Preparation and Characterization of Porous Carbon/RDX Nanocomposite Energetic Materials

• Autorzy: Jiang Ju , Su Jin-Xiao , Liu Zhi-Tao , Du Ping , Liao Xin , Li Xiao-An

Identyfikatory

DOI

10.22211/cejem/172963

• Języki publikacji: EN

Abstrakty

EN

A novel energetic material was fabricated by filling porous carbon with 1,3,5-trinitro-1,3,5-triazinane (RDX) via the ultrasonic stirring method. Characterization (TEM, BET, XRD, FTIR, etc.) was performed to determine the micromorphology, crystal structure, and specific surface area. TEM images indicated that the RDX particles were homogeneously distributed in the channels of the porous carbon, FTIR spectra and the XRD curve of the C/RDX composite exhibited the combined characteristics of porous carbon and RDX. The BET test data also confirmed this situation. The thermal decomposition kinetics and thermodynamics of the C/RDX nanocomposite energetic material were investigated at various heating rates (5, 10, 15, and 20 K·min⁻¹). The test results showed that the thermal decomposition temperature and the critical temperature of thermal explosion were lower than for RDX alone by 46.8 and 40.69 ℃, respectively. The activation energy of the C/RDX composite was lower than those of raw RDX and a C/RDX physical mixture, indicating that the C/RDX composite exhibited high thermolysis activity.

Słowa kluczowe

EN

porous carbon; RDX; nanocomposite materials; thermal decomposition

• Wydawca: Sieć Badawcza Łukasiewicz - Instytut Przemysłu Organicznego
• Czasopismo: Central European Journal of Energetic Materials
• Rocznik: 2023
• Tom: Vol. 20, no. 3
• Strony: 284--301
• Opis fizyczny: Bibliogr. 34 poz., rys., tab., wykr.

Twórcy

autor

Jiang Ju

• School of Chemistry and Chemical Engineering, Nanjing University of Science and Technology, Nanjing, 210014, China

autor

Su Jin-Xiao

• School of Chemistry and Chemical Engineering, Nanjing University of Science and Technology, Nanjing, 210014, China

autor

Liu Zhi-Tao

• School of Chemistry and Chemical Engineering, Nanjing University of Science and Technology, Nanjing, 210014, China

autor

Du Ping

• School of Chemistry and Chemical Engineering, Nanjing University of Science and Technology, Nanjing, 210014, China

autor

Liao Xin

• School of Chemistry and Chemical Engineering, Nanjing University of Science and Technology, Nanjing, 210014, China

autor

Li Xiao-An

• Nanjing Momentum Material Technology Co., Ltd., Nanjing, 211200, China

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