfuric acid concentration of the receiving phase (100-400 g/dm3) was investigated on the transport of germanium. Under the optimum condition being pH of 1.5, the germanium concentration of 40 mg/dm3, the carrier concentration of 1.18 mol/dm3, and the sulfuric acid concentration of 400 g/dm3, a mass transfer model was developed. Based on this model, the transport mechanism, diffusion of species to the feed-membrane interface, the chemical reaction of species and Cyanex 301, and diffusion of germanium-Cyanex 301 complexes across SLM were explained. According to the obtained model, the values of 6.57 and 738.6 s/cm were achieved for the aqueous and organic diffusion resistances, respectively.

Słowa kluczowe

EN

germanium; supported liquid membrane; Cyanex 301; mass transfer model; acidic medium

• Wydawca: Oficyna Wydawnicza Politechniki Wrocławskiej
• Czasopismo: Physicochemical Problems of Mineral Processing
• Rocznik: 2019
• Tom: Vol. 55, iss. 1
• Strony: 225--236
• Opis fizyczny: Bibliogr. 38 poz., rys., tab.

Twórcy

autor

Kamran Haghighi Hossein

• Department of Mining and Metallurgical Engineering, Amirkabir University of Technology, Tehran, Iran

autor

Irannajad Mehdi

• Department of Mining and Metallurgical Engineering, Amirkabir University of Technology, Tehran, Iran

autor

Moradkhani Davood

• Faculty of Engineering, University of Zanjan, Zanjan, Iran

Bibliografia

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Uwagi

Opracowanie rekordu w ramach umowy 509/P-DUN/2018 ze środków MNiSW przeznaczonych na działalność upowszechniającą naukę (2019).